PEDOT:PSS薄膜的山梨醇掺杂对光电池性能的影响

李蛟; 刘俊成; 高从堦

doi:10.7498/aps.60.078803

摘要

采用共混-旋涂技术在ITO导电玻璃上制备出经山梨醇掺杂的PEDOT:PSS导电膜,将所制得的薄膜作为空穴传输层用于有机太阳能电池研究.通过对比分析掺杂前后光电池暗电流曲线与光电流曲线的变化,考察了山梨醇掺杂对器件光伏性能的影响,并就其中的影响机理进行了讨论分析.结果表明,山梨醇的加入,可以明显提高光电池的短路电流,填充因子以及能量转换效率.较未掺杂器件,8wt %山梨醇掺杂条件下,器件短路电流由8.82 mA/cm2增加至11.27 mA/cm2,FF由0.43

关键词:

Abstract

In this article, the PEDOT:PSS doped with sorbitol film is fabricated on an ITO substrate by blending-spin coating method and used as a hole-extraction layer for organic solar cell (OSC). The effect of sorbitol concentration on the photovoltaic performance of the device is investigated based on P3HT:PCBM blend. Compared with a pristine device (i.e., without sorbitol), the sorbitol-doped (8wt %) OSC shows that the short-circuit current density, the fill factor and the power conversion efficiency are inereased from 8.82 to 9.03mA/cm2, 0.43 to 0.474 and 2.12% to 2.39 % (i.e., by about 13%), respectively. The canse of the improvement on performance of the device is discussed, showing that the increase in conductivity and transmittance of composite films is due to the improvement on OSC performances achieved through the incorporation of sorbitol into hole-extraction layer of PEDOT:PSS. The former leads to a lower series resistance of the device, while the latter gives rise to the improvement on the photo-induced carriers of the photovoltaics cells.

Keywords:

作者及机构信息

(1)山东理工大学材料科学与工程学院,淄博 255049; (2)山东理工大学材料科学与工程学院,淄博 255049;中国海洋大学化学化工学院,青岛 266100; (3)中国海洋大学化学化工学院,青岛 266100

基金项目: 教育部新世纪优秀人才支持计划项目(批准号:NCET-04-0648)资助的课题.

Authors and contacts

(1)College of Chemistry and Chemical Engineering , Ocean University of China, Qingdao 266100, China; (2)School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, China; (3)School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, China;College of Chemistry and Chemical Engineering , Ocean University of China, Qingdao 266100, China

参考文献

[1]	Nielsen T D, Cruickshank C, Foged S, Thorsen J, Krebs F C 2010 Sol. Energy Mater. Sol. Cells 94 1553
[2]	Yu H Z, Peng J B, Liu J C 2009 Acta Phys. Sin. 58 669 (in Chinese) [於黄忠、彭俊彪、刘金成 2009 58 669]
[3]	Helgesen M, Sondergaard R, Krebs F C 2010 Energy Environ. Sci. 3 36
[4]	Feng Z H, Hou Y B, Shi Q M, Qin L F, Li Y, Zhang L, Liu X J, Teng F, Wang Y S, Xia R D 2010 Chin. Phys. B 19 8601
[5]	Kim D Y, So F, Gao Y L 2009 Sol. Energy Mater. Sol. Cells 93 1688
[6]	Brown T M, Kim J S, Friend R H, Cacialli F, Daik R, Feast W J 1999 Appl. Phys. Lett. 75 1679
[7]	Boucle J, Chyla S, Shaffer M S P, Durrant J R, Bradley D D C, Nelson J 2008 Adv. Funct. Mater 18 622
[8]	Steirer K X, Reese M O, Rupert B L, Kopidakis N, Olson D C, Collins R T, Ginley D S 2009 Sol. Energy Mater. Sol. Cells 93 447
[9]	Jnsson S K M , Birgerson J , Crispin X , Greczynski G, Osikowicz W, Denier van der Gon A W, Salaneck W R, Fahlman M 2003 Synth. Met. 139 1
[10]	Kim J Y , Jung J H , Lee D E , Joo J 2002 Synth. Met. 126 311
[11]	Aernouts T, Geens W, Poortmans J, Heremans P, Borghs S, Mertens R 2002 Thin Solid Films 403-404 297
[12]	Crispin X, Jakobsson F L E, Crispin A, Grim P C M, Andersson P, Volodin A, Haesendonck C van, Auweraer M Van der, Salaneck W R, Berggren M 2006 Chem. Mater.18 4354
[13]	Wichiansee W, Sirivat A 2009 Mater. Sci. Eng. C 29 78
[14]	Li J, Liu J Ch, Gao C J, Sun H B Mater. Sci. Technol (in Chinese) accepted[李蛟、刘俊成、高从堦、孙海滨材料科学与工艺]录用
[15]	Saunders B R,Turner M L 2008 Adv. Colloid Interface Sci. 138 1
[16]	Braun D, Heeger A J, Kroemer H 1991 J. Electron. Mater 20 945
[17]	Ko Ch J, Lin Y K, Chen F C, Chu C W 2007 Appl. Phys. Lett. 90 3509
[18]	Yu H Z, Peng J B, Liu J C 2009 Acta Phys. Sin. 58 669 (in Chinese) [於黄忠、彭俊彪、刘金成 2009 58 669]
[19]	Li Y W, Liu P Y, Hou L T, Wu B 2010 Acta Phys. Sin. 59 1248 (in Chinese) [李艳武、刘彭义、侯林涛、吴冰 2010 59 1248]
[20]	Gadisa A, Svensson M, Andersson M R 2004 Appl. Phys. Lett. 84 1609
[21]	Yamanari T, Taima T, Sakai J, Saito K 2009 Sol. Energy Mater. Sol. Cells 93 759
[22]	Hummelen J C, Brabec C J, Cravino A, Meissner D, Sariciftci N S, Fromherz T, Rispens M T, Sanchez L 2001 Adv. Funct. Mater 11 374
[23]	Frohne H, Shaheen S E, Brabec C J, Müller D C, Sariciftci N S, Meerholz K 2002 Chem. Phys. Chem. 3 795
[24]	Nardes A M , Kemerink M , de Kok M M , Vinken Maturova E, Janssen K R A J 2008 Org. Electron 9 727
[25]	Cartera S A , Scott J C , Brock P J 1997 Appl. Phys. Lett. 71 1145
[26]	Yu H Z, Peng J B 2007 Acta Phys. Chim. Sin. 23 1637[於黄忠、彭俊彪 2007 物理化学学报 23 1637]

