激光诱导击穿火焰等离子体光谱研究

刘玉峰; 张连水; 和万霖; 黄宇; 杜艳君; 蓝丽娟; 丁艳军; 彭志敏

doi:10.7498/aps.64.045202

摘要

采用PI-MAX-II型增强型电荷耦合器件, 用Nd:YAG纳秒脉冲激光器输出的1064 nm强光束击穿在一个大气压的空气中燃烧的酒精灯火焰, 对激光诱导击穿酒精灯火焰产生的等离子体光谱进行了初步研究. 根据美国国家标准与技术研究院原子发射谱线数据库, 对等离子体中的主要元素的特征谱线进行了标识和归属. 通过激光诱导击穿空气等离子体光谱、激光诱导击穿酒精灯火焰等离子体光谱、激光诱导酒精喷灯火焰等离子体光谱的对比分析, 发现不同燃烧状况下的光谱中各原子谱线的相对强度是不同的. 这些结果对于使用激光诱导击穿技术分析和研究碳氢燃料在空气中的燃烧特性具有重要的意义和参考价值, 同时也为将该技术应用于燃烧诊断提供了实验依据.

关键词:

Abstract

The emission spectra from a flame-breakdown atmospheric pressure plasma generated by a nanosecond pulsed 1064 nm beam of Nd:YAG laser are investigated by using a PI-MAX-II intensified charge coupled device. The emission lines of the main elements, such as carbon, hydrogen, oxygen and nitrogen are identified according to the national institute of standards and technology database of atomic emission. It is found that the relative intensities of the atomic emission lines are different from each other under different combustion conditions by making a comparative analysis of the spectra of laser induced breakdown air plasma, alcohol burner flame plasma, and alcohol blast burner flame plasma. The obtained results in this work provide an experimental basis for applying the laser-induced breakdown technology to the combustion diagnostics, and have an important reference and significance for analyzing the characteristics of hydrocarbon fuel combusting in air.

Keywords:

作者及机构信息

1.
清华大学热能工程系, 电力系统与发电设备控制与仿真国家重点实验室, 北京 100084;

2.
河北大学物理科学与技术学院, 保定 071002;

3.
华北电力大学控制与计算机工程学院, 保定 071003

基金项目: 国家自然科学基金(批准号: 51206086, 51176085)资助的课题.

Authors and contacts

1.
State Key Laboratory of Power Systems, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China;

2.
College of Physics Science and Technology, Hebei University, Baoding 071002, China;

3.
School of Control and Computer Engineering, North China Electric Power University, Baoding 071003, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51206086, 51176085).

参考文献

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[9]	Hahn D W, Flower W L, Henken K R 1997 Appl. Spectrosc. 51 1836
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[19]	Pichahchy A E, Cremers D A, Ferris M J 1997 Spectrochim. Acta Part B 52 25
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[21]	Blevins L G, Shaddix C R, Sickafoose S M, Walsh P M 2003 Appl. Opt. 42 6107
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[31]	Ferioli F, Buckley S G 2006 Combust. Flame 144 435
[32]	Phuoc T X, White F P 2002 Fuel 81 1761
[33]	Stavropoulos P, Michalakou A, Skevis G, Couris S 2005 Spectrochim. Acta B 60 1092
[34]	Stavropoulos P, Michalakou A, Skevis G, Couris S 2005 Chem. Phys. Lett. 404 309
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[36]	Robert J N 1995 Appl. Spectrosc. 49 1490
[37]	Li X Y, Lin Z X, Liu Y Y, Chen Y Q, Gong S S 2004 Acta Opt. Sin. 24 1051 (in Chinese) [李小银, 林兆祥, 刘煜炎, 陈扬锓, 龚顺生 2004 光学学报 24 1051]
[38]	Ding H L, Gao L X, Zheng H Y, Wang Y P, Huang T, Ding L, Zhang W J, Fang L 2010 Spectrosc. Spect. Anal. 30 l (in Chinese) [丁慧林, 高立新, 郑海洋, 王颖萍, 黄腾, 丁蕾, 张为俊, 方黎 2010 光谱学与光谱分析 30 l]
[39]	Lin Z X, Wu J Q, Gong S S 2006 Acta Phys. Sin. 55 5892 (in Chinese) [林兆祥, 吴金泉, 龚顺生 2006 55 5892]

