有机-无机杂化钙钛矿材料的本征稳定性

张钰; 周欢萍

doi:10.7498/aps.68.20190343

摘要

有机-无机杂化钙钛矿太阳能电池的光电转换效率已逾 24%, 效率的飞速提升加之可低成本溶液法制备的市场优势, 使人们越来越期待钙钛矿太阳能电池的商业化. 目前钙钛矿太阳能电池商业化所面临最大的障碍是材料乃至器件的长期不稳定性, 这使其无法在使用寿命上与已商品化的硅基等太阳能电池匹敌. 本文从化学不稳定性和相不稳定性两个层面剖析了有机-无机杂化钙钛矿材料本征不稳定性的问题, 并从组分设计及制备工艺等角度给出了提高钙钛矿太阳能电池器件稳定性的相关建议.

关键词:

杂化钙钛矿 /
本征稳定性

Abstract

The power conversion efficiency of organic-inorganic hybrid perovskite solar cell has exceeded 24%. The rapid increase in efficiency coupled with its cost-effective fabrication has attracted tremendous attention toward the commercialization of perovskite solar cells. The biggest challenge that hinders the commercialization of perovskite solar cells is the long-term instability of materials and the corresponding devices, which cannot compete with other commercialized solar cells, such as Si cells, in terms of lifetime. The intrinsic instability of perovskite material itself is the most critical challenge faced by researchers. In this study, we discuss the intrinsic instability of organic-inorganic hybrid perovskite materials from the aspects of both chemical instability and phase instability. Suggestions for improving the stability of perovskite solar cell are provided from the perspective of composition design and fabrication process.

Keywords:

hybrid perovskite /
intrinsic stability

作者及机构信息

张钰,
周欢萍

北京大学工学院, 北京　100871

通信作者: 周欢萍, happy_zhou@pku.edu.cn

基金项目: 国家自然科学基金(批准号: 51722201, 51672008)资助的课题.

Authors and contacts

College of Engineering, Peking University, Beijing 100871, China

Corresponding author: Zhou Huan-Ping, happy_zhou@pku.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51722201, 51672008).

