玻璃形成体系中的β弛豫

闻平

doi:10.7498/aps.66.176407

摘要

一定压强下对液体进行冷却，若避免晶化，则冷却中液体不可避免地转变为典型非晶态固体-玻璃.这种现象称为玻璃转变，是一种普遍存在的自然现象，涉及多体相互关联体系中众多基础理论问题.近几十年以来，玻璃转变问题的探索过程中，弛豫存在的普适性、其机理/物理图像及其对液体和玻璃性能认知的影响等一直是争论的热点.在梳理β弛豫研究进展的同时，本文尝试对未来β弛豫研究方向进行展望.

关键词:

As soon as crystallization is suspended at constant pressure, cooling liquids turn inevitably into rigid amorphous solids, i.e. glasses. The process is a universal phenomenon in nature, termed as glass transition involving many fundamental problems in many-body interaction system and material science. Among the decades research on the glass transition, the universality of β-relaxation, its mechanism and its effects on the understanding of liquids and glasses have been studied argumentatively. In this paper we review the research progress of β-relaxation and also try to point out the tendency of β-relaxation study in future.

Keywords:

作者及机构信息

闻平

1.
中国科学院物理研究所, 北京 100190

通信作者: 闻平, pwen@iphy.ac.cn

基金项目: 国家自然科学基金（批准号：50671118，51071170，11274353）资助的课题.

Authors and contacts

Wen Ping

1.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Wen Ping, pwen@iphy.ac.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 50671118, 51071170, 11274353).

参考文献

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[2]	Dougherty R C, Noward L N 1998 J. Chem. Phys. 109 7379
[3]	Stillinger F H 1980 Science 209 451
[4]	Keutsch F N, Saykally R J 2001 PNAS 98 10533
[5]	Angell C A 2008 Science 319 582
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[12]	Boehmer R, Ngai K L, Angell C A, Plazek D J 1993 J. Chem. Phys. 99 4201
[13]	Sastry S, Debenedett P G, Stillinger F H 1998 Nature 393 554
[14]	Berthier L, Biroli G 2011 Rev. Mod. Phys. 83 587
[15]	Martinez L M, Angell C A 2001 Nature 410 663
[16]	Donth E 2001 The Glass Transition (Berlin, Heidelberg: Springe-Verlag)
[17]	Johari G P, Goldstein M 1970 J. Chem. Phys. 53 2372
[18]	Ngai K L 2011 Relaxation and Diffusion in Complex Systems (New York, Dordrecht, Heidelberg, London: Springer)
[19]	Johari G P 1976 Ann. N.Y. Acad. Sci. 279 117
[20]	Tanaka H 2004 Phys. Rev. E 69 021502
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[31]	Hensel-Bielowka S, Paluch M 2002 Phys. Rev. Lett. 89 025704
[32]	Wen P, Zhao D Q, Pan M X, et al. 2004 Appl. Phys. Lett. 84 2790
[33]	Zhao Z F, Wen P, Shek C H, Wang W H 2007 Phys. Rev. B 75 174201
[34]	Zhao Z F, Wen P, Wang W H 2006 Appl. Phys. Lett. 89 071920
[35]	Wen P, Zhao Z F, Pan M X, Wang W H 2010 Phys. Status Solidi A 207 2693
[36]	Yu H B, Wang W H, Bai H Y, Wu Y, Chen M W 2010 Phys. Rev. B 81 220201
[37]	Yu H B, Wang Z, Wang W H, Bai H Y 2012 J. Non-Cryst. Solids 358 869
[38]	Wang Z, Yu H B, Wen P, Bai H Y, Wang W H 2011 J. Phys.-Condens. Matter 23 142202
[39]	Wang W H 2011 J. Appl. Phys. 110 053521
[40]	Yu H B, Shen X, Wang Z, Gu L, Wang W H, Bai H Y 2012 Phys. Rev. Lett. 108 015504
[41]	Yu H B, et al. 2014 National Sci. Rev. 0 1
[42]	Bartsch A, Raetzke K, Meyer A, Faupel F 2010 Phys. Rev. Lett. 104 195901
[43]	Yu H B, Samwer K, Wu Y, Wang W H 2012 Phys. Rev. Lett. 109 095508
[44]	Debenedetti P G, Stillinger F H 2001 Nature 410 259
[45]	Williams G, Watts D C 1971 Trans. Faraday Soc. 67 1971
[46]	Goldstein M 1975 J. Phys. Paris. Colloq. C2 C2
[47]	Johari G P 1983 Plastic Deformation of Amorphous and Semi-Crystalline Materials (France, Les Ullis: Les Edition de Physique)
[48]	Vogel M, Roessler E 2000 J. Phys. Chem. B 104 4285
[49]	Teixeira J, Bellissent-Funel M C, Chen S H, Dianoux A J 1985 Phys. Rev. A 31 1913
[50]	Ke H B, Wen P, Wang W H 2012 AIP Adv. 2 041404

