新型高效聚合物/富勒烯有机光伏电池研究进展

高博文; 高潮; 阙文修; 韦玮

doi:10.7498/aps.61.194213

摘要

有机聚合物/富勒烯本体异质结光伏电池以其不断提高的能量转换效率受到了研究人员的广泛关注, 近年来成为光伏电池研究领域的热点之一. 本文主要通过对聚合物/富勒烯太阳能电池的内部机理,包括光吸收、激子扩散和解离以及自由载流子输运和提取等关键科学问题, 从器件材料和结构优化、形貌控制和界面修饰等不同侧面介绍了提高聚合物/富勒烯太阳能电池性能的方法, 讨论了各种器件的结构和能量转换效率, 对于进一步开展这方面的研究工作指明了方向, 最后对其未来的发展前景做出了展望.

关键词:

Abstract

Polymer photovoltaic cells with organic polymer materials as the active layers for an increasing power conversion efficiency have become a research hotspot in the field of photovoltaic devices in recent years. In this paper, Internal mechanism of polymer/fullerene solar cells are elaborated exhaustively, including light absorption, exciton diffusion and dissociation and charge carrier transport as well as extraction. Furthermore, the optimization of device structure, morphology control and interface modification are introduced to improve performance of polymer/fullerene solar cells. Power conversion efficiency and the various structures which can be achieved are discussed in detail. The future prospects of polymer photovoltaic cells are also expected.

Keywords:

作者及机构信息

1.
中国科学院西安光学精密机械研究所, 瞬态光学与光子技术国家重点实验室, 西安 710119;

2.
西安交通大学电子与信息工程学院, 西安 710049;

3.
西安近代化学研究所, 西安 710065

基金项目: 国家自然科学基金(批准号: 60907012, 61177031)资助的课题.

Authors and contacts

1.
State Key Laboratory of Transient Optics and Photonics, Xi'an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences , Xi'an 710119, China;

2.
School of Electronics and Information Engineering, Xi'an Jiaotong University, Xi'an 710049, China;

3.
Xi'an Modern Chemistry Research Institute, Xi'an 710065, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 60907012, 61177031).

