NiTi形状记忆合金形变机制的应变率相关性研究

刘洪涛; 孙光爱; 王沿东; 陈波; 汪小琳

doi:10.7498/aps.62.186201

摘要

利用高速拉伸实验机在宽的应变率范围内(0.001–1200 s-1), 研究了NiTi形状记忆合金的宏观力学性能随应变率的变化规律, 并借助透射电子显微镜深入研究了微观结构在不同应变率下的演变机制. 研究发现: NiTi合金马氏体(B19’相)孪晶的解孪晶应力随应变率的升高而近乎线性增大, 表明NiTi 合金解孪晶应力具有正向应变率相关性. 在拉伸应变率为10 s-1的样品微观结构中发现了大量的解孪晶区域, 而当应变率进一步增大到100 s-1和 1200 s-1时, 在样品中没有发现解孪晶区域的存在, 样品微观组织以孪晶形式存在. 该结果表明, NiTi合金的马氏体解孪晶速率应在 10–100 s-1范围内. 在高应变率下(≥qslant10 s-1)均发现了热引发奥氏体相(B2)的存在, 表明随应变率的增加, 拉伸过程由等温过程逐渐变为绝热过程. 此外, 在1200 s-1 的样品差示扫描热量曲线中还发现了一个小肩峰, 表明相变过程由一步相变变为两步相变.

关键词:

Abstract

In the NiTi shape memory alloys (SMAs), the macro-mechanical deformations and the microstructural evolutions at different strain-rates (0.001-1200 s-1) are investigated. It is found that the detwinning stress of martensitic twin increases with strain-rate increasing, which indicates that the detwinning stress has the positive strain-rate dependence. A large number of detwinning regions are found in the NiTi specimen which is deformed at the strain-rate of 10 s-1 under tension. However, with the strain-rate further increasing up to 100 s-1 and 1200 s-1, no detwinning region is observed and many twins still exist. It is shown that the detwinning rates of martensitic twin in NiTi SMAs are in a range of 10-100 s-1. Simultaneously, thermally-induced austenite is detected in the NiTi specimens deformed at high strain-rates (≥qslant10 s-1). It is ascribed to the fact that there is a change from the isothermal process to the adiabatic process when the tensile strain-rate goes up to a critical value. Additionally, a small shoulder peak is detected in differential scanning calorimeter peak of 1200 s-1 strain-rate specimen, indicating that the two-stage phase transformation occurs.

Keywords:

作者及机构信息

1.
东北大学, 材料各向异性与织构教育部重点实验室, 沈阳 110819;

2.
中国工程物理研究院, 中子物理学重点实验室, 核物理与化学研究所, 绵阳 621900

基金项目: 国家自然科学基金(批准号:91126001,11105128,51001024)和中国工程物理研究院科学技术发展基金(批准号:2010A0103002)资助的课题.

Authors and contacts

1.
Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education, Northeastern University, Shenyang 110819, China;

2.
Key Laboratory for Neutron Physics of Chinese Academy of Engineering Physics, Institute of Nuclear Physics and Chemistry, Mianyang 621900, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 91126001, 11105128, 51001024) and the Science and Technology Foundation of Chinese Academy of Engineering Physics (Grant No. 2010A0103002).

参考文献

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施引文献

[1]	Tsoi K A, Stalmans R, Schrooten J, Wevers M, Mai Y W 2003 Mater. Sci. Eng. A 342 207
[2]	Dolce M, Cardone D, Marnetto R 2000 Earthq. Eng. Struct. Dyn. 29 945
[3]	Zi-xue Q, Xing-tian Y, Jiang Y, Costas S 2006 Smart Mater. Struct. 15 1047
[4]	Liu Y, Li Y, Xie Z, Ramesh K T 2002 Philos. Mag. Lett. 82 511
[5]	Chang B C, Shaw J, Iadicola M 2006 Continuum Mech. Thermodyn. 18 83
[6]	Li H, Mao C, Ou J 2005 J. Mater. Civ. Eng. 17 676
[7]	Schmidt I 2006 J. Eng. Mater. Technol. 128 279
[8]	Shaw J A, Kyriakides S 1995 J. Mech. Phys. Solids 43 1243
[9]	Tobushi H, Shimeno Y, Hachisuka T, Tanaka K 1998 Mech. Mater. 30 141
[10]	Tobushi H, Takata K, Shimeno Y, Nowacki W K, Gadaj S P 1999 J. Mater. Des. Appl. 213 93
[11]	Chen W W, Wu Q, Kang J H, Winfree N A 2001 Int. J. Solids Struct. 38 8989
[12]	Liu Y, Li Y, Ramesh K T 2002 Philos. Mag. A 82 2461
[13]	Liu Y, Humbeeck Jv, Li Y, Ramesh K T 1999 Scripta Mater. 41 89
[14]	Liu Y, Xie Z, van Humbeeck J 1999 Mater. Sci. Eng. A 273-275 673
[15]	Nemat-Nasser S, Choi J Y, Guo W G, Isaacs J B 2005 Mech. Mater. 37 287
[16]	Nemat-Nasser S, Choi J Y 2005 Acta Mater. 53 449
[17]	Kolsky H 1949 Proc. Phys. Soc. London. Sect. B 62 676
[18]	Xu X, Thadhani N N 2001 Scripta Mater. 44 2477
[19]	Liu H T, Sun G A, Wang Y D, Chen B, Wang X L 2013 Acta Phys. Sin. 62 018103 (in Chinese) [刘洪涛, 孙光爱, 王沿东, 陈波, 汪小琳 2013 62 018103]
[20]	Liu H C, Wu S K, Chou T S 1991 Acta Metall. Mater. 39 2069
[21]	Nakayama H, Tsuchiya K, Umemoto M 2001 Scripta Mater. 44 1781
[22]	Carroll M C, Somsen C, Eggeler G 2004 Scripta Mater. 50 187

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