Li+和Er3+掺杂对Ba2SiO4：Eu2+发光性能的影响

罗林龄; 唐科; 朱达川; 韩涛; 赵聪

doi:10.7498/aps.62.157802

摘要

采用化学沉淀法一次煅烧工艺制备了Ba1.99-x/2-2ySiO4:Eu0.012+, Lix+y2+, Euy3+绿色荧光粉, 用X射线衍射仪和荧光分光光度计对样品的晶体结构、发光性能进行表征. 结果表明: 少量Eu2+, Li+和Er3+的共掺杂没有改变晶体结构; 其激发光谱分布在270440 nm波长范围, 谱峰位于288 nm, 360 nm处, 可以被InGaN 管芯产生的360410 nm辐射有效激发; 在360 nm近紫外光激发下, 测得其发射光谱峰值在500 nm 处, 是Eu2+4f65d14f7跃迁的典型发射; 荧光粉发光强度随着Li+掺杂量的增大先增强, 后减弱, 当x=0.1时, 发光强度最大; 随着Li+, Er3+共掺杂量的增加(y=0.012), 出现位于530 nm和488 nm的发射峰, 对应于Er3+的2H11/24I15/2和4F7/24I15/2特征发射, 同时分析了Eu2+Er3+的能量传递过程.

关键词:

Abstract

A series of Ba1.99-x/2-2ySiO4:Eu0.012+, Lix+y2+, Euy3+ green phosphors were synthesized by one-step calcination process with precursor prepared by chemical precipitation. X-ray diffraction (XRD) and fluorescence spectrophotometry were employed to characterize the crystal structure and luminescent properties, respectively. The results show that co-doping of Eu2+, Li+ or Er3+ do not change the crystal structure. The excitation band of green phosphors Ba1.99-x/2-2ySiO4:Eu0.012+, Lix+y2+, Euy3+ extends from 270 to 440 nm, with peaks appearing around 288 and 360 nm, thus the phosphors can be excited effectively by InGaN chip which produces ultraviolet light in the range of 350410 nm. The emission spectrum excited by 360 nm shows a characteristic wide band with a peak at about 500 nm, which can be attributed to the typical 4f65d14f7 transition emission of Eu2+. The emission spectrum intensity of Ba1.99-x/2SiO4:Eu0.012+, Lix2+ first increases with increasing Li+ doping concentration, and then decreases. The strongest emission intensity occars when Li+ doping concentration is 0.1. Two additional peaks appear in the emission spectrum of Ba1.99-x/2-2ySiO4:Eu0.012+, Lix+y2+, Euy3+ green phosphors around 488 nm and 530~nm separately when the phosphors are co-doped with Li+ and Er3+ from 0 to 0.012, which are attributed to the 4F7/24I15/2 and 2H11/24I15/2 translation emission of Er3+, the energy transfer effect from Eu2+ to Er3+ is also analyzed.

Keywords:

作者及机构信息

1.
四川大学材料科学与工程学院, 成都 610065;

2.
成都理工大学地球物理学院, 成都 610059;

3.
重庆文理学院材料交叉学科研究中心, 重庆 402168

基金项目: 重庆市科技攻关计划(批准号: 2009AB4171)和重庆市教育委员会科学技术研究基金(批准号: KJ111201)资助的课题.

Authors and contacts

1.
College of Materials Science and Engineering, Sichuan University, Chengdu 610065, China;

2.
Chengdu University of Technology, College of Geophysics, Chengdu 610059, China;

3.
Research Center for Material Interdisciplinary Science, Chongqing University of Arts and Sciences, Chongqing 402168, China

Funds: Project supported by the Science and Technology Key Program of Chongqing, China (Grant No. 2009AB4171), and the Science and Technology Research Foundation of the Education Committee of Chongqing, China (Grant No. KJ111201).