参考文献

[1]	Li G, Shrotriya V, Yang Y 2005 Nat. Mater. 4 864
[2]	Koster L J A, Mihailetchi V D, Blom P W M 2006 Appl. Phys. Lett. 88 093511
[3]	Green M A, Emery K, Hishikawa Y 2011 Res. Appl. 19 565
[4]	Wang E G, Wang L, Cao Y 2008 Appl. Phys. Lett. 92 033307
[5]	Liang Y, Feng D, Wu Y 2009 J. Am. Chem. Soc. 1317792
[6]	Liang Y Y, Yu L P, 2010 Accounts of Chemical Research 43 1227
[7]	Huo L J, Zhang Sh Q, Guo Xi 2011 Angew. Chem. Int. Ed. 50 9697
[8]	He Z C, Zhong C M , Huang X, Cao Y 2011 Advanced Materials 22 4636
[9]	Luhman W A, Holmes R J 2009 Appl. Phys. Lett. 94 153304
[10]	Yu G, Pakbaz K, Heeger A J 1994 Appl. Phys. Lett. 64 3422
[11]	Yu G, Gao J, Hummelen J C 1995 Science 270 1789
[12]	Shaheen,S E ,Brabec,C J Sariciftci, 2001 Applied Physics Letters 78 841
[13]	Padinger,F ,Rittberger R S ,Sariciftci 2003 Advanced Functional Materials 13 85
[14]	Ma,W L,Yang C Y,Gong,X 2005 Advanced Functional Materials 15 1617
[15]	Kim,J Y ,Kim,S H ,Lee,H H 2006 Advanced Materials 18 572
[16]	Wang E, Wang L, Lan L F 2008 Appl. Phys. Lett. 92 033307
[17]	Wang M, Hu X W, Liu P 2011 Journal of the American Chemical Society 133 9638
[18]	He Y J, Chen H Y, Hou J H 2010 Journal of the American Chemical Society 132 1377
[19]	Zhao G J, He Y J, Li Y F 2010 Advanced Materials 22 4355
[20]	Park S H, Roy A, Beaupré S, Heeger A J 2009 Nature Photonics 3 297
[21]	Hou J,Chen H ,Zhang S, Yang Y 2009 Journal of the American Society 131 15586
[22]	Chen H ,Hou J ,Zhang S, Yang Y 2009 Nature Photonics 3 649
[23]	Chu T Y , Lu J P, Beaupr, Tao Y 2011 J. S. Am. Chem. Soc. 133 4250
[24]	Jorgensen M, Norrman K, Krebs F C 2008 Sol. Energy Materials & Sol. Cells 92 686
[25]	Kim S Y, Hong K, Kim K 2008 Mater. Lett. 4 63
[26]	Kim H, Shin M, Park J 2010 IEEE Trans Nanotechnol. 9 400
[27]	deJong M P, vanIjzendoorn L J A, deVoigt M J 2000 Appl. Phys. Lett. 77 255
[28]	Xu Z, Chen L M, Yang G W 2009 Adv. Funct. Mater. 19 1227
[29]	Waldauf C , Morana M, Denk P 2006 Applied Physics Letters 89 233517
[30]	Liao H H, Chen L M , Xu Z, Yang Y 2008 Appl. Phys. Lett. 92 173303
[31]	Jiang Ch Y, Sun X W, Zhao D W 2010 Solar Energy Materials & Solar Cells 94 1618
[32]	Zhu Y X, Xu X F, Zhang L J 2011 Solar Energy Materials & Solar Cells 97 83
[33]	Lin Y H, Yang P C, Huang J S 2011 Solar Energy Materials & Solar Cells 95 2511
[34]	Cheng Y J, Hsieh Ch H, Li Y F 2010 J. Am. Chem. Soc. 132 17381
[35]	Chu T Y, Tsang S W, Zhou J Y 2012 Solar Energy Materials & Solar Cells 96 155
[36]	Amb C M,Amb, Chen S, Graham K R. 2011 J. Am. Chem. Soc. 133 10062
[37]	Kim C S, Tinker L L, DiSalle B F 2009 Adv .Mater. 21 3110
[38]	Reyes-Reyes M, López-Sandoval R, Arenas-Alatorre J 2007 Thin Solid Films 516 52
[39]	Savenije T J, Kroeze J E, Yang X 2005 Adv. Funct. Mater. 15 1260
[40]	Nguyen L H, Hoppe H, Erb T 2007 Adv. Funct. Mater. 17 1071
[41]	Erb T, Zhokhavets U, Gobsch G 2005 Adv. Funct .Mater. 15 1193
[42]	Inoue K, Ulbricht R, Madaka P C 2005 Synth .Met. 154 41
[43]	Ayzner A L, Wanger D D, Tassone C J 2008 J. Phys. Chem. C 112 18711
[44]	Yun J J, Peet J, Cho N S 2008 Appl .Phys. Lett. 92 251912
[45]	Mihailetchi V D, Xie H X, de-Boer B 2006 Adv. Funct. Mater. 16 699
[46]	Li G, Shrotriya V, Yang Y 2005 J. Appl. Phys. 98 043704
[47]	Ma W, Yang C, Heeger A J 2007 Adv. Mater. 19 1387
[48]	Goh C, Scully S R, McGehee M D 2007 J. Appl. Phys. 101 114503
[49]	Roy A, Park S H, Cowan S 2009 Appl. Phys. Lett. 95 013302

