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铁基非晶合金因高饱和磁化强度、高磁导率、低矫顽力和低损耗等优异的软磁性能而持续受到广泛关注。然而，目前针对非晶合金磁性的理论研究仍不完善，铁基非晶合金磁性能的结构本源尚未厘清，常难以充分解释其磁性行为。本文简要总结了近年来实验与计算研究中，铁基非晶结构与软磁性能，尤其是饱和磁化强度的关联机制等的研究进展。已有的研究工作主要集中在不同元素如何影响铁基非晶合金的电子结构、磁矩、饱和磁化强度等，缺乏对局域原子结构包括短程序、中程序结构影响磁矩等磁性能的微观机理的深入探索。本文试图为进一步深入系统地探索铁基非晶合金软磁性能的微观机理理清研究思路。Fe-based amorphous alloys have continuously attracted extensive attention due to their excellent soft magnetic properties, such as high saturation magnetization, high permeability, low coercivity, and low core loss. However, the theoretical studies on the magnetism of amorphous alloys remain incomplete, and the structural origins of the magnetic properties in Fe-based amorphous alloys are still unclear, making it difficult to fully explain their magnetic behavior. Accordingly, this review summarizes recent experimental and computational progress in exploring potential correlation mechanisms between amorphous structures and soft-magnetic properties. Existing research has primarily focused on how different elements affect the electronic structure, magnetic moment, saturation magnetization, and other properties of iron-based amorphous alloys. However, little effort has been devoted to the in-depth exploration into the underlying mechanisms of the local atomic structures, including short-range and medium-range order, influence magnetic properties. This review aims to provide a reference for further elucidating the structural origins of magnetic properties in Fe-based amorphous alloys, while also identifying key unresolved issues in future research.
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Keywords:
- Fe-based amorphous alloys /
- soft magnetism /
- structural origin /
- amorphous alloys
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