5 at%Yb3+: YNbO4 的提拉法晶体生长和光谱特性

周鹏宇; 张庆礼; 杨华军; 宁凯杰; 孙敦陆; 罗建乔; 殷绍唐

doi:10.7498/aps.61.228103

摘要

用提拉法生长了新型激光晶体5 at% Yb3+:YNbO4, 测量了它的吸收和光致发光光谱, 计算了它的吸收和发射截面, 并对其激光性能进行了评估. Yb3+:YNbO4的吸收半峰全宽为17 nm, 吸收峰位于933, 955, 974和1003 nm, 相应的吸收截面分别为0.731020, 1.8510-20, 0.8610-20和0.4410-20 cm2; 最大吸收截面值为Yb3+:YAG的两倍. 光致发光谱的发射带的中心位置处于1020 nm附近, 相应的半高宽为41 nm, 是Yb3+:YAG的3倍; Yb3+:YNbO4在955, 974, 1005, 1021和1030 nm处都有着较大的发射截面, 截面值分别为0.6910-20, 0.8610-20, 1.8110-20, 1.1110-20和0.5710-20 cm2, 最大发射截面值与Yb3+:YAG相当. Yb3+:YNbO4晶体的宽发射带有利于实现相应波长的超短脉冲和可调谐激光输出, 表明它是在这些领域非常有希望的全固态工作物质.

关键词:

Yb3+:YNbO4 /
晶体生长 /
光谱性质

Abstract

5 at%Yb3+:YNbO4 crystal is grown by Czochralski(CZ) method. Its transmission and emission spectra are measured. The absorption peaks are located at 933, 955, 974 and 1003 nm with their corresponding absorbtion cross section values 0.7310-20, 1.8510-20, 0.8610-20 and 0.4410-20 cm2; and the FWHM of 955 nm absorbtion peak is 17 nm. Its emission band centered at 1020 nm with the FWHM is 41 nm, which is over three times that of Yb3+:YAG crystal. The emission cross section values of 955, 974, 1005, 1021 and 1030 nm peaks are calculated to be 0.6910-20, 0.8610-20, 1.8110-20, 1.1110-20 and 0.5710-20 cm2, respectively, and the biggest one is comparable to that of Yb3+:YAG crystal. The laser parameters of 5 at% Yb3+:YNbO4 crystal are evaluated and the results suggest that it is a potential all-solid-state pumped laser crystal in tunable and ultrafast lasers field.

Keywords:

作者及机构信息

1.
中科院安徽光学精密机械研究所安徽省光子器件与材料重点实验室, 合肥 230031;

2.
中国科学院研究生院, 北京 100049

基金项目: 国家自然科学基金(批准号: 90922003, 50772112, 50872135, 50932005)和中科院知识创新项目(批准号: YYYJ-1002)资助的课题.

Authors and contacts

1.
The Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;

2.
Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 90922003, 50772112, 50872135, 50932005), and the Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No.YYYJ-1002).