施引文献

[1]	Li G, Shrotriya V, Yang Y 2005 Nat. Mater. 4 864
[2]	Koster L J A, Mihailetchi V D, Blom P W M 2006 Appl. Phys. Lett. 88 093511
[3]	Green M A, Emery K, Hishikawa Y 2011 Res. Appl. 19 565
[4]	Wang E G, Wang L, Cao Y 2008 Appl. Phys. Lett. 92 033307
[5]	Liang Y, Feng D, Wu Y 2009 J. Am. Chem. Soc. 1317792
[6]	Liang Y Y, Yu L P, 2010 Accounts of Chemical Research 43 1227
[7]	Huo L J, Zhang Sh Q, Guo Xi 2011 Angew. Chem. Int. Ed. 50 9697
[8]	He Z C, Zhong C M , Huang X, Cao Y 2011 Advanced Materials 22 4636
[9]	Luhman W A, Holmes R J 2009 Appl. Phys. Lett. 94 153304
[10]	Yu G, Pakbaz K, Heeger A J 1994 Appl. Phys. Lett. 64 3422
[11]	Yu G, Gao J, Hummelen J C 1995 Science 270 1789
[12]	Shaheen,S E ,Brabec,C J Sariciftci, 2001 Applied Physics Letters 78 841
[13]	Padinger,F ,Rittberger R S ,Sariciftci 2003 Advanced Functional Materials 13 85
[14]	Ma,W L,Yang C Y,Gong,X 2005 Advanced Functional Materials 15 1617
[15]	Kim,J Y ,Kim,S H ,Lee,H H 2006 Advanced Materials 18 572
[16]	Wang E, Wang L, Lan L F 2008 Appl. Phys. Lett. 92 033307
[17]	Wang M, Hu X W, Liu P 2011 Journal of the American Chemical Society 133 9638
[18]	He Y J, Chen H Y, Hou J H 2010 Journal of the American Chemical Society 132 1377
[19]	Zhao G J, He Y J, Li Y F 2010 Advanced Materials 22 4355
[20]	Park S H, Roy A, Beaupré S, Heeger A J 2009 Nature Photonics 3 297
[21]	Hou J,Chen H ,Zhang S, Yang Y 2009 Journal of the American Society 131 15586
[22]	Chen H ,Hou J ,Zhang S, Yang Y 2009 Nature Photonics 3 649
[23]	Chu T Y , Lu J P, Beaupr, Tao Y 2011 J. S. Am. Chem. Soc. 133 4250
[24]	Jorgensen M, Norrman K, Krebs F C 2008 Sol. Energy Materials & Sol. Cells 92 686
[25]	Kim S Y, Hong K, Kim K 2008 Mater. Lett. 4 63
[26]	Kim H, Shin M, Park J 2010 IEEE Trans Nanotechnol. 9 400
[27]	deJong M P, vanIjzendoorn L J A, deVoigt M J 2000 Appl. Phys. Lett. 77 255
[28]	Xu Z, Chen L M, Yang G W 2009 Adv. Funct. Mater. 19 1227
[29]	Waldauf C , Morana M, Denk P 2006 Applied Physics Letters 89 233517
[30]	Liao H H, Chen L M , Xu Z, Yang Y 2008 Appl. Phys. Lett. 92 173303
[31]	Jiang Ch Y, Sun X W, Zhao D W 2010 Solar Energy Materials & Solar Cells 94 1618
[32]	Zhu Y X, Xu X F, Zhang L J 2011 Solar Energy Materials & Solar Cells 97 83
[33]	Lin Y H, Yang P C, Huang J S 2011 Solar Energy Materials & Solar Cells 95 2511
[34]	Cheng Y J, Hsieh Ch H, Li Y F 2010 J. Am. Chem. Soc. 132 17381
[35]	Chu T Y, Tsang S W, Zhou J Y 2012 Solar Energy Materials & Solar Cells 96 155
[36]	Amb C M,Amb, Chen S, Graham K R. 2011 J. Am. Chem. Soc. 133 10062
[37]	Kim C S, Tinker L L, DiSalle B F 2009 Adv .Mater. 21 3110
[38]	Reyes-Reyes M, López-Sandoval R, Arenas-Alatorre J 2007 Thin Solid Films 516 52
[39]	Savenije T J, Kroeze J E, Yang X 2005 Adv. Funct. Mater. 15 1260
[40]	Nguyen L H, Hoppe H, Erb T 2007 Adv. Funct. Mater. 17 1071
[41]	Erb T, Zhokhavets U, Gobsch G 2005 Adv. Funct .Mater. 15 1193
[42]	Inoue K, Ulbricht R, Madaka P C 2005 Synth .Met. 154 41
[43]	Ayzner A L, Wanger D D, Tassone C J 2008 J. Phys. Chem. C 112 18711
[44]	Yun J J, Peet J, Cho N S 2008 Appl .Phys. Lett. 92 251912
[45]	Mihailetchi V D, Xie H X, de-Boer B 2006 Adv. Funct. Mater. 16 699
[46]	Li G, Shrotriya V, Yang Y 2005 J. Appl. Phys. 98 043704
[47]	Ma W, Yang C, Heeger A J 2007 Adv. Mater. 19 1387
[48]	Goh C, Scully S R, McGehee M D 2007 J. Appl. Phys. 101 114503
[49]	Roy A, Park S H, Cowan S 2009 Appl. Phys. Lett. 95 013302