文章全文 : translate this paragraph

参考文献

[1]	Chapin D M, Fuller C, Pearson G 1954 J. Appl. Phys. 25 676 Google Scholar
[2]	Kaelin M, Rudmann D, Tiwari A 2004 Sol. Energy 77 749 Google Scholar
[3]	Wang M, Chamberland N, Breau L, Moser J E, HumphryBaker R, Marsan B, Zakeeruddin S M, Grätzel M 2010 Nat. Chem. 2 385 Google Scholar
[4]	Zhou H, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z, You J, Liu Y, Yang Y 2014 Science 345 542 Google Scholar
[5]	Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050 Google Scholar
[6]	The National Renewable Energy Laboratory http://www.nrel.gov/ [2019-03-10]
[7]	Burschka J, Pellet N, Moon S J, HumphryBaker R, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316 Google Scholar
[8]	Liu M, Johnston M B, Snaith H J 2013 Nature 501 395 Google Scholar
[9]	Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341 Google Scholar
[10]	Jeon N J, Lee J, Noh J H, Nazeeruddin M K, Grätzel M, Seok S I 2013 J. Am. Chem. Soc. 135 19087 Google Scholar
[11]	Wang D L, Cui H J, Hou G J, Zhu Z G, Yan Q B, Su G 2016 Sci. Rep. 6 18922 Google Scholar
[12]	Conings B, Drijkoningen J, Gauquelin N, Babayigit A, D'Haen J, D'Olieslaeger L, Ethirajan A, Verbeeck J, Manca J, Mosconi E 2015 Adv. Energy Mater. 5 1500477 Google Scholar
[13]	Leijtens T, Eperon G E, Pathak S, Abate A, Lee M M, Snaith H J 2013 Nat. Commun. 4 2885 Google Scholar
[14]	Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Grätzel M, Park N G 2012 Sci. Rep. 2 591 Google Scholar
[15]	Kim H S, Seo J Y, Park N G 2016 ChemSusChem 9 2528 Google Scholar
[16]	Supasai T, Rujisamphan N, Ullrich K, Chemseddine A, Dittrich T 2013 Appl. Phys. Lett. 103 183906 Google Scholar
[17]	张翱, 陈云琳, 闫君, 张春秀 2018 67 106701 Google Scholar Zhang A, Chen Y L, Yan J, Zhang C X 2018 Acta Phys. Sin. 67 106701 Google Scholar
[18]	TurrenCruz S H, Hagfeldt A, Saliba M 2018 Science 362 449 Google Scholar
[19]	Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J 2014 Energy Environ. Sci. 7 982 Google Scholar
[20]	Lee J W, Seol D J, Cho A N, Park N G 2014 Adv. Mater. 26 4991 Google Scholar
[21]	Beal R E, Slotcavage D J, Leijtens T, Bowring A R, Belisle R A, Nguyen W H, Burkhard G F, Hoke E T, McGehee M D 2016 J. Phys. Chem. Lett. 7 746 Google Scholar
[22]	Zhao B, Jin S F, Huang S, Liu N, Ma J Y, Xue D J, Han Q, Ding J, Ge Q Q, Feng Y 2018 J. Am. Chem. Soc. 140 11716 Google Scholar
[23]	Wang P, Zhang X, Zhou Y, Jiang Q, Ye Q, Chu Z, Li X, Yang X, Yin Z, You J 2018 Nat. Commun. 9 2225 Google Scholar
[24]	Luo P, Xia W, Zhou S, Sun L, Cheng J, Xu C, Lu Y 2016 J. Phys. Chem. Lett. 7 3603 Google Scholar
[25]	Xue J, Lee J W, Dai Z, Wang R, Nuryyeva S, Liao M E, Chang S Y, Meng L, Meng D, Sun P 2018 Joule 2 1866 Google Scholar
[26]	Zhou N, Shen Y, Zhang Y, Xu Z, Zheng G, Li L, Chen Q, Zhou H 2017 Small 13 1700484 Google Scholar
[27]	Aristidou N, Sanchez-Molina I, Chotchuangchutchaval T, Brown M, Martinez L, Rath T, Haque S A 2015 Angew. Chem. Int. Edit. 54 8208 Google Scholar
[28]	Wang S, Jiang Y, JuarezPerez E J, Ono L K, Qi Y 2017 Nat. Energy 2 16195 Google Scholar
[29]	Raga S R, Jung M C, Lee M V, Leyden M R, Kato Y, Qi Y 2015 Chem. Mat. 27 1597 Google Scholar
[30]	Li Y, Xu X, Wang C, Ecker B, Yang J, Huang J, Gao Y 2017 J. Phys. Chem. C 121 3904 Google Scholar
[31]	Philippe B, Jacobsson T J, CorreaBaena J P, Jena N K, Banerjee A, Chakraborty S, Cappel U B, Ahuja R, Hagfeldt A, Odelius M 2017 J. Phys. Chem. C 121 26655 Google Scholar
