超分子凝胶与介观结构

林乃波; 林友辉; 黄巧玲; 刘向阳

doi:10.7498/aps.65.174702

摘要

从介观结构角度综述了超分子凝胶晶体网络结构的形成机理、结构特性对宏观性能的影响以及超分子凝胶的设计与调控，系统总结了超分子凝胶的表征方法. 超分子凝胶的性能由层级结构决定，介观结构可大幅提高材料的宏观性能，其结构与性能可以通过四个因素相关联：拓扑结构，相关长度，对称性/有序性和晶体网络间的结合力. 基于对超分子凝胶的介观概念更深、更新的理解，该类材料的研究和开发将被推向新的阶段.

关键词:

From the perspective of mesoscale, the formation mechanism of crystal network structure of supramolecular gel, the influence of structure on macroscopic properties, and the design and control of supramolecular gels are reviewed Crystal network is a key character of the hierarchical structure of the gel, the formations of the basic and multi-level crystal networks are based on the crystal nucleation and growth. The engineering and controlling of the gel structure can be implemented by various stimuli, such as additives, sonication, seeding, and thermodynamic driving force, which leads to a controllable performance of the gel In addition, the methods of characterizing supramolecular gels are systematically summarized, such as, rheology, atomic force microscope, scanning tunnel microscope, scanning electron microscope, transmission electron microscope, polarizing optical microscope, X-ray diffraction, small-angle X-ray scattering, small-angle neutron scattering, nuclear magnetic resonance spectroscopy, dynamic light scattering etc. Supramolecular gel performance is determined by the hierarchy mesoscopic structures, which can significantly improve the properties of the material. Four factors can be correlated to the structure and performance of material: topology, correlation length, symmetry/ordering, and strength of association of crystal networks. According to the more in-depth understanding of mesoscopic supramolecular gels, the research and development of such a material will be pushed to a new stage.

Keywords:

作者及机构信息

1.
厦门大学材料学院, 物理科学与技术学院, 生物仿生及软物质研究院, 福建省柔性功能材料重点实验室, 厦门 361005;

2.
新加坡国立大学物理系, 新加坡 117542

通信作者: 刘向阳, phyliuxy@nus.edu.sg

基金项目: 111计划（批准号：B16029）、国家自然科学基金（批准号：21404087，U1405226 21401154）和国家高技术研究发展计划（批准号：2011AA06Z228）、福建省科技厅项目（批准号：2014H6022，2015J05109）、广东省自然科学基金（批准号：2015A030310007，2014A030310005）、中组部千人计划项目和厦门大学校长基金（批准号：20720160088，20720150218，20720140528）资助的课题.

Authors and contacts

1.
Research Institute for Biomimetics and Soft Matter, Fujian Provincial Key Laboratory for Soft Functional Materials Research, College of Mateirals, College of Physical Science and Technology, Xiamen University, Xiamen 361005, China;

2.
Department of Physics, National University of Singapore, 117542 Singapore

Corresponding author: Liu Xiang-Yang, phyliuxy@nus.edu.sg

Funds: Project supported by the 111 Project (Grant No. B16029), National Natural Science Foundation of China (Grant Nos. 21404087, U1405226, 21401154), the National High Technology Research and Development Program, China (Grant No.2011AA06Z228) Fujian Provincial Department of Science and Technology, China (Grant Nos. 2014H6022, 2015J05109), Natural Science Foundation of Guangdong Province, China (Grant Nos. 2015A030310007, 2014A030310005), 1000 Talents Program, and President Foundation from Xiamen University, China (Grant Nos. 20720160088, 20720150218, 20720140528).

