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由于结合了金属和玻璃的特性,非晶合金表现出许多新奇和优异的力学和物理性质,在很多领域具有广泛的应用前景.非晶合金具有连续可调的成分、简单无序的原子结构、丰富多变的材料性质,为研究非晶态物理中的许多共性科学问题提供了理想的模型材料.块体非晶合金的发展更是将玻璃和液体及其相关科学问题的研究推进到凝聚态物理和材料科学的研究前沿.中国科学院物理研究所极端条件物理重点实验室亚稳材料合成、结构及性能研究组(EX4组)近二十年来一直致力于非晶材料和物理的研究,在新型非晶合金的制备、物性以及相关机理的研究上取得了许多重要成果.本文介绍团队最近在非晶材料和物理机理方面取得的研究成果,包括非晶合金的动力学行为和调控、非晶合金的表面动力学、功能应用以及材料探索新方法等.Owing to combining the properties of both metal and glass, metallic glasses exhibit superior physical and mechanical properties along with exotic phenomena, so they have a wide application prospect in many areas. In addition, their continuously adjustable composition and simple disordered atomic structure provide ideal model material systems for the study of fundamental questions commonly existing in glassy materials. The discovery of metallic glasses that can form bulk materials has pushed the relevant research to the frontier of condensed matter physics and material science. The EX4 group of the Institute of Physics, Chinese Academy of Sciences, has devoted to the study of glassy materials and physics for many years, and made important contributions to this field. In this paper, we summarize our recent progress of metallic glasses, including the relaxation behavior and stability, surface dynamics, materials functionalities, and new method on materials discovery.
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Keywords:
- metallic glasses /
- structural relaxation /
- surface dynamics /
- glass forming ability
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[1] Debenedetti P G, Stillinger F H 2001 Nature 410 259
[2] Guan P F, Fujita T, Hirata A, Liu Y H, Chen M W 2012 Phys. Rev. Lett. 108 175501
[3] Berthier L, Biroli G 2011 Rev. Mod. Phys. 83 587
[4] Hu Y C, Li F X, Li M Z, Bai H Y, Wang W H 2015 Nat. Commun. 6 8310
[5] Shintani H, Tanaka H 2008 Nat. Mater. 7 870
[6] Sokolov A P, Calemczuk R, Salce B, Kisliuk A, Quitmann D, Duval E 1997 Phys. Rev. Lett. 78 2405
[7] Sokolov A P, Rossler E, Kisliuk A, Quitmann D 1993 Phys. Rev. Lett. 71 2062
[8] Yannopoulos S N, Papatheodorou G N 2000 Phys. Rev. B 62 3728
[9] Luo P, Li Y Z, Bai H Y, Wen P, Wang W H 2016 Phys. Rev. Lett. 116 175901
[10] Luo P, Wen P, Bai H Y, Ruta B, Wang W H 2017 Phys. Rev. Lett. 118 225901
[11] Swallen S F, Kearns K L, Mapes M K, Kim Y S, McMahon R J, Ediger M D, Wu T, Yu L, Satija S 2007 Science 315 353
[12] Guo Y L, Morozov A, Schneider D, Chung J, Zhang C, Waldmann M, Yao N, Fytas G, Arnold C B, Priestley R D 2012 Nat. Mater. 11 337
[13] Yu H B, Luo Y S, Samwer K 2013 Adv. Mater. 25 5904
[14] Singh S, Ediger M D, de Pablo J J 2013 Nat. Mater. 12 139
[15] Luo P, Cao C R, Zhu F, L Y M, Liu Y H, Wen P, Bai H Y, Vaughan G, di Michiel M, Ruta B, Wang W H 2018 Nat. Commun. 9 1389
[16] Wang W H 2012 Nat. Mater. 11 275
[17] Liu Y H, Wang D, Nakajima K, Zhang W, Hirata A, Nishi T, Inoue A, Chen M W 2011 Phys. Rev. Lett. 106 125504
[18] Lu Z, Jiao W, Wang W H, Bai H Y 2014 Phys. Rev. Lett. 113 045501
[19] Wang Z, Sun B A, Bai H Y, Wang W H 2014 Nat. Commun. 5 5823
