Al-Ni-RE非晶合金的晶化行为和热稳定性

张章; 熊贤仲; 乙姣姣; 李金富

doi:10.7498/aps.62.136401

摘要

本文制备了一系列Al-Ni-RE (RE=La, Ce, Y) 非晶合金薄带, 利用差示量热扫描仪和X射线衍射仪考察了非晶合金的晶化行为和初生相, 并分析了其与合金成分和原子特性间的关系. 结果表明: 在拓扑不稳定参数λ以有效原子半径修正为λ'后, 每一Al-Ni-RE非晶合金体系可由其两个临界值划分为纳米晶、纳米玻璃和玻璃三类; Al-Ni-RE非晶合金的晶化开始温度和混合焓与λ'成良好的线性关系, 即λ'能很好的表征Al基非晶合金的热稳定性.

关键词:

Abstract

A series of Al-Ni-RE (RE=La, Ce, Y) amorphous ribbons were prepared. The crystallization behavior and primary phases were investigated using X-ray diffraction and differential scanning calorimeter, and their relationships with the alloy composition and atomic features were analyzed. Results show that if the topological instability parameter λ was modified using effective atomic radii, the metallic glasses in an Al-Ni-RE system can be classified into nanocrystalline, nanoglassy and glassy types according to their crystallization behaviors by two critical values of the modified topological instability parameter λ'. Linear relationships of onset temperature of crystallization and mixing enthalpy with λ' are also clearly revealed, indicating that λ' is closely related to the thermal stability of Al-Ni-RE metallic glasses.

Keywords:

作者及机构信息

1.
上海交通大学材料学院, 金属基复合材料国家重点实验室, 上海 200240

基金项目: 上海市教育委员会科研创新项目(批准号: 13ZZ016);国家重点基础研究发展计划(批准号: 2011CB610405)和国家自然科学基金(批准号: 50831003)资助的课题.

Authors and contacts

1.
School of Materials Science and Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China

Funds: Project supported by the Innovation Program of Shanghai Municipal Education Commission, China (Grant No. 13ZZ016), the National Basic Research Program of China (Grant No. 2011CB610405), and the National Natural Science Foundation of China (Grant No. 50831003).

参考文献

[1]	Greer A L 1995 Science 267 1947
[2]	Kim Y H, Inoue A, Masumoto T 1990 Mater. Trans. JIM 31 747
[3]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 331
[4]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 599
[5]	Zhuo L C, Pang S J, Wang H, Zhang H 2009 Chin. Phys. Lett. 26 066402
[6]	Zhong Z C, Jiang X Y, Greer A L 1997 Mater. Sci. Eng. A 226-228 531
[7]	Sa Lisboa R D, Bolfarini C, Botta W J 2005 Appl. Phys. Lett. 86 211904
[8]	Zhang Z, Zhou W, Xiong X Z, Li J F 2012 Intermetallics 24 1
[9]	Huang Z H, Li J F, Rao Q L, Zhou Y H 2007 Intermetallics 15 1139
[10]	Egami T, Waseda Y 1984 J Non-Cryst Solids 64 113
[11]	Ueno S, Waseda Y 1987 J. Mater. Eng. 9 199
[12]	Waseda Y, Chen H S, Jacob K T, Shibata H 2008 Sci. Technol. Adv. Mater. 9 023003
[13]	Inoue A 1998 Prog. Mater. Sci. 43 365
[14]	Liu S C, Davenport J D, Plummer E W 1990 Phys. Rev. B 42 1582
[15]	Hsieh H Y, Toby B H, Egami T 1990 J. Mater. Res. 5 2807
[16]	Huang Z H 2008 Ph. D. Dissertation (Shanghai: Shanghai Jiaotong University) (in Chinese) [黄振华 2008 博士学位论文 (上海: 上海交通大学) ]
[17]	Sanders W S, Warner J S, Miracle D B 2006 Intermetallics 14 348
[18]	Ma C S, Zhang J, Chang X C 2008 Philo. Mag. Lett. 88 917
[19]	Saini S, Zaluska A, Altounian Z 1999 J. Non-Cryst. Solids 250-252 714
[20]	Yang H, Wang J Q, Li Y 2007 Philo. Mag. 87 4211
[21]	Matsubara E, Waseda Y, Inoue A 1989 Z Naturforsch 44a 814
[22]	Yu C Y, Hui X D, Chen X H 2010 Sci. China. Tech. Sci. 53 3175
[23]	Karel S, Pál J, Hermann F 2006 J. Phys.: Condens. Matter. 18 7579
[24]	Pyykkö P, Atsumi M 2009 Chem. Eur. J. 15 122770
[25]	Egry I,.Hennet L, Kehr M 2008 J. Chem. Phys. 129 064508
[26]	Bacewicz R, Antonowicz J 2006 Scripta Mater. 54 1187
[27]	Zalewski W, Antonowicz J, Bacewicz R 2009 J. Alloys Compd. 468 40
[28]	Ahn K, Louca D, Poon S J 2004 Phys. Rev. B 70 224103
[29]	Li X L, Bian X F, Hu L N 2010 Phys. Lett. A 374 3784
[30]	Boer F R, Perrifor 1988 Cohension in metals (Netherlands, Elsevier Science Publishers)
[31]	Takeuchi A, Inoue A 2001 Mater. Sci. Eng. A 304-306 446
[32]	Buschow K H J, Beekman N M 1980 Solid State Commun. 35 233
[33]	Xia M X, Zhang S G, Li J G 2006 Appl. Phys. Lett. 88 261913
[34]	Li X L, Bian X F, Hu L N 2007 J. Appl. Phys. 101 103540

