石墨烯衍生物作为有机太阳能电池界面材料的研究进展

黄林泉; 周玲玉; 于为; 杨栋; 张坚; 李灿

doi:10.7498/aps.64.038103

摘要

本文综述了石墨烯及其衍生物作为界面材料在有机太阳能电池中的应用, 包括作为阳极界面层、阴极界面层和叠层电池中间层等方面. 氧化石墨烯由于较好的透光性, 易于分散在水溶液中与溶液加工等优点已被应用在有机太阳能电池中. 对氧化石墨烯作为阳极界面层的研究包括通过部分还原或掺杂提高其导电性、通过引入高负电性原子提高其表面功函数, 以及通过与其他材料复合提高性能等. 同时, 本文综述了石墨烯衍生物及复合材料作为有机太阳能电池阴极界面层和叠层电池中间层的研究. 最后本文展望了石墨烯及其衍生物在有机太阳能电池与有机无机复合钙钛矿太阳能电池中的应用前景.

关键词:

Abstract

This review surveys the application of graphene and its derivatives in organic solar cells, used as interfacial layers: including anode interfacial layers, cathode interfacial layers, and intermediate layers in a tandem device. Research work has be done for increasing the electroconductivity by reducing the oxide to partially oxidized graphene, as well as chemically modifying or making composite interfacial layer. Additionally, the researches on graphene derivatives and combined interfacial layers used as a cathode interfacial layer or an intermediate layer in the tandem device are discussed. Finally, this review suggests that graphene and its derivatives are potential to be used in perovskite solar cells.

Keywords:

作者及机构信息

1.
中国科学院大连化学物理研究所催化基础国家重点实验室, 洁净能源国家实验室(筹), 辽宁大连 116023;

2.
桂林电子科技大学材料科学与工程学院, 广西信息材料重点实验室, 广西桂林 541004;

3.
中国科学院大学, 北京 100049

基金项目: 国家自然科学基金(批准号: 20904057和21374120) 与广西“自治区八桂学者”专项经费资助的课题.

Authors and contacts

1.
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, China;

2.
Department of Materials Science & Engineering, Guilin University of Electrical Technology, Guilin 541004, China;

3.
Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 20904057, 21374120), and the Bagui Project of Guangxi Autonomous Region.