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施引文献

[1]	Li J L, Liu X Y 2013 Soft Fibrillar Materials: fabrication and applications (Vol. 1) (Weinheim, Germany: Wiley-VCH Verlag GmbH Co. KGaA) p163
[2]	Hemminger J 2012 From Quanta to the Continuum: Opportunities for Mesoscale Science (Vol. 1) (U.S. Department of Energy: Basic Energy Sciences Advisory Committee)
[3]	Xu G, Gong L, Yang Z, Liu X 2014 Soft Matt. 10 2116
[4]	Lin N, Liu X Y 2015 Chem. Soc. Rev. 44 7881
[5]	Sangeetha N M, Maitra U 2005 Chem. Soc. Rev. 34 821
[6]	Foster J A, Steed J W 2010 Angew. Chem. Int. Ed. 49 6718
[7]	Yu G, Yan X, Han C, Huang F 2013 Chem. Soc. Rev. 42 6697
[8]	Xiong J Y, Liu X Y, Li J L, Vallon M W 2007 J. Phys. Chem. B 111 5558
[9]	Estroff L A, Hamilton A D 2004 Chem. Rev. 104 1201
[10]	Garlaschelli L, Ramaccini F, Delia Sala S 1991 Nature 353 507
[11]	Lipowitz A 1841 Justus Liebigs Ann. Chem. 38 348
[12]	Lin N, Toh G W, Feng Y, Liu X Y, Xu H 2014 J. Mater. Chem. B 2 2136
[13]	Seiffert S, Anthamatten M 2015 Supramolecular Polymer Networks and Gels (Vol. 268) (Switzerland: Springer) p1
[14]	Nguyen A T, Huang Q L, Yang Z, Lin N, Xu G, Liu X Y 2015 Small 11 1039
[15]	Li J L, Liu X Y 2009 J. Phys. Chem. B,113 15467
[16]	Liu X Y, Sawant P D, Tan W B, Noor I, Pramesti C, Chen B 2002 J. Am. Chem. Soc. 124 15055
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[19]	Liu X Y, Sawant P D 2002 Adv. Mater. 14 421
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[23]	Li J L, Liu X Y 2010 Adv. Funct. Mater. 20 3196
[24]	Xiong J Y, Liu X Y, Li J L, Vallon M W 2007 J. Phys. Chem. B 111 5558
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[32]	Wang R, Liu X Y, Xiong J, Li J 2006 J. Phys. Chem. B 110 7275
[33]	Strom C, Liu X Y, Wang M 2000 J. Phys. Chem. B 104 9638
[34]	Liu X Y, Strom C 2000 J. Chem. Phys. 113 4408
[35]	Diao Y Y, Liu X Y 2012 Adv. Funct. Mater. 22 1354
[36]	Liu X 2000 Langmuir 16 7337
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[40]	Yu R, Lin N, Yu W D, Liu X Y 2015 Cryst. Eng. Comm. 17 7986
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[42]	Liu X Y, 2005 Low Molecular Mass Gelators: Design, Self-Assembly, Function (Vol. 256) (Berlin: Springer) p1
[43]	Xiong J Y, Narayanan J, Liu X Y, Chong T K, Chen S B, Chung T S 2005 J. Phys. Chem. B 109 5638
[44]	Xiong J, Liu X, Li J, Narayanan J, Wang R 2006 Appl. Phys. Lett. 89 083106
[45]	Wang L J, Zhang L H 2007 Synthetic Technol. Appl. 22 43 (in Chinese) [王立君, 张丽华 2007 合成技术及应用 22 43]
[46]	Tang S, Liu X Y, Strom C S 2009 Adv. Funct. Mater. 19 2252
[47]	Hiemenz P C, Rajagopalan R 1997 Principles of Colloid and Surface Chemistry, Revised and Expanded (Vol. 14) (New York: CRC Press)
[48]	Lin X-Y, Creuzet F, Arribart H 1993 J. Phys. Chem. 97 7272
[49]	Huang X, Terech P, Raghavan S R, Weiss R G 2005 J. Am. Chem. Soc. 127 4336
[50]	Huang X, Raghavan S R, Terech P, Weiss R G 2006 J. Am. Chem. Soc. 128 15341
[51]	Lam R, Quaroni L, Pedersen T, Rogers M A 2010 Soft Matt. 6 404
[52]	Terech P, Wade R 1988 J. Colloid Interface Sci. 125 542
[53]	George S J, Ajayaghosh A 2005 Chemistry 11 3217
[54]	Abdallah D J, Weiss R G 2000 Langmuir 16 352
[55]	Sakurai K, Ono Y, Jung J H, Okamoto S, Sakurai S, Shinkai S 2001 Journal of the Chemical Society, Perkin Transactions 2 108