[32]	Cho H, Jeong S H, Park M H, Kim Y H, Wolf C, Lee C L, Heo J H, Sadhanala A, Myoung N, Yoo S 2015 Science 350 1222 Google Scholar
[33]	Xie H, Liu X, Lyu L, Niu D, Wang Q, Huang J, Gao Y 2016 J. Phys. Chem. C 120 215
[34]	Zhang W, Pathak S, Sakai N, Stergiopoulos T, Nayak P K, Noel N K, Haghighirad A A, Burlakov V M, Sadhanala A, Li W 2015 Nat. Commun. 6 10030 Google Scholar
[35]	Liu Z, Hu J, Jiao H, Li L, Zheng G, Chen Y, Huang Y, Zhang Q, Shen C, Chen Q 2017 Adv. Mater. 29 1606774 Google Scholar
[36]	Wang L, Zhou H, Hu J, Huang B, Sun M, Dong B, Zheng G, Huang Y, Chen Y, Li L 2019 Science 363 265 Google Scholar
[37]	Christians J A, Miranda Herrera P A, Kamat P V 2015 J. Am. Chem. Soc. 137 1530 Google Scholar
[38]	Niu G, Guo X, Wang L 2015 J. Mater. Chem. A 3 8970 Google Scholar
[39]	Frost J M, Butler K T, Brivio F, Hendon C H, van Schilfgaarde M, Walsh A 2014 Nano Lett. 14 2584 Google Scholar
[40]	Chen J, Wang Y, Gan L, He Y, Li H, Zhai T 2017 Angew. Chem. Int. Edit. 56 14893 Google Scholar
[41]	Dou L, Wong A B, Yu Y, Lai M, Kornienko N, Eaton S W, Fu A, Bischak C G, Ma J, Ding T, Ginsberg N S, Wang L W, Alivisatos A P, Yang P 2015 Science 349 1518 Google Scholar
[42]	Stoumpos C C, Cao D H, Clark D J, Young J, Rondinelli J M, Jang J I, Hupp J T, Kanatzidis M G 2016 Chem. Mat. 28 2852 Google Scholar
[43]	Zhang X, Ren X, Liu B, Munir R, Zhu X, Yang D, Li J, Liu Y, Smilgies D M, Li R, Yang Z, Niu T, Wang X, Amassian A, Zhao K, Liu S 2017 Energy Environ. Sci. 10 2095 Google Scholar
[44]	Smith I C, Hoke E T, Solis-Ibarra D, McGehee M D, Karunadasa H I 2014 Angew. Chem. 126 11414 Google Scholar
[45]	Grancini G, RoldánCarmona C, Zimmermann I, Mosconi E, Lee X, Martineau D, Narbey S, Oswald F, de Angelis F, Graetzel M 2017 Nat. Commun. 8 15684 Google Scholar
[46]	Li P, Zhang Y, Liang C, Xing G, Liu X, Li F, Liu X, Hu X, Shao G, Song Y 2018 Adv. Mater. 30 1805323 Google Scholar
[47]	Zhao Y, Wei J, Li H, Yan Y, Zhou W, Yu D, Zhao Q 2016 Nat. Commun. 7 10228 Google Scholar
[48]	Yang S, Wang Y, Liu P, Cheng Y B, Zhao H J, Yang H G 2016 Nat. Energy 1 15016 Google Scholar
[49]	Yin W J, Shi T, Yan Y 2014 Adv. Mater. 26 4653 Google Scholar
[50]	Yan Y, Yin WJ, Shi T, Meng W, Feng C 2016 Organic-Inorganic Halide Perovskite Photovoltaics (Switzerland: Springer) pp79－105
[51]	Buin A, Pietsch P, Xu J, Voznyy O, Ip A H, Comin R, Sargent E H 2014 Nano Lett. 14 6281 Google Scholar
[52]	Buin A, Comin R, Xu J, Ip A H, Sargent E H 2015 Chem. Mat. 27 4405 Google Scholar
[53]	Park B W, Seok S I 2019 Adv. Mater. 31 1805337 Google Scholar
[54]	李少华, 李海涛, 江亚晓, 涂丽敏, 李文标, 潘玲, 杨仕娥, 陈永生 2018 67 158801 Google Scholar Li S H, Li H T, Jiang Y X, Tu L M, Li W B, Pan L, Yang S E, Chen Y S 2018 Acta Phys. Sin. 67 158801 Google Scholar
[55]	Yang W S, Park B W, Jung E H, Jeon N J, Kim Y C, Lee D U, Shin S S, Seo J, Kim E K, Noh J H 2017 Science 356 1376 Google Scholar
[56]	Chen Y H, Li N X, Wang L G, Li L, Xu Z Q, Jiao H Y, Liu P F, Zhu C, Zai H C, Sun M Z, Zou W, Zhang S, Xing G C, Liu X F, Wang J P, Li D D, Huang B L, Chen Q, Zhou H P 2019 Nat. Commun. 10 1112 Google Scholar
[57]	Saliba M, Matsui T, Domanski K, Seo J Y, Ummadisingu A, Zakeeruddin S M, CorreaBaena J P, Tress W R, Abate A, Hagfeldt A, Grätzel M 2016 Science 354 206 Google Scholar
[58]	Wang R, Xue J, Meng L, Lee J W, Zhao Z, Sun P, Cai L, Huang T, Wang Z, Wang Z K 2019 Joule 3
[59]	Lee J W, Yu H, Lee K, Bae S, Kim J, Han G R, Hwang D, Kim S K, Jang J 2019 J. Am. Chem. Soc. 141 5808 Google Scholar