参考文献

[1]	Nakamura S, Mukai T, Senoh M 1994 J. Appl. Phys. 76 8189
[2]	Cao S X, Han T, Tu M J 2011 Acta Phys. Sin. 60 127802 (in Chinese) [曹仕秀, 韩涛, 涂铭旌 2011 60 127802]
[3]	Zhao C, Ma M X, Han T, Cao S X, Zhu D C 2011 Chin. J. Lumin. 32 1099 (in Chinese) [赵聪, 马明星, 韩涛, 曹仕秀, 朱达川 2011 发光学报 32 1099]
[4]	Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 55 4946]
[5]	Luo H B 2010 MS Dissertation (Zhejiang: Zhejiang University) (in Chinese) [罗海滨 2010 硕士学位论文 (浙江: 浙江大学)]
[6]	Ma M X, Zhu D C, Tu M J 2009 Acta Phys. Sin. 58 5826 (in Chinese) [马明星, 朱达川, 涂铭旌 2009 58 5826]
[7]	Yang Z P, Song Y C, Han Y, Zhao Q, Zhou D Z, Pan F 2012 J. Chin. Rare Earths Soc. 30 47 (in Chinese) [杨志平, 宋延春, 韩月, 赵青, 周东站, 潘飞 2012 中国稀土学报 30 47]
[8]	Birkel A, DeCino N A, George N C, Hazelton K A, Hong B, Seshadri R 2013 Solid State Sci. 19 51
[9]	Huang Z, Chen Y J, Chen L, Xie Y, Xiao L J, Yang Y 2013 Ceram. Int. 39 2709
[10]	Han J K, Hannah M E, Piquette A, Micone J, Hirata G A, Talbot J B, Mishra K C, McKittrick J 2013 J. Lumin. 133 184
[11]	Song G L, Sun K X 2006 Spectrosc. Spect. Anal. 26 1806 (in Chinese) [宋国利, 孙凯霞 2006 光谱学与光谱分析 26 1806]
[12]	Kim J S, Jeon P E, Choi J C, Park H L 2005 Solid State Commun. 133 187
[13]	Liu H L, Guo S, Hao Y Y, Wang H, Xu B S 2012 J. Lumin. 132 2908
[14]	Yang J L, Wang Z 2010 J.Chin.Rare Earths soc. 28 536 (in Chinese) [杨继兰, 王卓 2010 中国稀土学报 28 536 ]
[15]	Zhang M, Wang J, Zhang Q H, Ding W J, Su Q 2007 Mater. Res. Bull. 42 33
[16]	Zhong D, Hu X Y, Li Z H, Li Y X 2009 J. Chin. Rare Earths soc. 27 36 (in Chinese) [钟丹, 胡小野, 李振华, 李永绣 2009 中国稀土学报 27 36]
[17]	Ma M X, Zhu D C, Tu M J 2009 Acta Phys. Sin. 58 6512 (in Chinese) [马明星, 朱达川, 涂铭旌 2009 58 6512]
[18]	Pu Y, Zhu D C, Han T 2012 Chin. J. Lumin. 33 12 (in Chinese) [蒲勇, 朱达川, 韩涛 2012 发光学报 33 12]
[19]	Sugiyama M, Fujimoto Y, Yanagida T, Totsuka D, Kurosawa S, Futami Y,Yokota Y, Chani V, Yoshikawa A 2012 Nucl. Instrum. Methods Phys. Res. Sect. A 664 127
[20]	Kumar G A, Pokhrel M, Sardar D K 2012 Mater. Lett. 68 395
[21]	Kumar G A, Pokhrel M, Martinez A, Dennis R C, Villegas I L, Sardar D K 2012 J. Alloys. Compd. 513 559
[22]	Raju G S R, Park J Y, Jung H C, Pavitra E, Moon B K, Jeong J H, Yu J S, Kim J H, Choi H 2011 J.Alloys. Compd. 509 7537
[23]	Zhu F, Xiao Z S, Yan L, Zhang F, Zhong K, Cheng G A 2009 Nucl.Instrum.Methods Phys. Res. Sect. B 267 3100
[24]	Wang D Y, Xie P B, Zhang W P, Lou L R, Xia S D 2001 Acta. Phys. Sin. 50 329 (in Chinese) [王殿元, 谢平波, 张慰萍, 楼立人, 夏上达 2001 50 329]
[25]	Zhang S Y, Bi X Z 1991 Spectrum Theory of Rare Earth (Jilin: Jilin science &technology press) p214 (in Chinese) [张思远, 毕宪章 1991 稀土光谱理论 (吉林: 吉林科学技术出版社) 第214页]
[26]	Zhang S Y, Bi X Z 1991 Spectrum Theory of Rare Earth (Jilin: Jilin science &technology press) p228 (in Chinese) [张思远, 毕宪章 1991 稀土光谱理论 (吉林: 吉林科学技术出版社) 第228页]