施引文献

[1]	Nielsen T D, Cruickshank C, Foged S, Thorsen J, Krebs F C 2010 Sol. Energy Mater. Sol. Cells 94 1553
[2]	Yu H Z, Peng J B, Liu J C 2009 Acta Phys. Sin. 58 669 (in Chinese) [於黄忠、彭俊彪、刘金成 2009 58 669]
[3]	Helgesen M, Sondergaard R, Krebs F C 2010 Energy Environ. Sci. 3 36
[4]	Feng Z H, Hou Y B, Shi Q M, Qin L F, Li Y, Zhang L, Liu X J, Teng F, Wang Y S, Xia R D 2010 Chin. Phys. B 19 8601
[5]	Kim D Y, So F, Gao Y L 2009 Sol. Energy Mater. Sol. Cells 93 1688
[6]	Brown T M, Kim J S, Friend R H, Cacialli F, Daik R, Feast W J 1999 Appl. Phys. Lett. 75 1679
[7]	Boucle J, Chyla S, Shaffer M S P, Durrant J R, Bradley D D C, Nelson J 2008 Adv. Funct. Mater 18 622
[8]	Steirer K X, Reese M O, Rupert B L, Kopidakis N, Olson D C, Collins R T, Ginley D S 2009 Sol. Energy Mater. Sol. Cells 93 447
[9]	Jnsson S K M , Birgerson J , Crispin X , Greczynski G, Osikowicz W, Denier van der Gon A W, Salaneck W R, Fahlman M 2003 Synth. Met. 139 1
[10]	Kim J Y , Jung J H , Lee D E , Joo J 2002 Synth. Met. 126 311
[11]	Aernouts T, Geens W, Poortmans J, Heremans P, Borghs S, Mertens R 2002 Thin Solid Films 403-404 297
[12]	Crispin X, Jakobsson F L E, Crispin A, Grim P C M, Andersson P, Volodin A, Haesendonck C van, Auweraer M Van der, Salaneck W R, Berggren M 2006 Chem. Mater.18 4354
[13]	Wichiansee W, Sirivat A 2009 Mater. Sci. Eng. C 29 78
[14]	Li J, Liu J Ch, Gao C J, Sun H B Mater. Sci. Technol (in Chinese) accepted[李蛟、刘俊成、高从堦、孙海滨材料科学与工艺]录用
[15]	Saunders B R,Turner M L 2008 Adv. Colloid Interface Sci. 138 1
[16]	Braun D, Heeger A J, Kroemer H 1991 J. Electron. Mater 20 945
[17]	Ko Ch J, Lin Y K, Chen F C, Chu C W 2007 Appl. Phys. Lett. 90 3509
[18]	Yu H Z, Peng J B, Liu J C 2009 Acta Phys. Sin. 58 669 (in Chinese) [於黄忠、彭俊彪、刘金成 2009 58 669]
[19]	Li Y W, Liu P Y, Hou L T, Wu B 2010 Acta Phys. Sin. 59 1248 (in Chinese) [李艳武、刘彭义、侯林涛、吴冰 2010 59 1248]
[20]	Gadisa A, Svensson M, Andersson M R 2004 Appl. Phys. Lett. 84 1609
[21]	Yamanari T, Taima T, Sakai J, Saito K 2009 Sol. Energy Mater. Sol. Cells 93 759
[22]	Hummelen J C, Brabec C J, Cravino A, Meissner D, Sariciftci N S, Fromherz T, Rispens M T, Sanchez L 2001 Adv. Funct. Mater 11 374
[23]	Frohne H, Shaheen S E, Brabec C J, Müller D C, Sariciftci N S, Meerholz K 2002 Chem. Phys. Chem. 3 795
[24]	Nardes A M , Kemerink M , de Kok M M , Vinken Maturova E, Janssen K R A J 2008 Org. Electron 9 727
[25]	Cartera S A , Scott J C , Brock P J 1997 Appl. Phys. Lett. 71 1145
[26]	Yu H Z, Peng J B 2007 Acta Phys. Chim. Sin. 23 1637[於黄忠、彭俊彪 2007 物理化学学报 23 1637]

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