[60]	Ohmann R, Ono L K, Kim H S, Lin H, Lee M V, Li Y, Park N G, Qi Y 2015 J. Am. Chem. Soc. 137 16049 Google Scholar
[61]	Rothmann M U, Li W, Zhu Y, Bach U, Spiccia L, Etheridge J, Cheng Y B 2017 Nat. Commun. 8 14547 Google Scholar
[62]	Liu Y T, Collins L, Proksch R, Kim S, Watson B R, Doughty B, Calhoun T R, Ahmadi M, Ievlev A V, Jesse S, Retterer S T, Belianiov A, Xiao K, Huang J S, Sumpter B G, Kalinin S V, Hu B, Ovchinnikova O S 2018 Nat. Mater. 17 1013 Google Scholar
[63]	Shao Y, Fang Y, Li T, Wang Q, Dong Q, Deng Y, Yuan Y, Wei H, Wang M, Gruverman A 2016 Energy Environ. Sci. 9 1752 Google Scholar
[64]	Chen Q, Zhou H, Song T B, Luo S, Hong Z, Duan H S, Dou L, Liu Y, Yang Y 2014 Nano Lett. 14 4158 Google Scholar
[65]	Shao Y, Xiao Z, Bi C, Yuan Y, Huang J 2014 Nat. Commun. 5 5784 Google Scholar
[66]	Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng X C, Huang J 2017 Nat. Energy 2 17102 Google Scholar
[67]	Yang S, Dai J, Yu Z, Shao Y, Zhou Y, Xiao X, Zeng X C, Huang J 2019 J. Am. Chem. Soc. 141 5781 Google Scholar
[68]	Tan H, Jain A, Voznyy O, Lan X Z, de Arquer F P G, Fan J Z, Quintero-Bermudez R, Yuan M J, Zhang B, Zhao Y C, Fan F J, Li P C, Quan L N, Zhao Y B, Lu Z H, Yang Z Y, Hoogland S, Sargent E H 2017 Science 355 722 Google Scholar
[69]	Abdi-Jalebi M, Andaji-Garmaroudi Z, Cacovich S, Stavrakas C, Philippe B, Richter J M, Alsari M, Booker E P, Hutter E M, Pearson A J, Lilliu S, Savenije T J, Rensmo H, Divitini G, Ducati C, Friend R H, Stranks S D 2018 Nature 555 497 Google Scholar
[70]	Wang F, Geng W, Zhou Y, Fang H H, Tong C J, Loi M A, Liu L M, Zhao N 2016 Adv. Mater. 28 9986 Google Scholar
[71]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen Y, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photon. 13 460 Google Scholar
[72]	Bi E, Chen H, Xie F, Wu Y, Chen W, Su Y, Islam A, Grätzel M, Yang X, Han L 2017 Nat. Commun. 8 15330 Google Scholar
[73]	Eames C, Frost J M, Barnes P R, O’regan B C, Walsh A, Islam M S 2015 Nat. Commun. 6 7497 Google Scholar
[74]	Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511 Google Scholar
[75]	van Reenen S, Kemerink M, Snaith H J 2015 J. Phys. Chem. Lett. 6 3808 Google Scholar
[76]	Liu L, Huang S, Lu Y, Liu P, Zhao Y, Shi C, Zhang S, Wu J, Zhong H, Sui M 2018 Adv. Mater. 30 1800544 Google Scholar
[77]	Li Z, Xiao C, Yang Y, Harvey S P, Kim D H, Christians J A, Yang M, Schulz P, Nanayakkara S U, Jiang C S 2017 Energy Environ. Sci. 10 1234 Google Scholar
[78]	Son D Y, Kim S G, Seo J Y, Lee S H, Shin H, Lee D, Park N G 2018 J. Am. Chem. Soc. 140 1358 Google Scholar
[79]	Lee J W, Dai Z, Han T H, Choi C, Chang S Y, Lee S J, de Marco N, Zhao H, Sun P, Huang Y 2018 Nat. Commun. 9 3021 Google Scholar
[80]	Goldschmidt V, Videnskaps-Akad S, Oslo I 1926 Mat. Nat. Kl8
[81]	Li Z, Yang M, Park J S, Wei S H, Berry J J, Zhu K 2016 Chem. Mat. 28 284
[82]	Amat A, Mosconi E, Ronca E, Quarti C, Umari P, Nazeeruddin M K, Grätzel M, de Angelis F 2014 Nano Lett. 14 3608 Google Scholar
[83]	Poglitsch A, Weber D 1987 J. Chem. Phys. 87 6373 Google Scholar
[84]	Christians J A, Schulz P, Tinkham J S, Schloemer T H, Harvey S P, de Villers B J T, Sellinger A, Berry J J, Luther J M 2018 Nat. Energy 3 68 Google Scholar
[85]	CorreaBaena J P, Luo Y, Brenner T M, Snaider J, Sun S, Li X, Jensen M A, Hartono N T P, Nienhaus L, Wieghold S 2019 Science 363 627 Google Scholar
[86]	Liu C, Li W, Zhang C, Ma Y, Fan J, Mai Y 2018 J. Am. Chem. Soc. 140 3825 Google Scholar
[87]	Ke W, Spanopoulos I, Stoumpos C C, Kanatzidis M G 2018 Nat. Commun. 9 4785