[1]	王康颖, 马才媛, 蔚慧敏, 张海涛, 岑建勇, 王英英, 潘俊星, 张进军. 振荡场作用下聚合物/纳米棒混合体系的自组装. , 2023, 72(7): 079401. doi: 10.7498/aps.72.20222207
[2]	高艺雯, 王影, 田文得, 陈康. 空间调制的驱动外场下活性聚合物的动力学行为. , 2022, 71(24): 240501. doi: 10.7498/aps.71.20221367
[3]	刘俊娟, 魏增江, 常虹, 张亚琳, 邸冰. 杂质离子对有机共轭聚合物中极化子动力学性质的影响. , 2016, 65(6): 067202. doi: 10.7498/aps.65.067202
[4]	严大东, 张兴华. 聚合物结晶理论进展. , 2016, 65(18): 188201. doi: 10.7498/aps.65.188201
[5]	封国宝, 王芳, 曹猛. 电子辐照聚合物带电特性多参数共同作用的数值模拟. , 2015, 64(22): 227901. doi: 10.7498/aps.64.227901
[6]	王文静, 孟瑞璇, 李元, 高琨. 共轭聚合物中受激吸收与受激辐射的量子动力学研究. , 2014, 63(19): 197901. doi: 10.7498/aps.63.197901
[7]	黄永宪, 冷劲松, 田修波, 吕世雄, 李垚. 等离子体浸没离子注入非导电聚合物的适应性及栅网诱导效应的研究. , 2012, 61(15): 155206. doi: 10.7498/aps.61.155206
[8]	廖瑞金, 周天春, George Chen, 杨丽君. 聚合物材料空间电荷陷阱模型及参数. , 2012, 61(1): 017201. doi: 10.7498/aps.61.017201
[9]	黄永宪, 吕世雄, 田修波, 杨士勤, Fu Ricky, Chu K Paul, 冷劲松, 李垚. 聚合物物理属性对离子注入效应的影响. , 2012, 61(10): 105203. doi: 10.7498/aps.61.105203
[10]	闫悦, 赵谡玲, 徐征, 龚伟, 王大伟. 多环类苝四甲酸二酐插入层对ZnO纳米棒和聚合物复合太阳电池性能的影响. , 2011, 60(8): 088803. doi: 10.7498/aps.60.088803
[11]	周可余, 叶辉, 甄红宇, 尹伊, 沈伟东. 基于压电聚合物薄膜可调谐Fabry-Perot滤波器的研究. , 2010, 59(1): 365-369. doi: 10.7498/aps.59.365
[12]	徐苗, 彭俊彪. 制膜工艺对聚合物太阳电池性能影响的研究. , 2010, 59(3): 2131-2136. doi: 10.7498/aps.59.2131
[13]	全荣辉, 张振龙, 韩建伟, 黄建国, 闫小娟. 电子辐照下聚合物介质深层充电现象研究. , 2009, 58(2): 1205-1211. doi: 10.7498/aps.58.1205
[14]	张红平, 欧阳洁, 阮春蕾. 纤维悬浮聚合物熔体描述的均一结构多尺度模型. , 2009, 58(1): 619-630. doi: 10.7498/aps.58.619
[15]	史晶, 高琨, 雷杰, 解士杰. 基态非简并导电聚合物——坐标空间研究. , 2009, 58(1): 459-464. doi: 10.7498/aps.58.459
[16]	张亚妮. 微结构聚合物光纤中高双折射可调效应研究. , 2008, 57(9): 5729-5734. doi: 10.7498/aps.57.5729
[17]	王义平, 陈建平, 李新碗, 周俊鹤, 沈浩, 施长海, 张晓红, 洪建勋, 叶爱伦. 快速可调谐电光聚合物波导光栅. , 2005, 54(10): 4782-4788. doi: 10.7498/aps.54.4782
[18]	陈波, 夏庆中, V. T. Lebedev. 富勒烯-PVP聚合物链团结构的中子小角散射实验研究. , 2005, 54(6): 2821-2825. doi: 10.7498/aps.54.2821
[19]	张锡娟, 李广起, 孙鑫. 聚合物中产生双激子的新通道. , 2002, 51(1): 134-137. doi: 10.7498/aps.51.134
[20]	曹万强, 李景德. 聚合物介电弛豫的温度特性. , 2002, 51(7): 1634-1638. doi: 10.7498/aps.51.1634

计量

文章访问数: 7998
PDF下载量: 2330
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板