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Er3 + /Yb3 + co-doped TeO2-WO3-Bi2O3 (TWB) glass has been prepared.The absorption spectra, fluorescence spectra and up-conversion luminescence of the glass were measured. The strength parameters of Er3+ in glass were calculated according to the Judd-Oflet theory. Along with Bi2O3 content increasing, Ω2 increases, Ω4, and Ω6 gradually decrease. The broad 1.5 μm fluorescence was observed under 976 nm excitation, and its full width at half maximum (FWHM) was 96 nm. The stimulated emissiow was calculated using the McCumber theory, and the peak emission cross-section was 0.70 × 10-20cm2 at 1.5 μm. The product of stimulated emission cross section and fluorescence of FWHM was 60.2 cm2 nm. At the same time, there is an obvious phenomenon of fluorescence up-conversion of Er3 +/Yb3 + co-doped TeO2-WO3-Bi2O3 glass under 976 nm pump, and the intensity of the conversion gradually weakened with the increasing of Bi2O3 content.
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Keywords:
- tellurite glass /
- spectral properties /
- up-conversion
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[17] Yang J H, Dai S X, Wen L, Liu Z P, Hu L L, Jiang Z H 2003 Acta Phys. Sin. 52 508 (in Chinese) [杨建虎、戴世勋、温 磊、柳祝平、胡丽丽、姜中宏 2003 52 508]
[18] Jia X H, Lü S C 2007 Acta Phys. Sin. 56 4974 (in Chinese) [贾相华、吕树臣2007 56 4974]
[19] Dong L Q, Duan X X, Huang S H, Wang D W, Wen H Y, Yang Y M 2009 Acta Phys. Sin . 58 1263 (in Chinese) [董力强、段晓霞、黄世华、王大伟、温红宇、杨艳民2009 58 1263]
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[1] Chen G X, Jiang Z H, Yang G F, Yang Z M, Zhang Q Y 2007 Acta Phys. Sin. 56 4200 (in Chinese) [陈敢新、杨钢锋、杨中民、张勤远 2007 56 4200]
[2] Tanabe S, Sugimoto N, Ito S, Hanada T 2000 J. Lumin. 87-89 670
[3] Chen W, Hu L L, Wang G N, Wen L, Yang J H, Zhang L Y 2006 Acta Phys. Sin. 2006 55 1486 (in Chinese) [陈 伟、胡丽丽、汪国年、温 磊、杨建虎2006 55 1486]
[4] Jiang Z H, Yang Z M, Zhang Q Y, Zhao C 2006 Acta Phys. Sin. 55 3107 (in Chinese) [姜中宏、杨中民、张勤远、赵 纯2006 55 3106]
[5] Cheng B W, Ding W C, Guo J C,Liu Y, Wang Q M, Yu J Z, Zhang Y, Zuo Y H, 2009 Chin. Phys. B 18 3046
[6] Dai S X, Huang S L, Nie Q H, Xu T F, Zhou L, Zhou Y X 2009 Acta Phys.Sin. 58 1263 (in Chinese) [戴世勋、黄尚廉、聂秋华、徐铁峰、周 灵、周亚训2009 58 1263]
[7] Zhao S H, Chen B Y, Hu L L 2004 Journal of Inorganic Materials 32 1430 (in Chinese) [赵士龙、陈宝玉、胡丽丽 2004 硅酸盐学报 32 1430]
[8] Dai S X, Lu L J, Nie Q H, Shen X, Xu T F, Zhang X D, Zhang X H 2007 Acta Phys. Sin. 56 1759 (in Chinese) [戴世勋、陆龙君、聂秋华、沈 祥、徐铁峰、张旭东、章向华2007 56 1759]
[9] Jia X H, Lv S C, Peng H Y, Sun J T, Zhang M H 2008 Acta Phys. Sin. 57 5978 (in Chinese) [贾相华、吕树臣、彭鸿雁、孙江亭、张梅恒2008 57 5978]
[10] Dai S X, Li X J, Nie Q H, Shen X, Wang X S, Xu T F 2007 Acta Phys. Sin . 56 5520 (in Chinese) [戴世勋、厉旭杰、聂秋华、沈 祥、王训四、徐铁峰2007 56 5520]
[11] Judd B R 1962 Phys. Rev. 127 750
[12] Ofelt G S 1962 J. Chem. Phys. 37 511
[13] Chen D D, Jiang Z H, Zhang Q Y, Zhao C 2007 Acta Phys. Sin. 56 4195 (in Chinese) [陈东丹、姜中宏、张勤远、赵 纯2007 56 4195]
[14] Yang J H, Dai S X 2003 J. Pot. Soc. Am. B 20 5
[15] McCumber D E 1964 Phys. Rev . A 134 299
[16] Miniscalco W J, Quimby R S 1991 Opt. Lett. 16 258
[17] Yang J H, Dai S X, Wen L, Liu Z P, Hu L L, Jiang Z H 2003 Acta Phys. Sin. 52 508 (in Chinese) [杨建虎、戴世勋、温 磊、柳祝平、胡丽丽、姜中宏 2003 52 508]
[18] Jia X H, Lü S C 2007 Acta Phys. Sin. 56 4974 (in Chinese) [贾相华、吕树臣2007 56 4974]
[19] Dong L Q, Duan X X, Huang S H, Wang D W, Wen H Y, Yang Y M 2009 Acta Phys. Sin . 58 1263 (in Chinese) [董力强、段晓霞、黄世华、王大伟、温红宇、杨艳民2009 58 1263]
[20] Cao C Y, Di W H, Qin W P, Wang Y, Zhang J S 2008 Chin. Phys.B 17 3302
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