施引文献

图 1 MA⁺, FA⁺, Cs⁺, Rb⁺结构示意图^[18]

Fig. 1. Schematic diagram of MA⁺, FA⁺, Cs⁺, Rb⁺^[18].

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图 2 RbCsFA三元钙钛矿太阳能电池最大功率点输出^[18]

Fig. 2. Maximum power point tracking of RbCsFA hybrid perovskite solar cells^[18].

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图 3 Eu³⁺/Eu²⁺催化消除铅、碘零价缺陷机理^[36]

Fig. 3. Proposed mechanism diagram of cyclically elimination of Pb⁰ and I⁰ defects and regeneration of Eu³⁺-Eu²⁺ metal ion pair^[36].

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图 4 PEA₂MA₂Pb₃I₁₀晶体结构示意图^[44]

Fig. 4. Crystal structure of PEA₂MA₂Pb₃I₁₀^[44].

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图 5 MAPbI₃中各类型点缺陷能级位置^[49]

Fig. 5. Calculated transition energy levels of point defects in MAPbI₃^[49].

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图 6 X射线荧光光谱显示出不同碱金属卤化物添加剂情况下的Br离子分布^[85]

Fig. 6. X-ray fluorescence mapping indicates heterogeneous distribution of Br as a function of alkali metal incorporation of the perovskite films^[85].

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图 7 (a) DMA掺杂薄膜与HI酸添加薄膜对比; (b) DMA掺杂薄膜与HI酸添加薄膜XRD对比; (c) DMA掺杂薄膜与DMF和HI反应所得产物DMAI的核磁共振对比^[87]

Fig. 7. Film properties and component studies: (a) Photographs, (b) XRD spectra, (c) nuclear magnetic resonance spectra of the Cs_0.7DMA_0.3PbI₃ films and DMAI polycrystalline powder synthesized from DMF and HI^[87].

