Xe离子束辐照硼硅酸盐玻璃和石英玻璃效应对比研究

彭海波; 刘枫飞; 张冰焘; 张晓阳; 孙梦利; 杜鑫; 王鹏; 袁伟; 王铁山; 王建伟

doi:10.7498/aps.67.20172117

摘要

玻璃固化体作为放射性废物地质处置的第一道安全屏障，它的耐辐照性能研究至关重要.玻璃固化体主要网络结构硅氧四面体与石英玻璃的硅氧四面体是一致的，所以这里用石英玻璃代替玻璃固化体作为研究对象.本文采用Xe离子在相同条件下辐照石英玻璃和硼硅酸盐玻璃.利用纳米压痕技术和椭圆偏振仪表征了辐照前后样品的硬度、模量以及折射率的变化情况.结果表明：硼硅酸盐玻璃和石英玻璃的硬度均随着辐照剂量的增大而减小，硼硅酸盐玻璃的模量随着辐照剂量的增大而减小；石英玻璃的模量随着辐照剂量的增大而增大.模量的变化可能和密度的变化有关，这点与折射率的结果相符.

关键词:

Abstract

As the first safety barrier of high level radioactive waste, the tolerance to radiation of vitrification is critical. Vitrification is a kind of specialized glass used as the package of high-level radioactive waste in nuclear power industry. Because of its structural consistency with the main structure of vitrification (silicon-oxygen tetrahedron), fused silica is used to study the irradiation effect on network of vitrification in the present study. Borosilicate glass, a simplified version of vitrification, is studied under the same conditions for comparison. Hardness values, moduli and refractive indexes of fused silica and borosilicate glass are measured before and after irradiation with nanoindentation technology and elliptic polarization instrument. It is shown in this study that the hardness values of fused silica and borosilicate glass decrease with increasing dose. On the other hand, with dose increasing, the modulus of borosilicate glass decreases but the modulus of silica increases. Change in modulus might be attributed to the change of density, which is consistent with results from the refractive index.

Keywords:

作者及机构信息

1.
兰州大学核科学与技术学院, 兰州 730000;

2.
兰州大学物理科学与技术学院, 兰州 730000;

3.
中国工程物理研究院微系统与太赫兹中心, 成都 610200

通信作者: 王建伟, wangjianwei@mtrc.ac.cn

基金项目: 国家自然科学基金（批准号：11505085，11505086）和兰州大学教学研究项目基金（批准号：201621）资助的课题.

Authors and contacts

1.
School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, China;

2.
School of Physics Science and Technology, Lanzhou University, Lanzhou 730000, China;

3.
Microsystem and Terahertz Research Center, China Academy of Engineering Physics, Chengdu 610200, China

Corresponding author: Wang Jian-Wei, wangjianwei@mtrc.ac.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 11505085, 11505086) and the Teaching Research Project Foundation of Lanzhou University, China (Grant No. 201621).