施引文献

[1]	Greer A L 1995 Science 267 1947
[2]	Kim Y H, Inoue A, Masumoto T 1990 Mater. Trans. JIM 31 747
[3]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 331
[4]	Kim Y H, Inoue A, Masumoto T 1991 Mater. Trans. JIM 32 599
[5]	Zhuo L C, Pang S J, Wang H, Zhang H 2009 Chin. Phys. Lett. 26 066402
[6]	Zhong Z C, Jiang X Y, Greer A L 1997 Mater. Sci. Eng. A 226-228 531
[7]	Sa Lisboa R D, Bolfarini C, Botta W J 2005 Appl. Phys. Lett. 86 211904
[8]	Zhang Z, Zhou W, Xiong X Z, Li J F 2012 Intermetallics 24 1
[9]	Huang Z H, Li J F, Rao Q L, Zhou Y H 2007 Intermetallics 15 1139
[10]	Egami T, Waseda Y 1984 J Non-Cryst Solids 64 113
[11]	Ueno S, Waseda Y 1987 J. Mater. Eng. 9 199
[12]	Waseda Y, Chen H S, Jacob K T, Shibata H 2008 Sci. Technol. Adv. Mater. 9 023003
[13]	Inoue A 1998 Prog. Mater. Sci. 43 365
[14]	Liu S C, Davenport J D, Plummer E W 1990 Phys. Rev. B 42 1582
[15]	Hsieh H Y, Toby B H, Egami T 1990 J. Mater. Res. 5 2807
[16]	Huang Z H 2008 Ph. D. Dissertation (Shanghai: Shanghai Jiaotong University) (in Chinese) [黄振华 2008 博士学位论文 (上海: 上海交通大学) ]
[17]	Sanders W S, Warner J S, Miracle D B 2006 Intermetallics 14 348
[18]	Ma C S, Zhang J, Chang X C 2008 Philo. Mag. Lett. 88 917
[19]	Saini S, Zaluska A, Altounian Z 1999 J. Non-Cryst. Solids 250-252 714
[20]	Yang H, Wang J Q, Li Y 2007 Philo. Mag. 87 4211
[21]	Matsubara E, Waseda Y, Inoue A 1989 Z Naturforsch 44a 814
[22]	Yu C Y, Hui X D, Chen X H 2010 Sci. China. Tech. Sci. 53 3175
[23]	Karel S, Pál J, Hermann F 2006 J. Phys.: Condens. Matter. 18 7579
[24]	Pyykkö P, Atsumi M 2009 Chem. Eur. J. 15 122770
[25]	Egry I,.Hennet L, Kehr M 2008 J. Chem. Phys. 129 064508
[26]	Bacewicz R, Antonowicz J 2006 Scripta Mater. 54 1187
[27]	Zalewski W, Antonowicz J, Bacewicz R 2009 J. Alloys Compd. 468 40
[28]	Ahn K, Louca D, Poon S J 2004 Phys. Rev. B 70 224103
[29]	Li X L, Bian X F, Hu L N 2010 Phys. Lett. A 374 3784
[30]	Boer F R, Perrifor 1988 Cohension in metals (Netherlands, Elsevier Science Publishers)
[31]	Takeuchi A, Inoue A 2001 Mater. Sci. Eng. A 304-306 446
[32]	Buschow K H J, Beekman N M 1980 Solid State Commun. 35 233
[33]	Xia M X, Zhang S G, Li J G 2006 Appl. Phys. Lett. 88 261913
[34]	Li X L, Bian X F, Hu L N 2007 J. Appl. Phys. 101 103540