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map

[1]	Chapin D M, Fuller C, Pearson G 1954 J. Appl. Phys. 25 676 Google Scholar
[2]	Kaelin M, Rudmann D, Tiwari A 2004 Sol. Energy 77 749 Google Scholar
[3]	Wang M, Chamberland N, Breau L, Moser J E, HumphryBaker R, Marsan B, Zakeeruddin S M, Grätzel M 2010 Nat. Chem. 2 385 Google Scholar
[4]	Zhou H, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z, You J, Liu Y, Yang Y 2014 Science 345 542 Google Scholar
[5]	Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050 Google Scholar
[6]	The National Renewable Energy Laboratory http://www.nrel.gov/ [2019-03-10]
[7]	Burschka J, Pellet N, Moon S J, HumphryBaker R, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316 Google Scholar
[8]	Liu M, Johnston M B, Snaith H J 2013 Nature 501 395 Google Scholar
[9]	Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341 Google Scholar
[10]	Jeon N J, Lee J, Noh J H, Nazeeruddin M K, Grätzel M, Seok S I 2013 J. Am. Chem. Soc. 135 19087 Google Scholar
[11]	Wang D L, Cui H J, Hou G J, Zhu Z G, Yan Q B, Su G 2016 Sci. Rep. 6 18922 Google Scholar
[12]	Conings B, Drijkoningen J, Gauquelin N, Babayigit A, D'Haen J, D'Olieslaeger L, Ethirajan A, Verbeeck J, Manca J, Mosconi E 2015 Adv. Energy Mater. 5 1500477 Google Scholar
[13]	Leijtens T, Eperon G E, Pathak S, Abate A, Lee M M, Snaith H J 2013 Nat. Commun. 4 2885 Google Scholar
[14]	Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Grätzel M, Park N G 2012 Sci. Rep. 2 591 Google Scholar
[15]	Kim H S, Seo J Y, Park N G 2016 ChemSusChem 9 2528 Google Scholar
[16]	Supasai T, Rujisamphan N, Ullrich K, Chemseddine A, Dittrich T 2013 Appl. Phys. Lett. 103 183906 Google Scholar
[17]	张翱, 陈云琳, 闫君, 张春秀 2018 67 106701 Google Scholar Zhang A, Chen Y L, Yan J, Zhang C X 2018 Acta Phys. Sin. 67 106701 Google Scholar
[18]	TurrenCruz S H, Hagfeldt A, Saliba M 2018 Science 362 449 Google Scholar
[19]	Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J 2014 Energy Environ. Sci. 7 982 Google Scholar
[20]	Lee J W, Seol D J, Cho A N, Park N G 2014 Adv. Mater. 26 4991 Google Scholar
[21]	Beal R E, Slotcavage D J, Leijtens T, Bowring A R, Belisle R A, Nguyen W H, Burkhard G F, Hoke E T, McGehee M D 2016 J. Phys. Chem. Lett. 7 746 Google Scholar
[22]	Zhao B, Jin S F, Huang S, Liu N, Ma J Y, Xue D J, Han Q, Ding J, Ge Q Q, Feng Y 2018 J. Am. Chem. Soc. 140 11716 Google Scholar
[23]	Wang P, Zhang X, Zhou Y, Jiang Q, Ye Q, Chu Z, Li X, Yang X, Yin Z, You J 2018 Nat. Commun. 9 2225 Google Scholar
[24]	Luo P, Xia W, Zhou S, Sun L, Cheng J, Xu C, Lu Y 2016 J. Phys. Chem. Lett. 7 3603 Google Scholar
[25]	Xue J, Lee J W, Dai Z, Wang R, Nuryyeva S, Liao M E, Chang S Y, Meng L, Meng D, Sun P 2018 Joule 2 1866 Google Scholar
[26]	Zhou N, Shen Y, Zhang Y, Xu Z, Zheng G, Li L, Chen Q, Zhou H 2017 Small 13 1700484 Google Scholar
[27]	Aristidou N, Sanchez-Molina I, Chotchuangchutchaval T, Brown M, Martinez L, Rath T, Haque S A 2015 Angew. Chem. Int. Edit. 54 8208 Google Scholar
[28]	Wang S, Jiang Y, JuarezPerez E J, Ono L K, Qi Y 2017 Nat. Energy 2 16195 Google Scholar
[29]	Raga S R, Jung M C, Lee M V, Leyden M R, Kato Y, Qi Y 2015 Chem. Mat. 27 1597 Google Scholar
[30]	Li Y, Xu X, Wang C, Ecker B, Yang J, Huang J, Gao Y 2017 J. Phys. Chem. C 121 3904 Google Scholar
[31]	Philippe B, Jacobsson T J, CorreaBaena J P, Jena N K, Banerjee A, Chakraborty S, Cappel U B, Ahuja R, Hagfeldt A, Odelius M 2017 J. Phys. Chem. C 121 26655 Google Scholar
[32]	Cho H, Jeong S H, Park M H, Kim Y H, Wolf C, Lee C L, Heo J H, Sadhanala A, Myoung N, Yoo S 2015 Science 350 1222 Google Scholar