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施引文献

[1]	Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A 2004 Science 306 666
[2]	Yang G W, Xu C L, Li H L 2008 Chem. Commun. 6537
[3]	Dou L, You J, Hong Z, Xu Z, Li G, Street R A, Yang Y 2013 Adv. Mater. 25 6642
[4]	Qian D, Ma W, Li Z, Guo X, Zhang S, Ye L, Ade H, Tan Z a, Hou J 2013 J. Am. Chem. Soc. 135 8464
[5]	He Z, Wu H, Cao Y 2014 Adv. Mater. 26 1006
[6]	Chen L M, Hong Z, Li G, Yang Y 2009 Adv. Mater. 21 1434
[7]	Gnes S, Neugebauer H, Sariciftci N S 2007 Chem. Rev. 107 1324
[8]	Chen Y, Wan X, Long G 2013 Acc. Chem. Res. 46 2645
[9]	Coughlin J E, Henson Z B, Welch G C, Bazan G C 2013 Acc. Chem. Res. 47 257
[10]	Lin Y, Li Y, Zhan X 2012 Chem. Soc. Rev. 41 4245
[11]	Chen Y H, Lin L Y, Lu C W, Lin F, Huang Z Y, Lin H W, Wang P H, Liu Y H, Wong K T, Wen J, Miller D J, Darling S B 2012 J. Am. Chem. Soc. 134 13616
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[15]	Cheng Y J, Yang S H, Hsu C S 2009 Chem. Rev. 109 5868
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[17]	Weinberger B R, Akhtar M, Gau S C 1982 Synth. Met. 4 187
[18]	Tang C W 1986 Appl. Phys. Lett. 48 183
[19]	Yu G, Gao J, Hummelen J C, Wudl F, Heeger A J 1995 Science 270 1789
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[25]	Liu Z, Liu Q, Huang Y, Ma Y, Yin S, Zhang X, Sun W, Chen Y 2008 Adv. Mater. 20 3924
[26]	Braun S, Salaneck W R, Fahlman M 2009 Adv. Mater. 21 1450
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[60]	Chuang M K, Lin S W, Chen F C, Chu C W, Hsu C S 2014 Nanoscale 6 1573
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[62]	Stratakis E, Stylianakis M M, Koudoumas E, Kymakis E 2013 Nanoscale 5 4144
[63]	Ryu M S, Jang J 2011 Sol. Energy Mater. Sol. Cells 95 2893
[64]	Chao Y H, Wu J S, Wu C E, Jheng J F, Wang C L, Hsu C S 2013 Adv. Energy Mater. 3 1279
[65]	Park Y, Soon Choi K, Young Kim S 2012 Physica Status Solidi 209 1363
[66]	Liu J, Kim G H, Xue Y, Kim J Y, Baek J B, Durstock M, Dai L 2014 Adv. Mater. 26 786
[67]	Liu J, Xue Y, Gao Y, Yu D, Durstock M, Dai L 2012 Adv. Mater. 24 2228
[68]	Qu S, Li M, Xie L, Huang X, Yang J, Wang N, Yang S 2013 ACS Nano 7 4070
[69]	Wang D H, Kim J K, Seo J H, Park I, Hong B H, Park J H, Heeger A J 2013 Angew. Chem. Int. Ed. 52 2874
[70]	Beliatis M J, Gandhi K K, Rozanski L J, Rhodes R, McCafferty L, Alenezi M R, Alshammari A S, Mills C A, Jayawardena K D G I, Henley S J, Silva S R P 2014 Adv. Mater. 26 2078
[71]	Yu H Z 2013 Acta Phys. Sin 62 027201
[72]	Sista S, Park M H, Hong Z R, Wu Y, Hou J H, Kwan W L, Li G, Yang Y 2010 Adv. Mater. 22 380
[73]	Gilot J, Wienk M M, Janssen R A J 2010 Adv. Mater. 22 E67
[74]	Tung V C, Kim J, Huang J 2012 Adv. Energy Mater. 2 299
[75]	Tung V C, Kim J, Cote L J, Huang J 2011 J. Am. Chem. Soc. 133 9262
[76]	Tong S W, Wang Y, Zheng Y, Ng M F, Loh K P 2011 Adv. Funct. Mater. 21 4430
[77]	Yusoff A R b M, Jose da Silva W, Kim H P, Jang J 2013 Nanoscale 5 11051
[78]	Park N G 2014 Mater. Today DOI.10.1016/j. mattod.2014.07.007
[79]	Jeng J Y, Chen K C, Chiang T Y, Lin P Y, Tsai T D, Chang Y C, Guo T F, Chen P, Wen T C, Hsu Y J 2014 Adv. Mater. 26 4107
[80]	Zhao Y, Nardes A M, Zhu K 2014 Appl. Phys. Lett. 104 213906
[81]	Christians J A, Fung R C M, Kamat P V 2013 J. Am. Chem. Soc. 136 758
[82]	Burschka J, Pellet N, Moon S J, Humphry Baker R, Gao P, Nazeeruddin M K, Gratzel M 2013 Nature 499 316
[83]	Xiao Z, Bi C, Shao Y, Dong Q, Wang Q, Yuan Y, Wang C, Gao Y, Huang J 2014 Energy Environ. Sci. 7 2619
[84]	Seo J, Park S, Chan Kim Y, Jeon N J, Noh J H, Yoon S C, Seok S I 2014 Energy Environ. Sci. 7 2642
[85]	Liu M, Johnston M B, Snaith H J 2013 Nature 501 395
[86]	Wang J T W, Ball J M, Barea E M, Abate A, Alexander Webber J A, Huang J, Saliba M, Mora Sero I, Bisquert J, Snaith H J, Nicholas R J 2013 Nano Lett. 14 724

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