源于团簇-共振模型的理想金属玻璃电子化学势均衡

韩光; 羌建兵; 王清; 王英敏; 夏俊海; 朱春雷; 全世光; 董闯

doi:10.7498/aps.61.036402

摘要

理想金属玻璃是指完全满足电子结构稳定性的金属玻璃. 在我们前期工作中提出的团簇加连接原子及理想金属玻璃的团簇-共振结构模型的基础上, 本文指出理想金属玻璃应该满足电子化学势均衡判据, 可定量给出团簇与连接原子的比例, 最终确定了理想金属玻璃成分式[团簇](连接原子)x. 运用此判据, 解析了Cu-Zr基和Co-B基块体金属玻璃, 实验确定的最佳形成能力成分满足电子化学势均衡.

关键词:

Ideal metallic glasses are the metallic glasses that satisfy electronic structure stability. Previously we have developed a so-calledcluster-plus-glue-atom modeland more recently acluster-resonance modelfor the ideal metallic glasses. Good metallic glass forming compositions always satisfy simple cluster formulas [cluster] (glue atoms), with x denoting the number of glue atoms matching one cluster. In this paper we present an electrochemical potential equilibrium criterion based on these models to obtain the number of glue atoms. By examples of Cu-Zr and Co-B bulk metallic glasses, it is confirmed that the experimentally determined good BMG-forming compositions well agree with the calculated composition formulas.

Keywords:

作者及机构信息

1.
大连理工大学三束材料改性教育部重点实验室, 大连 116024;

2.
大连大学, 物理科学与技术学院, 大连 116622

基金项目: 国家自然科学基金(批准号: 51041011,50901012)和国家重点基础研究发展计划(批准号: 2007CB613902)资助的课题.

Authors and contacts

1.
Key Laboratory of Materials Modification, Dalian University of Technology, Ministry of Education, Dalian 116024, China;

2.
College of Physics, Dalian University, Dalian 116622, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51041011, 50901012) and the National Basic Research Program of China (Grant No. 2007CB613902).