施引文献

[1]	Iida T 1988 The Physical Properties of Liquid Metals (Oxford: Clarendon Press)
[2]	Dougherty R C, Noward L N 1998 J. Chem. Phys. 109 7379
[3]	Stillinger F H 1980 Science 209 451
[4]	Keutsch F N, Saykally R J 2001 PNAS 98 10533
[5]	Angell C A 2008 Science 319 582
[6]	Jäckle J 1986 Rep. Prog. Phys. 49 171
[7]	Dyre J C 2006 Rev. Mod. Phys. 78 953
[8]	Cohen M H, Turnbull D 1959 J. Chem. Phys. 31 1164
[9]	Dyre J C, Olsen N B, Christensen T 1996 Phys. Rev. B 53 2171
[10]	Adam G, Gibbs J H 1965 J. Chem. Phys. 43 139
[11]	Barra J L T, Goetze W, Latz A 1989 J. Phys. Condens. Matter 1 7163
[12]	Boehmer R, Ngai K L, Angell C A, Plazek D J 1993 J. Chem. Phys. 99 4201
[13]	Sastry S, Debenedett P G, Stillinger F H 1998 Nature 393 554
[14]	Berthier L, Biroli G 2011 Rev. Mod. Phys. 83 587
[15]	Martinez L M, Angell C A 2001 Nature 410 663
[16]	Donth E 2001 The Glass Transition (Berlin, Heidelberg: Springe-Verlag)
[17]	Johari G P, Goldstein M 1970 J. Chem. Phys. 53 2372
[18]	Ngai K L 2011 Relaxation and Diffusion in Complex Systems (New York, Dordrecht, Heidelberg, London: Springer)
[19]	Johari G P 1976 Ann. N.Y. Acad. Sci. 279 117
[20]	Tanaka H 2004 Phys. Rev. E 69 021502
[21]	Lunkenheimer P, Schneider U, Brand R, Loidl A 2000 Contemp. Phys. 41 15
[22]	Johari G P 2002 J. Non-Cryst. Solids 307-310 317
[23]	Tarjus G, Kivelson D 2000 J. Chem. Phys. 112 368
[24]	Ngai K L 1979 Comments Solid State Phys. 9 127
[25]	Ngai K L 2003 J. Phys. Condens. Matter 15 S1107
[26]	Schneider U, Brand R, Lunkenheimer P, Loidl A 2000 Phys. Rev. Lett. 84 5560
[27]	Ngai K L, Lunkenheimer P, Leoen C, Schneider U, Brand R, Loidl A 2001 J. Chem. Phys. 115 1405
[28]	Doeß A, Paluch M, Sillescu H, Hinze G 2002 Phys. Rev. Lett. 88 095701
[29]	Casalini R, Roland C M 2002 Phys. Rev. B 66 180201
[30]	Dixon P K, Wu L, Nagel S R, Williams B D, Carini J P 1990 Phys. Rev. Lett. 65 1108
[31]	Hensel-Bielowka S, Paluch M 2002 Phys. Rev. Lett. 89 025704
[32]	Wen P, Zhao D Q, Pan M X, et al. 2004 Appl. Phys. Lett. 84 2790
[33]	Zhao Z F, Wen P, Shek C H, Wang W H 2007 Phys. Rev. B 75 174201
[34]	Zhao Z F, Wen P, Wang W H 2006 Appl. Phys. Lett. 89 071920
[35]	Wen P, Zhao Z F, Pan M X, Wang W H 2010 Phys. Status Solidi A 207 2693
[36]	Yu H B, Wang W H, Bai H Y, Wu Y, Chen M W 2010 Phys. Rev. B 81 220201
[37]	Yu H B, Wang Z, Wang W H, Bai H Y 2012 J. Non-Cryst. Solids 358 869
[38]	Wang Z, Yu H B, Wen P, Bai H Y, Wang W H 2011 J. Phys.-Condens. Matter 23 142202
[39]	Wang W H 2011 J. Appl. Phys. 110 053521
[40]	Yu H B, Shen X, Wang Z, Gu L, Wang W H, Bai H Y 2012 Phys. Rev. Lett. 108 015504
[41]	Yu H B, et al. 2014 National Sci. Rev. 0 1
[42]	Bartsch A, Raetzke K, Meyer A, Faupel F 2010 Phys. Rev. Lett. 104 195901
[43]	Yu H B, Samwer K, Wu Y, Wang W H 2012 Phys. Rev. Lett. 109 095508
[44]	Debenedetti P G, Stillinger F H 2001 Nature 410 259
[45]	Williams G, Watts D C 1971 Trans. Faraday Soc. 67 1971
[46]	Goldstein M 1975 J. Phys. Paris. Colloq. C2 C2
[47]	Johari G P 1983 Plastic Deformation of Amorphous and Semi-Crystalline Materials (France, Les Ullis: Les Edition de Physique)
[48]	Vogel M, Roessler E 2000 J. Phys. Chem. B 104 4285
[49]	Teixeira J, Bellissent-Funel M C, Chen S H, Dianoux A J 1985 Phys. Rev. A 31 1913
[50]	Ke H B, Wen P, Wang W H 2012 AIP Adv. 2 041404

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