[33]	Xie H, Liu X, Lyu L, Niu D, Wang Q, Huang J, Gao Y 2016 J. Phys. Chem. C 120 215
[34]	Zhang W, Pathak S, Sakai N, Stergiopoulos T, Nayak P K, Noel N K, Haghighirad A A, Burlakov V M, Sadhanala A, Li W 2015 Nat. Commun. 6 10030 Google Scholar
[35]	Liu Z, Hu J, Jiao H, Li L, Zheng G, Chen Y, Huang Y, Zhang Q, Shen C, Chen Q 2017 Adv. Mater. 29 1606774 Google Scholar
[36]	Wang L, Zhou H, Hu J, Huang B, Sun M, Dong B, Zheng G, Huang Y, Chen Y, Li L 2019 Science 363 265 Google Scholar
[37]	Christians J A, Miranda Herrera P A, Kamat P V 2015 J. Am. Chem. Soc. 137 1530 Google Scholar
[38]	Niu G, Guo X, Wang L 2015 J. Mater. Chem. A 3 8970 Google Scholar
[39]	Frost J M, Butler K T, Brivio F, Hendon C H, van Schilfgaarde M, Walsh A 2014 Nano Lett. 14 2584 Google Scholar
[40]	Chen J, Wang Y, Gan L, He Y, Li H, Zhai T 2017 Angew. Chem. Int. Edit. 56 14893 Google Scholar
[41]	Dou L, Wong A B, Yu Y, Lai M, Kornienko N, Eaton S W, Fu A, Bischak C G, Ma J, Ding T, Ginsberg N S, Wang L W, Alivisatos A P, Yang P 2015 Science 349 1518 Google Scholar
[42]	Stoumpos C C, Cao D H, Clark D J, Young J, Rondinelli J M, Jang J I, Hupp J T, Kanatzidis M G 2016 Chem. Mat. 28 2852 Google Scholar
[43]	Zhang X, Ren X, Liu B, Munir R, Zhu X, Yang D, Li J, Liu Y, Smilgies D M, Li R, Yang Z, Niu T, Wang X, Amassian A, Zhao K, Liu S 2017 Energy Environ. Sci. 10 2095 Google Scholar
[44]	Smith I C, Hoke E T, Solis-Ibarra D, McGehee M D, Karunadasa H I 2014 Angew. Chem. 126 11414 Google Scholar
[45]	Grancini G, RoldánCarmona C, Zimmermann I, Mosconi E, Lee X, Martineau D, Narbey S, Oswald F, de Angelis F, Graetzel M 2017 Nat. Commun. 8 15684 Google Scholar
[46]	Li P, Zhang Y, Liang C, Xing G, Liu X, Li F, Liu X, Hu X, Shao G, Song Y 2018 Adv. Mater. 30 1805323 Google Scholar
[47]	Zhao Y, Wei J, Li H, Yan Y, Zhou W, Yu D, Zhao Q 2016 Nat. Commun. 7 10228 Google Scholar
[48]	Yang S, Wang Y, Liu P, Cheng Y B, Zhao H J, Yang H G 2016 Nat. Energy 1 15016 Google Scholar
[49]	Yin W J, Shi T, Yan Y 2014 Adv. Mater. 26 4653 Google Scholar
[50]	Yan Y, Yin WJ, Shi T, Meng W, Feng C 2016 Organic-Inorganic Halide Perovskite Photovoltaics (Switzerland: Springer) pp79－105
[51]	Buin A, Pietsch P, Xu J, Voznyy O, Ip A H, Comin R, Sargent E H 2014 Nano Lett. 14 6281 Google Scholar
[52]	Buin A, Comin R, Xu J, Ip A H, Sargent E H 2015 Chem. Mat. 27 4405 Google Scholar
[53]	Park B W, Seok S I 2019 Adv. Mater. 31 1805337 Google Scholar
[54]	李少华, 李海涛, 江亚晓, 涂丽敏, 李文标, 潘玲, 杨仕娥, 陈永生 2018 67 158801 Google Scholar Li S H, Li H T, Jiang Y X, Tu L M, Li W B, Pan L, Yang S E, Chen Y S 2018 Acta Phys. Sin. 67 158801 Google Scholar
[55]	Yang W S, Park B W, Jung E H, Jeon N J, Kim Y C, Lee D U, Shin S S, Seo J, Kim E K, Noh J H 2017 Science 356 1376 Google Scholar
[56]	Chen Y H, Li N X, Wang L G, Li L, Xu Z Q, Jiao H Y, Liu P F, Zhu C, Zai H C, Sun M Z, Zou W, Zhang S, Xing G C, Liu X F, Wang J P, Li D D, Huang B L, Chen Q, Zhou H P 2019 Nat. Commun. 10 1112 Google Scholar
[57]	Saliba M, Matsui T, Domanski K, Seo J Y, Ummadisingu A, Zakeeruddin S M, CorreaBaena J P, Tress W R, Abate A, Hagfeldt A, Grätzel M 2016 Science 354 206 Google Scholar
[58]	Wang R, Xue J, Meng L, Lee J W, Zhao Z, Sun P, Cai L, Huang T, Wang Z, Wang Z K 2019 Joule 3
[59]	Lee J W, Yu H, Lee K, Bae S, Kim J, Han G R, Hwang D, Kim S K, Jang J 2019 J. Am. Chem. Soc. 141 5808 Google Scholar
[60]	Ohmann R, Ono L K, Kim H S, Lin H, Lee M V, Li Y, Park N G, Qi Y 2015 J. Am. Chem. Soc. 137 16049 Google Scholar