施引文献

[1]	Nakamura S, Mukai T, Senoh M 1994 J. Appl. Phys. 76 8189
[2]	Cao S X, Han T, Tu M J 2011 Acta Phys. Sin. 60 127802 (in Chinese) [曹仕秀, 韩涛, 涂铭旌 2011 60 127802]
[3]	Zhao C, Ma M X, Han T, Cao S X, Zhu D C 2011 Chin. J. Lumin. 32 1099 (in Chinese) [赵聪, 马明星, 韩涛, 曹仕秀, 朱达川 2011 发光学报 32 1099]
[4]	Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 55 4946]
[5]	Luo H B 2010 MS Dissertation (Zhejiang: Zhejiang University) (in Chinese) [罗海滨 2010 硕士学位论文 (浙江: 浙江大学)]
[6]	Ma M X, Zhu D C, Tu M J 2009 Acta Phys. Sin. 58 5826 (in Chinese) [马明星, 朱达川, 涂铭旌 2009 58 5826]
[7]	Yang Z P, Song Y C, Han Y, Zhao Q, Zhou D Z, Pan F 2012 J. Chin. Rare Earths Soc. 30 47 (in Chinese) [杨志平, 宋延春, 韩月, 赵青, 周东站, 潘飞 2012 中国稀土学报 30 47]
[8]	Birkel A, DeCino N A, George N C, Hazelton K A, Hong B, Seshadri R 2013 Solid State Sci. 19 51
[9]	Huang Z, Chen Y J, Chen L, Xie Y, Xiao L J, Yang Y 2013 Ceram. Int. 39 2709
[10]	Han J K, Hannah M E, Piquette A, Micone J, Hirata G A, Talbot J B, Mishra K C, McKittrick J 2013 J. Lumin. 133 184
[11]	Song G L, Sun K X 2006 Spectrosc. Spect. Anal. 26 1806 (in Chinese) [宋国利, 孙凯霞 2006 光谱学与光谱分析 26 1806]
[12]	Kim J S, Jeon P E, Choi J C, Park H L 2005 Solid State Commun. 133 187
[13]	Liu H L, Guo S, Hao Y Y, Wang H, Xu B S 2012 J. Lumin. 132 2908
[14]	Yang J L, Wang Z 2010 J.Chin.Rare Earths soc. 28 536 (in Chinese) [杨继兰, 王卓 2010 中国稀土学报 28 536 ]
[15]	Zhang M, Wang J, Zhang Q H, Ding W J, Su Q 2007 Mater. Res. Bull. 42 33
[16]	Zhong D, Hu X Y, Li Z H, Li Y X 2009 J. Chin. Rare Earths soc. 27 36 (in Chinese) [钟丹, 胡小野, 李振华, 李永绣 2009 中国稀土学报 27 36]
[17]	Ma M X, Zhu D C, Tu M J 2009 Acta Phys. Sin. 58 6512 (in Chinese) [马明星, 朱达川, 涂铭旌 2009 58 6512]
[18]	Pu Y, Zhu D C, Han T 2012 Chin. J. Lumin. 33 12 (in Chinese) [蒲勇, 朱达川, 韩涛 2012 发光学报 33 12]
[19]	Sugiyama M, Fujimoto Y, Yanagida T, Totsuka D, Kurosawa S, Futami Y,Yokota Y, Chani V, Yoshikawa A 2012 Nucl. Instrum. Methods Phys. Res. Sect. A 664 127
[20]	Kumar G A, Pokhrel M, Sardar D K 2012 Mater. Lett. 68 395
[21]	Kumar G A, Pokhrel M, Martinez A, Dennis R C, Villegas I L, Sardar D K 2012 J. Alloys. Compd. 513 559
[22]	Raju G S R, Park J Y, Jung H C, Pavitra E, Moon B K, Jeong J H, Yu J S, Kim J H, Choi H 2011 J.Alloys. Compd. 509 7537
[23]	Zhu F, Xiao Z S, Yan L, Zhang F, Zhong K, Cheng G A 2009 Nucl.Instrum.Methods Phys. Res. Sect. B 267 3100
[24]	Wang D Y, Xie P B, Zhang W P, Lou L R, Xia S D 2001 Acta. Phys. Sin. 50 329 (in Chinese) [王殿元, 谢平波, 张慰萍, 楼立人, 夏上达 2001 50 329]
[25]	Zhang S Y, Bi X Z 1991 Spectrum Theory of Rare Earth (Jilin: Jilin science &technology press) p214 (in Chinese) [张思远, 毕宪章 1991 稀土光谱理论 (吉林: 吉林科学技术出版社) 第214页]
[26]	Zhang S Y, Bi X Z 1991 Spectrum Theory of Rare Earth (Jilin: Jilin science &technology press) p228 (in Chinese) [张思远, 毕宪章 1991 稀土光谱理论 (吉林: 吉林科学技术出版社) 第228页]

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