参考文献

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施引文献

[1]	Qiu H W, Mao Y L, Dong J, Deng P Z, Xu J, Chen W 2002 Chinese J. Quant. Electron. 19 1 (in Chinese) [邱宏伟, 毛艳丽, 董俊, 邓佩珍, 徐军, 陈伟 2002 量子电子学报 19 1]
[2]	Zhang Q L, Xiao J Z, Sun D L, Wang A H, Yin S T 2004 Specrosc. Spect. Anal. 24 1157 (in Chinese) [张庆礼, 肖敬忠, 孙敦陆, 王爱华, 殷绍唐 2004 光谱学与光谱分析 24 1157]
[3]	Wang X D, Zhao Z W, Xu X D, Song P X, Jiang B X, Xu J, Deng P Z 2006 Acta Phys. Sin. 55 4558 (in Chinese) [王晓丹, 赵志伟, 晓东, 宋平新, 姜本学, 徐军, 邓佩珍 2006 55 4558]
[4]	Zhang H J, Jiang M H 2008 J. Inorg. Mater. 23 417 (in Chinese) [张怀金, 蒋民华 2008 无机材料学报 23 417]
[5]	Zhang Q L, Zhou W L, Liu W P, Ding L H, Luo J Q, Yin S T, Jiang H H 2010 Acta Opt. Sin. 30 849 (in Chinese) [张庆礼, 周文龙, 刘文鹏, 丁丽华, 罗建乔, 殷绍唐, 江海河 2010 光学学报 30 849]
[6]	Ding L H, Zhang Q L, Zhou W L, Liu W P, Yin S T 2009 The Pacific Rim Conference on Lasers and Electro-Optics, ShangHai, China, 2009 pp2
[7]	Gaume R, Haumesser P H, Viana B, Vivien D, Ferrand B, Aka G 2002 Opt. Mater. 19 81
[8]	Yan C, Zhao G, Zhang L, Xu J, Liang X Y, Juan D, Li W X, Pan H F, Ding L G, Zeng H P 2006 Solid State Commun. 137 451
[9]	Xue Y C, Wang Q Y, Chai L, Liu Q W, Zhao G J, Su L B, Xu X D, Xu J 2006 Acta Phys. Sin. 55 457 (in Chinese) [薛迎红, 王清月, 柴路, 刘庆文, 赵广军, 苏良碧, 徐晓东, 徐军 2006 55 457]
[10]	Jacquemet M, Jacquemet C, Janel N, Druon F, Balembois F 2005 Appl. Phys. B 80 171
[11]	Sych A M, Golub A M 1977 Russian Chem. Rev. 46 417
[12]	Choi S H, Anoop G, Suh D W, Kim K P, Lee H J, Yoo J S 2012 J. Rare Earths 30 205
[13]	Lee E Y, Kim Y J 2010 Thin Solid Films 518 E72
[14]	Nazarov M, Kim Y J, Lee E Y, Min K I, Jeong M S, Lee S W, Noh D Y 2010 J. App. Phys. 107 103104
[15]	Zhou Y, Ma Q, Lu M, Qiu M, Zhang A 2008 J. Phys. Chem. C 112 19901
[16]	Xiao X Z, Yan B 2008 J. Alloys Compd. 456 447
[17]	Xiao X Z, Yan B 2005 J. Non-cryst. Solids 351 3634
[18]	Trunov V K, Efremov V A, Velikodnyi Y A, Averina I M 1981 Kristallografiya 26 67
[19]	Zhang Q L, Yin S T, Wang Z B, Sun D L, Wan S M 2007 J. Synth. Cryst. l36 111 (in Chinese) [张庆礼, 殷绍唐, 王召兵, 孙敦陆, 万松明 2007 人工晶体学报 l36 111]
[20]	Chénais S, Duron F, Balembos F, Georges P, Brenier A, Boulon G 2003 Opt. Mater. 22 99
[21]	Gschneidner K A Jr., LeRoy E 1996 Handbook on the Physics and Chemistry of Rear Earths (Vol. 23) (Elsevier Science B. V.) p267
[22]	Payne S A, Chase L L, Smith L K 1992 IEEE. Quant. Electron. 28 2619
[23]	Zhang H W, Yang Q H, Xu J, Su L B 2007 Acta Photonica Sin. 36 286 (in Chinese) [张红伟, 杨秋红, 徐军, 苏良碧 2007 光子学报 36 286]
[24]	Song P X, Zhao Z W, Xu X D, Den P Z, Xu J 2005 Chinese J. Lasers 32 1433 (in Chinese) [宋平新, 赵志伟, 徐晓东, 邓佩珍, 徐军 2005 中国激光 32 1433]
[25]	DeLoach L D, Payne S A, Smith L K, Kway W L, Krupke W F 1994 J. Opt. Soc. Am. B 11 269
[26]	Boulon G, Collombet A, Brenier A, Cohen-Adad Marie-Thor.se, Yoshikawa A, Kheirreddine Lebbou, Lee J H, Fukuda T 2001 Adv. Funct. Mater. 11 263

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