[61]	Rothmann M U, Li W, Zhu Y, Bach U, Spiccia L, Etheridge J, Cheng Y B 2017 Nat. Commun. 8 14547 Google Scholar
[62]	Liu Y T, Collins L, Proksch R, Kim S, Watson B R, Doughty B, Calhoun T R, Ahmadi M, Ievlev A V, Jesse S, Retterer S T, Belianiov A, Xiao K, Huang J S, Sumpter B G, Kalinin S V, Hu B, Ovchinnikova O S 2018 Nat. Mater. 17 1013 Google Scholar
[63]	Shao Y, Fang Y, Li T, Wang Q, Dong Q, Deng Y, Yuan Y, Wei H, Wang M, Gruverman A 2016 Energy Environ. Sci. 9 1752 Google Scholar
[64]	Chen Q, Zhou H, Song T B, Luo S, Hong Z, Duan H S, Dou L, Liu Y, Yang Y 2014 Nano Lett. 14 4158 Google Scholar
[65]	Shao Y, Xiao Z, Bi C, Yuan Y, Huang J 2014 Nat. Commun. 5 5784 Google Scholar
[66]	Zheng X, Chen B, Dai J, Fang Y, Bai Y, Lin Y, Wei H, Zeng X C, Huang J 2017 Nat. Energy 2 17102 Google Scholar
[67]	Yang S, Dai J, Yu Z, Shao Y, Zhou Y, Xiao X, Zeng X C, Huang J 2019 J. Am. Chem. Soc. 141 5781 Google Scholar
[68]	Tan H, Jain A, Voznyy O, Lan X Z, de Arquer F P G, Fan J Z, Quintero-Bermudez R, Yuan M J, Zhang B, Zhao Y C, Fan F J, Li P C, Quan L N, Zhao Y B, Lu Z H, Yang Z Y, Hoogland S, Sargent E H 2017 Science 355 722 Google Scholar
[69]	Abdi-Jalebi M, Andaji-Garmaroudi Z, Cacovich S, Stavrakas C, Philippe B, Richter J M, Alsari M, Booker E P, Hutter E M, Pearson A J, Lilliu S, Savenije T J, Rensmo H, Divitini G, Ducati C, Friend R H, Stranks S D 2018 Nature 555 497 Google Scholar
[70]	Wang F, Geng W, Zhou Y, Fang H H, Tong C J, Loi M A, Liu L M, Zhao N 2016 Adv. Mater. 28 9986 Google Scholar
[71]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen Y, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photon. 13 460 Google Scholar
[72]	Bi E, Chen H, Xie F, Wu Y, Chen W, Su Y, Islam A, Grätzel M, Yang X, Han L 2017 Nat. Commun. 8 15330 Google Scholar
[73]	Eames C, Frost J M, Barnes P R, O’regan B C, Walsh A, Islam M S 2015 Nat. Commun. 6 7497 Google Scholar
[74]	Snaith H J, Abate A, Ball J M, Eperon G E, Leijtens T, Noel N K, Stranks S D, Wang J T W, Wojciechowski K, Zhang W 2014 J. Phys. Chem. Lett. 5 1511 Google Scholar
[75]	van Reenen S, Kemerink M, Snaith H J 2015 J. Phys. Chem. Lett. 6 3808 Google Scholar
[76]	Liu L, Huang S, Lu Y, Liu P, Zhao Y, Shi C, Zhang S, Wu J, Zhong H, Sui M 2018 Adv. Mater. 30 1800544 Google Scholar
[77]	Li Z, Xiao C, Yang Y, Harvey S P, Kim D H, Christians J A, Yang M, Schulz P, Nanayakkara S U, Jiang C S 2017 Energy Environ. Sci. 10 1234 Google Scholar
[78]	Son D Y, Kim S G, Seo J Y, Lee S H, Shin H, Lee D, Park N G 2018 J. Am. Chem. Soc. 140 1358 Google Scholar
[79]	Lee J W, Dai Z, Han T H, Choi C, Chang S Y, Lee S J, de Marco N, Zhao H, Sun P, Huang Y 2018 Nat. Commun. 9 3021 Google Scholar
[80]	Goldschmidt V, Videnskaps-Akad S, Oslo I 1926 Mat. Nat. Kl8
[81]	Li Z, Yang M, Park J S, Wei S H, Berry J J, Zhu K 2016 Chem. Mat. 28 284
[82]	Amat A, Mosconi E, Ronca E, Quarti C, Umari P, Nazeeruddin M K, Grätzel M, de Angelis F 2014 Nano Lett. 14 3608 Google Scholar
[83]	Poglitsch A, Weber D 1987 J. Chem. Phys. 87 6373 Google Scholar
[84]	Christians J A, Schulz P, Tinkham J S, Schloemer T H, Harvey S P, de Villers B J T, Sellinger A, Berry J J, Luther J M 2018 Nat. Energy 3 68 Google Scholar
[85]	CorreaBaena J P, Luo Y, Brenner T M, Snaider J, Sun S, Li X, Jensen M A, Hartono N T P, Nienhaus L, Wieghold S 2019 Science 363 627 Google Scholar
[86]	Liu C, Li W, Zhang C, Ma Y, Fan J, Mai Y 2018 J. Am. Chem. Soc. 140 3825 Google Scholar
[87]	Ke W, Spanopoulos I, Stoumpos C C, Kanatzidis M G 2018 Nat. Commun. 9 4785

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