参考文献

[1]	Weber W J, Matzke H, Routort J L 1984 J. Mater. Sci. 19 2533
[2]	Weber W J 1988 Nucl. Instrum. Meth. B 32 471
[3]	Weber W J, Ewing R C, Angell C A, Arnold G W, Cormack A N, Delaye J M, Griscom D L, Hobbs L W, Navrotsky A, Price D L, Stoneham A M, Weinberg M C 1997 J. Mater. Res. 12 1948
[4]	Peuget S, Fares T, Maugeri E A, Caraballo R, Charpentier T, Martel L, Somers J, Janssen A, Wiss T, Rozenblum F, Magnin M, Deschanels X, Jgou C 2014 Nucl. Instrum. Meth. B 327 22
[5]	Peuget S, Nol P Y, Loubet J L, Pavan S, Nivet P, Chenet A 2006 Nucl. Instrum. Meth. B 246 379
[6]	Peuget S, Delaye J M, Jgou C 2014 J. Nucl. Mater. 444 76
[7]	Peuget S, Broudic V, Jgou C, Frugier P, Roudil D, Deschanels X, Rabiller H, Noel P 2007 J. Nucl. Mater. 362 474
[8]	Ollier N, Champagnon B, Boizot B, Guyot Y, Panczer G, Padlyak B 2003 J. Non-Cryst. Solids 323 200
[9]	Ollier N, Boizot B, Reynard B, Ghaleb D, Petite G 2005 J. Nucl. Mater. 340 209
[10]	Ollier N, Boizot B, Reynard B, Ghaleb D, Petite G 2004 Nucl. Instrum. Meth. B 218 176
[11]	Mohapatra M, Kadam R M, Mishra R K, Kaushik C P, Tomar B S, Godbole S V 2011 Physica B 406 3980
[12]	Mohapatra M, Kadam R M, Mishra R K, Dutta D, Pujari P K, Kaushik C P, Kshirsagar R J, Tomar B S, Godbole S V 2011 Nucl. Instrum. Meth. B 269 2057
[13]	Mohapatra M, Manchanda V K 2009 IOP Conf. Ser.: Mater. Sci. Eng. 2 012022
[14]	Yang K J, Wang T S, Zhang G F, Peng H B, Chen L, Zhang L M, Li C X, Tian F, Yuan W 2013 Nucl. Instrum. Meth. B 307 541
[15]	Zhang G F, Wang T S, Yang K J, Chen L, Zhang L M, Peng H B, Yuan W, Tian F 2013 Nucl. Instrum. Meth. B 316 218
[16]	Chen L, Wang T S, Yang K J, Peng H B, Zhang G F, Zhang L M, Jiang H, Wang Q 2013 Nucl. Instrum. Meth. B 307 566
[17]	Chen L, Yuan W, Nan S, Du X, Zhang D F, L P, Peng H B, Wang T S 2016 Nucl. Instrum. Meth. B 370 42
[18]	Peng H B, Sun M L, Yang K J, Chen H, Yang D, Yuan W, Chen L, Duan B H, Wang T S 2016 J. Non-Cryst. Solids 443 143
[19]	Wang T S, Duan B H, Tian F, Peng H B, Chen L, Zhang L M, Yuan W 2015 Chin. Phys. B 24 076102
[20]	Wang T S, Du X, Yuan W, Duan B H, Zhang J D, Chen L, Peng H B, Yang D, Zhang G F, Zhu Z H 2016 Surf. Coat. Technol. 306 245
[21]	Karakurt G, Abdelouas A, Guin J P, Nivard M, Sauvage T, Paris M, Bardeau J F 2016 J. Nucl. Mater. 475 243
[22]	Inagaki Y, Furuya H, Idemitsu K, Banba Y, Matsumoto S, Muraoka S 1991 Mater. Res. Soc. Symp. Proc. 257 199
[23]	Mir A H, Monnet I, Toulemonde M, Bouffard S, Jegou C, Peuget S 2016 J. Nucl. Mater. 469 244
[24]	Mir A H, Toulemonde M, Jegou C, Miro S, Serruys Y, Bouffard S, Peuget S 2016 Sci. Rep. 6 30191
[25]	Routbort J L, Matzke H 1983 J. Mater. Sci. Eng. 58 229
[26]	Joslin D L, Oliver W C 1990 J. Mater. Res. 5 123
[27]	Zhu D R, Lai T S 1997 Acta Sci. Natur. Univ. 36 31 (in Chinese) [朱德瑞, 赖天树 1997 中山大学学报 (自然科学版) 36 31]
[28]	Peng H, Sun M, Du X, Yuan W, Yang D, Chen L, Duan B, Wang T 2017 Nucl. Instrum. Meth. B 406 561
[29]	Peuget S, Cachia J N, Jgou C, Deschanels X, Roudil D, Broudic V, Delaye J M, Bart J M 2006 J. Nucl. Mater. 354 1
[30]	Arndt J, Devine R A B, Revesz A G 1991 J. Non-Cryst. Solids 131-133 1206
[31]	Arndt J, Stffler D 1969 Phys. Chem. Glasses 10 117
[32]	Makishima A, Mackenzie J 1973 J. Non-Cryst. Solids 12 35
[33]	Chi Y S, Shen J Y, Chen X X, Miu Z X 2002 J. Inorg. Mater. 17 475 (in Chinese) [迟玉山, 沈菊云, 陈学贤, 缪之训 2002 无机材料学报 17 475]