参考文献

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施引文献

[1]	Inoue A 2000 Acta Mater. 48 279
[2]	Yu P, Bai H Y, Tang M B,WangWL,WangWH 2005 Acta Phys.Sin. 54 3284 (in Chinese) [余鹏, 白海洋, 汤美波, 王万录, 汪卫华 2005 54 3284]
[3]	Wang Q, Qiang J B, Wang Y M, Xia J H, Lin Z, Zhang X F, DongC 2006 Acta Phys. Sin. 55 378 (in Chinese) [王清, 羌建兵, 王英敏, 夏俊海, 林哲, 张新房, 董闯 2006 55 378]
[4]	Zhao Z F, Zhang Z, Li Z, Wen P, Zhao D Q, Pan M X, Wang W L, Wang W H 2004 Acta Phys. Sin. 53 850 (in Chinese) [赵作峰, 张志, 李正, 闻平, 赵德乾, 潘明祥, 王万录, 汪卫华 2004 53 850]
[5]	Lu Z P, Liu C T 2002 Acta Mater. 50 3501
[6]	Wang Y M, Qiang J B, Wong C H, Shek C H, Dong C 2003 J.Mater. Res. 18 642
[7]	Dong C, Wang Y M, Qiang J B, Wang D H, Chen W R, Shek C H2004 Mater. Trans. JIM 45 1177
[8]	Xia J H, Qiang J B,Wang Y M,Wang Q, Dong C 2006 Appl. Phys.Lett. 88 1019071
[9]	Dong C, Wang Q, Qiang J B, Wang Y M, Jiang N, Han G, Li Y H,Wu J, Xia J H 2007 J. Phys. D: Appl. Phys. 40 273
[10]	Zhang J X, Li H, Zhang J, Song X G, Bian X F 2009 Chin. Phys.B 18 4949
[11]	Lu B C, Yao H J, Xu J, Li Y 2009 Appl. Phys. Lett. 94 241913
[12]	Guo G Q, Yang L, Zhang G Q 2011 Acta Phys. Sin. 60 016103(in Chinese) [郭古青, 杨亮, 张国庆 2011 60 016103]
[13]	Han G, Qiang J B,Wang Q,Wang Y M, Zhu C L, Quan S G, DongC, Häussler P 2011 Philosophical Magazine 91 2404
[14]	Sanderson R T 1951 Science 114 670
[15]	Mortier W J, Ghosh K, Shankar S 1986 J. Am. Chem. Soc. 1084315
[16]	Parr R G, Donnelly R A, Levy M, Palke W E 1978 J. Chem. Phys.68 3801
[17]	Itskowitz P, Berkowitz M L 1997 J. Phys. Chem. A 101 5687
[18]	Nagel S R, Tauc J 1975 Phys. Rev. Lett. 35 380
[19]	Mott N F, Jones H 1936 The Theory of the Properties of Metal andAlloys (Oxford: Clarendon ) p310
[20]	Nagel S R 1977 Phys. Rev. B 16 1694
[21]	Beck H, Oberie R 1979 Solids State Commun. 32 959
[22]	Haussler P 1992 Phys. Reports 222 65
[23]	Häussler P, Nowak H , Bhuiyan M, Barzola Q J 2002 Physica B316–317 489
[24]	Friedel J 1958 Nuovo Cimento 7 287
[25]	Bernal J D 1959 Nature 183 141
[26]	Peker A, Johnson W L 1993 Appl. Phys. Lett. 63 2342
[27]	Saida J, Matsushita M, Inoue A 2001 Appl. Phys. Lett. 79 412
[28]	Wang W H, Wu E, Wang R J, Studer A J 2002 Phys. Rev. B 66104205
[29]	Li C, Saida J, Inoue A 2000 Mater. Trans. JIM 41 1521
[30]	Koster U, Zander D, Rainer J 2002 Mater. Sci. Forum 386–688 89
[31]	Saksl K, Franz H, Jovari P, Klementiev K, Welter E, Ehnes A,Saida J, Inoue A, Jiang J Z 2003 Appl. Phys. Lett. 83 3924
[32]	Wang R 1979 Nature 278 700
[33]	Wang W H, Wei Q, Friedrich S 1998 Phys. Rev. B 57 8211
[34]	Miracle D B 2004 Nature Mater. 3 697
[35]	Sheng H W, Luo W K, Alamgir F M, Bai J M, Ma E 2006 Nature439 419
[36]	Wang Y M, Wang Q, Zhao J J, Dong C 2010 Scripta Materialia63 178
[37]	Yuan L, Pang C, Wang Y M, Wang Q, Qiang J B, Dong C 2010 Intermetallics 18 1800
[38]	Zhu C L, Wang Q, Wang Y M, Qiang J B, Dong C 2010 Intermetallics18 791
[39]	Zhu C L, Wang Q, Zhang J, Wang Y M, Dong C 2010 Inter. J.Minerals, Metallurgy and Materials 17 323
[40]	Chen J X, Qiang J B, Wang Q, Dong C 2012 Acta Phys. Sin. (inChinese) 61 046102 [陈季香, 羌建兵, 王清, 董闯 2011 in Press]
[41]	Luo L J, Wu J, Wang Q, Wang Y M, Han G, Dong C 2010 Phil.Mag. 90 3961
[42]	Xu D H, Lohwongwatana B, Duan G, Johnson W L, Garland C2004 Acta Mater. 52 2621
[43]	Wang Q, Qiang J B,Wang Y M, Xia J H, Zhang X F, Dong C 2005Materials Science Forum 475–479 3381
[44]	Xia J H, Qiang J B, Wang Y M, Wang Q, Dong C 2007 Mate. Sci.Eng. A 449–451 281
[45]	Inoue A, Zhang W 2004 Mater. Trans. JIM 45 584
[46]	Jia P, Guo H, Li Y, Xu J, Ma E 2006 Scripta Mater. 54 2165
[47]	Inoue A, Kato A, Zhang T, Kim S G, Masumoto T 1991 Mater.Trans. JIM 32 609
[48]	Yao K F, Ruan F 2005 Chin. Phys. Lett. 22 1481
[49]	Chen Q J, Shen J, Zhang D L, Fan H B, Sun J F, McCartney D G2006 Mater. Sci. Eng. A 433 155
[50]	Zhu C L 2011 Ph.D. Dissertation (Dalian: Dalian University ofTechnology) (in Chinese) [朱春雷 2011 博士学位论文(大连: 大连理工大学)]

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