[1]	许思维, 王训四, 沈祥. 元素取代对Ge-As(Sb)-Se玻璃转变阈值行为的影响. , 2024, 73(5): 057102. doi: 10.7498/aps.73.20231797
[2]	康亚斌, 袁小朋, 王晓波, 李克伟, 宫殿清, 程旭东. 分层化金属陶瓷光热转换涂层的微结构构筑与热稳定性. , 2023, 72(5): 057103. doi: 10.7498/aps.72.20221693
[3]	王晓波, 李克伟, 高丽娟, 程旭东, 蒋蓉. 耐高温CrAlON基太阳能光谱选择性吸收涂层的制备与热稳定性. , 2021, 70(2): 027103. doi: 10.7498/aps.70.20200845
[4]	刘乐, 汤建, 王琴琴, 时东霞, 张广宇. 石墨烯封装单层二硫化钼的热稳定性研究. , 2018, 67(22): 226501. doi: 10.7498/aps.67.20181255
[5]	王峥, 汪卫华. 非晶合金中的流变单元. , 2017, 66(17): 176103. doi: 10.7498/aps.66.176103
[6]	金肖, 王利民. 非晶材料玻璃转变过程中记忆效应的热力学. , 2017, 66(17): 176406. doi: 10.7498/aps.66.176406
[7]	卢顺顺, 张晋敏, 郭笑天, 高廷红, 田泽安, 何帆, 贺晓金, 吴宏仙, 谢泉. 碳纳米管包裹的硅纳米线复合结构的热稳定性研究. , 2016, 65(11): 116501. doi: 10.7498/aps.65.116501
[8]	崔晓, 徐保臣, 王知鸷, 王丽芳, 张博, 祖方遒. 1 at% Ag替代Zr57Cu20Al10Ni8Ti5 金属玻璃中各组元对玻璃形成能力及热稳定性的作用分析. , 2013, 62(1): 016101. doi: 10.7498/aps.62.016101
[9]	张杨, 宋晓艳, 徐文武, 张哲旭. SmCo7纳米晶合金晶粒组织热稳定性的热力学分析与计算机模拟. , 2012, 61(1): 016102. doi: 10.7498/aps.61.016102
[10]	闫建成, 何智兵, 阳志林, 陈志梅, 唐永建, 韦建军. 玻璃微球表面辉光等离子体聚合物涂层的热稳定性研究. , 2010, 59(11): 8005-8009. doi: 10.7498/aps.59.8005
[11]	李美丽, 付兴烨, 孙宏宁, 赵洪安, 李丛, 段永平, 闫元, 孙民华. 高压作用下相分离液体玻璃转变的分子动力学研究. , 2009, 58(8): 5604-5609. doi: 10.7498/aps.58.5604
[12]	张凯旺, 孟利军, 李俊, 刘文亮, 唐翌, 钟建新. 碳纳米管内金纳米线的结构与热稳定性. , 2008, 57(7): 4347-4355. doi: 10.7498/aps.57.4347
[13]	张旭东, 徐铁峰, 聂秋华, 戴世勋, 沈祥, 陆龙君, 章向华. Er3+/Yb3+共掺碲硼硅酸盐玻璃的光谱性质和热稳定性研究. , 2007, 56(3): 1758-1764. doi: 10.7498/aps.56.1758
[14]	王秀英, 陈莹, 张宁玉, 赵丽萍, 庞岩涛, 王文魁. 压力对Zr46.75Ti8.25Cu7.5Ni10Be27.5大块非晶合金玻璃转变和晶化动力学的影响. , 2007, 56(7): 4004-4008. doi: 10.7498/aps.56.4004
[15]	沈祥, 聂秋华, 徐铁峰, 高媛. Er3+/Yb3+共掺碲钨酸盐玻璃的光谱性质和热稳定性的研究. , 2005, 54(5): 2379-2384. doi: 10.7498/aps.54.2379
[16]	滕蛟, 蔡建旺, 熊小涛, 赖武彦, 朱逢吾. NiFe/FeMn双层膜交换偏置的形成及热稳定性研究. , 2004, 53(1): 272-275. doi: 10.7498/aps.53.272
[17]	赵作峰, 张志, 李　正, 闻　平, 赵德乾, 潘明祥, 王万录, 汪卫华. 新型Pr基大块非晶及其特性研究. , 2004, 53(3): 850-853. doi: 10.7498/aps.53.850
[18]	陈志浩, 刘兰俊, 张　博, 席　赟, 王　强, 祖方遒. Zr-Al-Ni-Cu(Nb,Ti)大块非晶玻璃转变的动力学性质. , 2004, 53(11): 3839-3844. doi: 10.7498/aps.53.3839
[19]	李正, 白海洋, 赵德乾, 潘明祥, 王万录, 汪卫华. 永磁性Pr55Al12Fe30Cu3 大块金属玻璃. , 2003, 52(3): 652-655. doi: 10.7498/aps.52.652
[20]	杨慎东, 宁兆元, 黄峰, 程珊华, 叶超. a-C:F薄膜的热稳定性与光学带隙的关联. , 2002, 51(6): 1321-1325. doi: 10.7498/aps.51.1321

计量

文章访问数: 6674
PDF下载量: 550
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板