[56]	Sakurai K, Jeong Y, Koumoto K, Friggeri A, Gronwald O, Sakurai S, Okamoto S, Inoue K, Shinkai S 2003 Langmuir 19 8211
[57]	Jeong Y, Hanabusa K, Masunaga H, Akiba I, Miyoshi K, Sakurai S, Sakurai K 2005 Langmuir 21 586
[58]	Takeno H, Mochizuki T, Yoshiba K, Kondo S, Dobashi T 2009 Gels: Structures, Properties, and Functions (Vol. 136) (Berlin: Springer) pp47-53
[59]	Wilder E A, Hall C K, Spontak R J 2003 J. Colloid Interface Sci. 267 509
[60]	Wilder E A, Braunfeld M B, Jinnai H, Hall C K, Agard D A, Spontak R J 2003 J. Phys. Chem. B 107 11633
[61]	Xu D H, Wang Z G, Douglas J F 2008 Macromolecules 41 815
[62]	Schnablegger H, Singh Y 2013 The SAXS Guide (Vol. 1) (Austria: Anton Paar GmbH)
[63]	Weiss R G, Terech P 2006 Molecular Gels: Materials with Self-assembled Fibrillar Networks (Vol. 1) (Dordrecht: Springer) p1
[64]	Bouas-Laurent H, Desvergne J P 2006 Optical Spectroscopic Methods as Tools to Investigate Gel Structures (Vol. 1) (Amsteldam: Springer) p363
[65]	Kotova O, Daly R, dos Santos C M, Boese M, Kruger P E, Boland J J, Gunnlaugsson T 2012 Angew. Chem. Int. Ed. 51 7208
[66]	Liao X, Chen G, Liu X, Chen W, Chen F, Jiang M 2010 Angew. Chem. 122 4511
[67]	Liao X, Chen G, Liu X, Chen W, Chen F, Jiang M 2010 Angew. Chem. 122 4511
[68]	Feng Y D, Chen D B, Huang, G L 1991 Polym. Mater. Sci. Eng. 3 1 (in Chinese) [冯雨丁, 陈德本, 黄光琳 1991 高分子材料科学与工程 3 1]
[69]	Li J L, Liu X Y 2013 Soft Fibrillar Materials: Fabrication and Applications (Vol. 1) (Weinheim: Wiley-VCH Verlag GmbH Co. KGaA)
[70]	Chernov A A 1984 Modern Crystallography (Vol. 3) (New York: Springer) p1
[71]	Mutaftschiev B 1993 Handbook of Crystal Growth (Vol. (Amsterdam: North Holland) p189
[72]	Carretti E, Bonini M, Dei L, Berrie B H, Angelova L V, Baglioni P, Weiss R G 2010 Acc. Chem. Res. 43 751
[73]	Yuan B, Liu X Y, Li J L, Xu H Y 2011 Soft Matt. 7 1708
[74]	Du N, Yang Z, Liu X Y, Li Y, Xu H Y 2011 Adv. Funct. Mater. 21 772
[75]	Wu X, Liu X Y, Du N, Xu G, Li B 2009 Appl. Phys. Lett. 95 093703
[76]	Nguyen A T, Huang Q L, Yang Z, Lin N, Xu G, Liu X Y 2015 Small 11 1013
[77]	Dastidar P 2008 Chem. Soc. Rev. 37 2699
[78]	Wrthner F, Hanke B, Lysetska M, Lambright G, Harms G S 2005 Org. Lett. 7 967
[79]	Lan Y, Corradini M G, Weiss R G, Raghavan S R, Rogers M A 2015 Chem. Soc. Rev. 44 6035
[80]	Schenning A P, Benneker F B, Geurts H P, Liu X Y, Nolte R J 1996 J. Am. Chem. Soc. 118 8549
[81]	Liu X Y, Sawant P D 2002 Angew. Chem. Int. Ed. 114 3793
[82]	Zhan C, Wang J, Yuan J, Gong H, Liu Y, Liu M 2003 Langmuir 19 9440
[83]	Li J L, Liu X Y, Strom C S, Xiong J Y 2006 Adv. Mater. 18 2574
[84]	Hanabusa K, Matsumoto M, Kimura M, Kakehi A, Shirai H 2000 J. Colloid Interface Sci. 224 231
[85]	Makarević J, Jokić M, Perić B, Tomiić V, Kojić-Prodić B, Žinić M 2001 Chemistry 7 3328
[86]	Zhao C X, Wang H T, Li M 2014 Acta Phys.-Chim. Sin. 30 2197 (in Chinese) [赵呈孝, 王海涛, 李敏 2014 物理化学学报 30 2197]
[87]	Liu X Y 1994 Phys. Rev. E 49 583
[88]	Liu X Y, Bennema P 1993 Phys. Rev. E 48 2006
[89]	Liu X Y, Bennema P, Meijer L A, Couto M S 1994 Chem. Phys. Lett. 220 53
[90]	Liu X Y 1999 Phys. Rev. B 60 2810
[91]	Liu X Y 1995 J. Chem. Phys. 102 1373
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