[20] Zhu Z G, Wen P, Wang D P, Xue R J, Zhao D Q, Wang W H 2013 J. Appl. Phys. 114 083512
[21] Ketov S V, Sun Y H, Nachum S, Lu Z, Checchi A, Beraldin A R, Bai H Y, Wang W H, Louzguine-Luzgin D V, Carpenter M A, Greer A L 2015 Nature 524 200
[22] Concustell A, Mear F O, Surinach S, Baro M D, Greer A L 2009 Phil. Mag. Lett. 89 831
[23] Sheng H W, Liu H Z, Cheng Y Q, Wen J, Lee P L, Luo W K, Shastri S D, Ma E 2007 Nat. Mater. 6 192
[24] Zeng Q S, Sheng H W, Ding Y, Wang L, Yang W G, Jiang J Z, Mao W L, Mao H K 2011 Science 332 1404
[25] Jin H J, Gu X J, Wen P, Wang L B, Lu K 2003 Acta Mater. 51 6219
[26] Wang C, Yang Z Z, Ma T, Sun Y T, Yin Y Y, Gong Y, Gu L, Wen P, Zhu P W, Long Y W, Yu X H, Jin C Q, Wang W H, Bai H Y 2017 Appl. Phys. Lett. 110 111901
[27] Ge T P, Wang C, Tan J, Ma T, Yu X H, Jin C Q, Wang W H, Bai H Y 2017 J. Appl. Phys. 121 205109
[28] Schuster B E, Wei Q, Hufnagel T C, Ramesh K T 2008 Acta Mater. 56 5091
[29] Guo H, Yan P F, Wang Y B, Tan J, Zhang Z F, Sui M L, Ma E 2007 Nat. Mater. 6 735
[30] L Y M, Sun B A, Zhao L Z, Wang W H, Pan M X, Liu C T, Yang Y 2016 Sci. Rep-Uk. 6 28523
[31] Stevenson J D, Wolynes P G 2008 J. Chem. Phys. 129 234514
[32] Cao C R, L Y M, Bai H Y, Wang W H 2015 Appl. Phys. Lett. 107 141606
[33] Chen L, Cao C R, Shi J A, Lu Z, Sun Y T, Luo P, Gu L, Bai H Y, Pan M X, Wang W H 2017 Phys. Rev. Lett. 118 016101
[34] L Y M, Zeng J F, Huang J C, Kuan S Y, Nieh T G, Wang W H, Pan M X, Liu C T, Yang Y 2017 J. Appl. Phys. 121 095304
[35] L Y M 2017 Ph. D. Dissertation (Beijing:Institute of Physics, Chinese Academy of Sciences) (in Chinese)[吕玉苗 2017 博士学位论文 (北京:中国科学院物理研究所)]
[36] Jang D C, Greer J R 2010 Nat. Mater. 9 215
[37] Lee D W, Zhao B G, Perim E, Zhang H T, Gong P, Gao Y L, Liu Y H, Toher C, Curtarolo S, Schroers J, Vlassak J J 2016 Acta Mater. 121 68
[38] Liu M, Cao C R, L Y M, Wang W H, Bai H Y 2017 Appl. Phys. Lett. 110 031901
[39] Hammock M L, Chortos A, Tee B C K, Tok J B H, Bao Z A 2013 Adv. Mater. 25 5997
[40] Xian H J, Cao C R, Shi J A, Zhu X S, Hu Y C, Huang Y F, Meng S, Gu L, Liu Y H, Bai H Y, Wang W H 2017 Appl. Phys. Lett. 111 121906
[41] Dresselhaus M S, Thomas I L 2001 Nature 414 332
[42] Turner J A 2004 Science 305 972
[43] Jaramillo T F, Jorgensen K P, Bonde J, Nielsen J H, Horch S, Chorkendorff I 2007 Science 317 100
[44] Hu Y C, Wang Y Z, Su R, Cao C R, Li F, Sun C W, Yang Y, Guan P F, Ding D W, Wang Z L, Wang W H 2016 Adv. Mater. 28 10293
[45] Silver D, Huang A, Maddison C J, Guez A, Sifre L, van den Driessche G, Schrittwieser J, Antonoglou I, Panneershelvam V, Lanctot M, Dieleman S, Grewe D, Nham J, Kalchbrenner N, Sutskever I, Lillicrap T, Leach M, Kavukcuoglu K, Graepel T, Hassabis D 2016 Nature 529 484
[46] Ghiringhelli L M, Vybiral J, Levchenko S V, Draxl C, Scheffler M 2015 Phys. Rev. Lett. 114 105503
[47] Raccuglia P, Elbert K C, Adler P D F, Falk C, Wenny M B, Mollo A, Zeller M, Friedler S A, Schrier J, Norquist A J 2016 Nature 533 73
[48] Cortes C, Vapnik V 1995 Mach. Learn. 20 273
[49] Sun Y T, Bai H Y, Li M Z, Wang W H 2017 J. Phys. Chem. Lett. 8 3434
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