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单锥形纳米孔的制备和离子传导特性研究

朱晓蕊 王卫东 秦广雍 焦浈

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单锥形纳米孔的制备和离子传导特性研究

朱晓蕊, 王卫东, 秦广雍, 焦浈

Fabrication and electrolytic conduction of single conical nanopores

Zhu Xiao-Rui, Wang Wei-Dong, Qin Guang-Yong, Jiao Zhen
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  • 用荷能重离子径迹刻蚀的方法在高分子多聚物膜 (PET) 上制备出单锥形纳米孔. 刻蚀过程通过监测跨膜电流来控制, 最大刻蚀电流Imax不同, 得到的锥形孔小孔孔径也不同. 研究单锥形纳米孔在KCl 溶液中的I-V曲线发现, 单锥形纳米孔的离子传导呈现出不对称特性, 该现象称为整流效应, 整流系数γ大小随纳米小孔孔径大小和电解质溶液浓度而变化.
    Single conical nanopores were fabricated by etching single-ion-irradiated polymer (ethylene terephthalate) (PET) films. The etching process was monitored by measuring the transmembrane current. A series of conical nanopores with different tip sizes were obtained at different maximum etching currents, "Imax". Results showed that it was possible to control the tip diameter by terminating etching at a certain Imax. The current-voltage characteristic of the nanopores in KCl solution was investigated. Results showed also that the ionic conduction was asymmetrical, this phenomenon is called rectification. The current rectification coefficient, was influenced by the tip size and electrolyte concentration.
    • 基金项目: 国家自然科学基金 (批准号: 30800204, 41101244) 资助的课题.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 30800204, 41101244).
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    [5]

    Siwy Z, Kosinska I D, Fulinski A, Martin C R 2005 Phys. Rev. Lett. 94 048102

    [6]

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    [7]

    Jiang Y, Lee A, Chen J, Cadene M, Chait B T, MacKinnon R 2002 Nature 417 523

    [8]

    Krapf D, Wu M Y, Smeets R M M, Zandbergen H W, Dekker C, Lemay S G 2006 Nano Lett. 6 105

    [9]

    Fologea D, Gershow M, Ledden B, McNabb D S, Golovchenko J A, Li J 2005 Nano Lett. 5 1905

    [10]

    Mara A, Siwy Z, Trautmann C, Wan J, Kamme F 2004 Nano Lett. 4 497

    [11]

    Siwy Z, Trofin L, Kohli P, Baker L A, Trautmann C, Martin C R 2005 J. Am. Chem. Soc. 127 5000

    [12]

    Han A, Schrmann G, Mondin G, Bitterli R, Hegelbach N, de Rooij N F, Staufer U 2006 Appl. Phys. Lett. 88 093901

    [13]

    Iqbal S M, Akin D, Bashir R 2007 Nature Nanotechnology 2 243

    [14]

    Li J, Gershow M, Stein D, Brandin E, Golovchenko J A 2003 Nature Mater 2 611

    [15]

    Chang H, Kosari F, Andreadakis G, Alam M A, Vasmatzis G, Bashir R 2004 Nano Lett. 4 1551

    [16]

    Kohli P, Harrell C C, Cao Z, Gasparac R, Tan W, Martin C R 2004 Science 305 984

    [17]

    Keyser U F, Koeleman B N, Dorp S V, Krapf D, Smeets R M M, Lemay S G, Dekker N H, Dekker C 2006 Nat. Phys. 2 473

    [18]

    Yan H, Huang Q L, Cui J, Veinot J G C, Kern M M, Marks T J 2003 Advanced Materials 15 835

    [19]

    Chu S Z, Wada K, Inoue S, Isogai M, Yasumori A 2005 Advanced Materials 17 2115

    [20]

    Siwy Z, Apel P Y, Baur D, Dobrev D D, Korchev Y E, Neumann R , Spohr R, Trautmann C, Voss K O 2003 Surface Science 1061 532

    [21]

    Apel P Y, Korchev Y E, Siwy Z, Spohr R, Yoshida M 2001 Nuclear Instruments and Methods in Physics Reasearch B 184 337

    [22]

    Trautmann C, Bruchle W, Spohr R, Vetter J, Angert N 1996 Nuclear Instruments and Me thods in Physics Reasearch B 111 70

    [23]

    Apel P Y, Blonskaya1 I V, Dmitriev S N, Orelovitch O L, Presz A, Sartowska B A, 2007 Nanotechnology 18 305302

    [24]

    Schiedt B, Healy K , Morrison A P, Neumann R, Siwy Z 2005 Nuclear Instruments and Methods in Physics Reasearch B 236 109

    [25]

    Stein D, Kruithof M, Dekker C 2004 Phys. Rev. Lett. 93 035901

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  • PDF下载量:  860
  • 被引次数: 0
出版历程
  • 收稿日期:  2012-10-08
  • 修回日期:  2012-12-06
  • 刊出日期:  2013-04-05

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