施引文献

[1]	Lu C P, Liu W Q, Zhao N J, Liu L T, Chen D, Zhang Y J, Liu J G 2011 Acta Phys. Sin. 60 045206 (in Chinese) [鲁翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国 2011 60 045206]
[2]	Nakimana A, Tao H Y, Hao Z Q, Sun C K, Gao X, Lin J Q 2013 Chin. Phys. B 22 014209
[3]	Guo L B, Hao R F, Hao Z Q, Li K H, Shen M, Ren Z, Li X Y, Zeng X Y 2013 Acta Phys. Sin. 62 224211 (in Chinese) [郭连波, 郝荣飞, 郝中骐, 李阔湖, 沈萌, 任昭, 李祥友, 曾晓雁 2013 62 224211]
[4]	Miziolek A, Palleschi V, Schechter I 2006 Laser-Induced Breakdown Spectroscopy (LIBS): Fundamentals and Applications (Cambridge: Cambridge University Press) pp257-290
[5]	Singh J P, Thakur S N 2007 Laser-Induced Breakdown Spectroscopy (New York: Elsevier) pp10-15
[6]	Cremers D A, Radziemski L J 2007 Handbook of Laser-Induced Breakdown Spectroscopy (New York: Wiley) pp36-42
[7]	Rusak D A, Castle B C, Smith B W, Winefordner J D 1997 Crit. Rev. Anal. Chem. 27 257
[8]	Zhang H, Yueh F Y, Singh J P 1999 Appl. Opt. 38 1459
[9]	Hahn D W, Flower W L, Henken K R 1997 Appl. Spectrosc. 51 1836
[10]	Zhang H, Singh J P, Yueh F Y, Cook R L 1995 Appl. Spectrosc. 49 1617
[11]	Michalakou A, Stavropoulos P, Couris S 2008 Appl. Phys. Lett. 92 081501
[12]	Cremers D A, Radziemski L J 1983 Anal. Chem. 55 1252
[13]	Radziemski L J, Loree T R, Cremers D A, Hoffman N M 1983 Anal. Chem. 55 1246
[14]	Sturm V, Peter L, Noll R 2000 Appl. Spectrosc. 54 1275
[15]	Cabalín L M, Laserna J J 1998 Spectrochim. Acta Part B 53 723
[16]	Sattmann R, Monch I, Krause H, Noll R, Couris S, Hatziapostolou A, Mavromanolakis A, Fotakis C, Larrauri E, Miguel R 1998 Appl. Spectrosc. 52 456
[17]	Gornushkin I B, Anzano J M, King L A, Smith B W, Omenetto N, Winefordner J D 1999 Spectrochim. Acta Part B 54 491
[18]	Cremers D A, Radziemski L J, Loree T R 1984 Appl. Spectrosc. 38 721
[19]	Pichahchy A E, Cremers D A, Ferris M J 1997 Spectrochim. Acta Part B 52 25
[20]	Hanafi M, Omar M M, Gamal Y E E D 2000 Radiat. Phys. Chem. 57 11
[21]	Blevins L G, Shaddix C R, Sickafoose S M, Walsh P M 2003 Appl. Opt. 42 6107
[22]	Lithgow G A, Robinson A L, Buckley S G 2004 Atmos. Environ. 38 3319
[23]	Kiefer J, Tröger J W, Seeger T, Leipertz A, Li B, Li Z S, Aldén M 2010 Meas. Sci. Technol. 21 065303
[24]	Kiefer J, Li Z S, Aldén M 2013 Meas. Sci. Technol. 24 075205
[25]	Tripathi M M, Srinivasan K K, Krishnan S R, Yueh F Y, Singh J P 2013 Fuel 106 318
[26]	Kiefer J, Tröger J W, Li Z S, Aldén M 2011 Appl. Phys. B 103 229
[27]	Einecke S, Schulz C, Sick V 2000 Appl. Phys. B 71 717
[28]	Ma L, Sanders S T, Jeffries J B, Hanson R K 2003 Proc. Combust. Inst. 29 161
[29]	Hoinghaus K K, Jeffries J B 2002 Applied Combustion Diagnostics (New York: Taylor and Francis) pp15-28
[30]	Ferioli F, Puzinauskas P V, Buckley S G 2003 Appl. Spectrosc. 57 1183
[31]	Ferioli F, Buckley S G 2006 Combust. Flame 144 435
[32]	Phuoc T X, White F P 2002 Fuel 81 1761
[33]	Stavropoulos P, Michalakou A, Skevis G, Couris S 2005 Spectrochim. Acta B 60 1092
[34]	Stavropoulos P, Michalakou A, Skevis G, Couris S 2005 Chem. Phys. Lett. 404 309
[35]	Lin Z X, Li X Y, Cheng X W, Li F Q, Gong S S 2003 Spectrosc. Spect. Anal. 23 421 (in Chinese) [林兆祥, 李小银, 程学武, 李发泉, 龚顺生 2003 光谱学与光谱分析 23 421]
[36]	Robert J N 1995 Appl. Spectrosc. 49 1490
[37]	Li X Y, Lin Z X, Liu Y Y, Chen Y Q, Gong S S 2004 Acta Opt. Sin. 24 1051 (in Chinese) [李小银, 林兆祥, 刘煜炎, 陈扬锓, 龚顺生 2004 光学学报 24 1051]
[38]	Ding H L, Gao L X, Zheng H Y, Wang Y P, Huang T, Ding L, Zhang W J, Fang L 2010 Spectrosc. Spect. Anal. 30 l (in Chinese) [丁慧林, 高立新, 郑海洋, 王颖萍, 黄腾, 丁蕾, 张为俊, 方黎 2010 光谱学与光谱分析 30 l]
[39]	Lin Z X, Wu J Q, Gong S S 2006 Acta Phys. Sin. 55 5892 (in Chinese) [林兆祥, 吴金泉, 龚顺生 2006 55 5892]

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