施引文献

[1]	Weber W J, Matzke H, Routort J L 1984 J. Mater. Sci. 19 2533
[2]	Weber W J 1988 Nucl. Instrum. Meth. B 32 471
[3]	Weber W J, Ewing R C, Angell C A, Arnold G W, Cormack A N, Delaye J M, Griscom D L, Hobbs L W, Navrotsky A, Price D L, Stoneham A M, Weinberg M C 1997 J. Mater. Res. 12 1948
[4]	Peuget S, Fares T, Maugeri E A, Caraballo R, Charpentier T, Martel L, Somers J, Janssen A, Wiss T, Rozenblum F, Magnin M, Deschanels X, Jgou C 2014 Nucl. Instrum. Meth. B 327 22
[5]	Peuget S, Nol P Y, Loubet J L, Pavan S, Nivet P, Chenet A 2006 Nucl. Instrum. Meth. B 246 379
[6]	Peuget S, Delaye J M, Jgou C 2014 J. Nucl. Mater. 444 76
[7]	Peuget S, Broudic V, Jgou C, Frugier P, Roudil D, Deschanels X, Rabiller H, Noel P 2007 J. Nucl. Mater. 362 474
[8]	Ollier N, Champagnon B, Boizot B, Guyot Y, Panczer G, Padlyak B 2003 J. Non-Cryst. Solids 323 200
[9]	Ollier N, Boizot B, Reynard B, Ghaleb D, Petite G 2005 J. Nucl. Mater. 340 209
[10]	Ollier N, Boizot B, Reynard B, Ghaleb D, Petite G 2004 Nucl. Instrum. Meth. B 218 176
[11]	Mohapatra M, Kadam R M, Mishra R K, Kaushik C P, Tomar B S, Godbole S V 2011 Physica B 406 3980
[12]	Mohapatra M, Kadam R M, Mishra R K, Dutta D, Pujari P K, Kaushik C P, Kshirsagar R J, Tomar B S, Godbole S V 2011 Nucl. Instrum. Meth. B 269 2057
[13]	Mohapatra M, Manchanda V K 2009 IOP Conf. Ser.: Mater. Sci. Eng. 2 012022
[14]	Yang K J, Wang T S, Zhang G F, Peng H B, Chen L, Zhang L M, Li C X, Tian F, Yuan W 2013 Nucl. Instrum. Meth. B 307 541
[15]	Zhang G F, Wang T S, Yang K J, Chen L, Zhang L M, Peng H B, Yuan W, Tian F 2013 Nucl. Instrum. Meth. B 316 218
[16]	Chen L, Wang T S, Yang K J, Peng H B, Zhang G F, Zhang L M, Jiang H, Wang Q 2013 Nucl. Instrum. Meth. B 307 566
[17]	Chen L, Yuan W, Nan S, Du X, Zhang D F, L P, Peng H B, Wang T S 2016 Nucl. Instrum. Meth. B 370 42
[18]	Peng H B, Sun M L, Yang K J, Chen H, Yang D, Yuan W, Chen L, Duan B H, Wang T S 2016 J. Non-Cryst. Solids 443 143
[19]	Wang T S, Duan B H, Tian F, Peng H B, Chen L, Zhang L M, Yuan W 2015 Chin. Phys. B 24 076102
[20]	Wang T S, Du X, Yuan W, Duan B H, Zhang J D, Chen L, Peng H B, Yang D, Zhang G F, Zhu Z H 2016 Surf. Coat. Technol. 306 245
[21]	Karakurt G, Abdelouas A, Guin J P, Nivard M, Sauvage T, Paris M, Bardeau J F 2016 J. Nucl. Mater. 475 243
[22]	Inagaki Y, Furuya H, Idemitsu K, Banba Y, Matsumoto S, Muraoka S 1991 Mater. Res. Soc. Symp. Proc. 257 199
[23]	Mir A H, Monnet I, Toulemonde M, Bouffard S, Jegou C, Peuget S 2016 J. Nucl. Mater. 469 244
[24]	Mir A H, Toulemonde M, Jegou C, Miro S, Serruys Y, Bouffard S, Peuget S 2016 Sci. Rep. 6 30191
[25]	Routbort J L, Matzke H 1983 J. Mater. Sci. Eng. 58 229
[26]	Joslin D L, Oliver W C 1990 J. Mater. Res. 5 123
[27]	Zhu D R, Lai T S 1997 Acta Sci. Natur. Univ. 36 31 (in Chinese) [朱德瑞, 赖天树 1997 中山大学学报 (自然科学版) 36 31]
[28]	Peng H, Sun M, Du X, Yuan W, Yang D, Chen L, Duan B, Wang T 2017 Nucl. Instrum. Meth. B 406 561
[29]	Peuget S, Cachia J N, Jgou C, Deschanels X, Roudil D, Broudic V, Delaye J M, Bart J M 2006 J. Nucl. Mater. 354 1
[30]	Arndt J, Devine R A B, Revesz A G 1991 J. Non-Cryst. Solids 131-133 1206
[31]	Arndt J, Stffler D 1969 Phys. Chem. Glasses 10 117
[32]	Makishima A, Mackenzie J 1973 J. Non-Cryst. Solids 12 35
[33]	Chi Y S, Shen J Y, Chen X X, Miu Z X 2002 J. Inorg. Mater. 17 475 (in Chinese) [迟玉山, 沈菊云, 陈学贤, 缪之训 2002 无机材料学报 17 475]

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