Nd0.7Sr0.3MnO3陶瓷EPIR效应的起源

杨昌平; 陈顺生; 戴琪; 宋学平

doi:10.7498/aps.60.117202

摘要

用两线法和四线法对球磨合成后热处理的Nd0.7Sr0.3MnO3陶瓷样品的电脉冲诱导电阻转变(EPIR)效应进行了测试.结果表明:在Nd0.7Sr0.3MnO3块体中用四线法测得的I-V曲线为非线性,说明Nd0.7Sr0.3MnO3样品在晶(相)界处存在空间电荷层和界面电阻.但用四线法测量EPIR效应时,没有EPIR效应发生,表明晶(相)界处的空间电荷层和肖特基势垒不能产生EPIR效应;对同一样品采用直流两线法测量,其I-V曲线也为非线性,但却发生明显的EPIR效应.说明在Nd0.7Sr0.3MnO3陶瓷中发现的EPIR效应起源于样品与电极之间的接触界面,块体内的晶(相)界处虽能产生相似I-V特性,但却不能发生EPIR效应.

关键词:

Abstract

Polycrystalline ceramic Nd0.7Sr0.3MnO3 is synthesized using high-energy ball milling and post heat treatment method. The properties of electric transport are measured using direct current (DC) 4-wire and 2-wire methods. The results show that both the grain (phase) boundary and the electrode-bulk contact interface has interfacial resistance and space charge layer. The two kinds of space charge regions have greatly different effects on the DC transport: for the former, the I-V curve exhibits nonlinear characteristic and no EPIR effect takes place; for the later, however, an obvious EPIR effect is observed even if the I-V curve also shows nonlinear behaviour. It well suggests that for the ceramic Nd0.7Sr0.3MnO3, only the electrode-bulk contact interface can induce the EPIR effect although there is a similar nonlinear I-V characteristic for the grain (phase) boundary and the electrode-bulk contact interface.

Keywords:

作者及机构信息

1.
湖北大学物理学与电子技术学院,铁电压电材料与器件湖北省重点实验室,武汉 430062;

2.
燕山大学材料科学与工程学院,亚稳材料制备技术与科学国家重点实验室,秦皇岛 066004

基金项目: 国家自然科学基金(批准号:11174073,11074067)和教育部新世纪优秀人才支持计划(批准号:NCET-08-0674)资助的课题.

Authors and contacts

1.
Faculty of Physics and Electronic Technology, Hubei University, Wuhan 430062, China;

2.
State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, China

参考文献

[1]	Tokura Y, Tomioka Y 2000 J. Magn. Magn. Mater. 1999 1
[2]	Liu J M, Wang K F 2005 Prog. in Phys. 25 82 (in Chinese) [刘俊明、王克锋 2005 物理学进展 25 82]
[3]
[4]	Zhao Y G, Wang Y H, Zhang G M, Zhang B, Zhang X P, Yang C X, Lang P L, Zhu M H, Guan P C 2005 Appl. Phys. Lett. 86 122502
[5]
[6]
[7]	Hu F X, Gao J, Wu X S 2005 Phys. Rev. B 72 064428
[8]
[9]	Chen S S, Yang C P, Deng H, Sun Z G 2008 Acta Phys. Sin. 57(6) 3798 (in Chinese) [陈顺生、杨昌平、邓恒、孙志刚 2008 57 3798]
[10]
[11]	Gao J, Hu F X 2005 J. Appl. Phys. 97 10H706
[12]
[13]	Yang C P, Chen S S, Dai Q, Guo D H, Wang H 2007 Acta Phys. Sin. 56 4908 (in Chinese) [杨昌平、陈顺生、戴琪、郭定和、王浩 2007 56 4908].
[14]
[15]	Chen S S, Wang R L, Wang H, Yang C P 2010 J. Rare Earth 28 251
[16]	Chen S S, Yang C P, Wang H, Medvedeva I V, Brner K 2010 Mat. Sci. Eng. B 172 167
[17]
[18]	Liu S Q, Wu N J, Ignative A 2000 Appl. Phys. Lett. 76 2749
[19]
[20]
[21]	Sawa A, Fujii T, Kawasaki M, Tokura Y 2004 Appl. Phys. Lett. 85 4073
[22]	Baikalov A, Wang Y Q, Shen B, Lorenz B, Tsui S, Sun Y Y, Xue Y Y, Chu C W 2003 Appl. Phys. Lett. 83 957
[23]
[24]	Chen S S, Yang C P, Xiong L B, Wang R L, Yang F J, Wang H, Brner K 2010 Sol. Sta. Commun. 150 240
[25]
[26]
[27]	Tsui S, Baikalov A, Cmaidalka J, Sun Y Y, Wang Y Q, Xue Y Y, Chu C W, Chen L, Jacobson A J 2004 Appl. Phys. Lett. 85 317
[28]	Rozenberg M J, Inoue I H, Sanchez M J 2004 Phys. Rev. Lett. 92 178302
[29]
[30]
[31]	Strukov D B, Snider G S, Stewart D R, Williams R S 2008 Nature 453 80
[32]	Aoyama K, Waku K, Asanuma A, Uesu Y, Katsufuji T 2004 Appl. Phys. Lett. 85 1208
[33]
[34]	Yang R, Li M X, Yu W D, Gao X D, Shang D S, Liu X J, Cao X, Wang Q, Chen L D 2009 Appl. Phys. Lett. 95 072105
[35]
[36]
[37]	Tan G T, Chen Z H, Zhang X Z 2005 Acta Phys. Sin. 54 0379 (in Chinese) [谈国太、陈正豪、章晓中 2005 54 0379]
[38]
[39]	Venkataiah G, Krishna D C, Vithal M, Rao S S, Bhat S V, Prasad V, Subramanyam S V, Venugopal Reddy P 2005 Physic B 357 370
[40]	Kalyana Lakshmi Y, Venugopal Reddy P 2010 Sol. Sta. Sci. 12 1731
[41]
[42]
[43]	Muroi M, Street R, McCormick P G 2000 J. Appl. Phys. 87 3424
[44]	Zhang Q W, Saito Fumio 2000 J. Alloys Comps. 297 99
[45]
[46]
[47]	Chen S S 2010 MS Thesis (Wuhan: Hubei University) (in Chinese) [陈顺生 2010 硕士学位论文 (武汉:湖北大学)]
[48]	Hsu Daniel, Lin J G, Wu W F 2007 J. Magn. Magn. Mater. 310 978
[49]
[50]
[51]	Manuel V, Gabriel J, Silvia P D H, David C 2007 Physica B 398 321
[52]
[53]	Beck A, Bednorz J G, Gerber Ch, Rossel C, Widmer D 2000 Appl. Phys. Lett. 77 139
[54]	Sawa A, Fujii T, Kawasaki M, Tokura Y 2006 Appl. Phys. Lett. 88 232112
[55]
[56]	Shang D S, Wang Q, Chen L D, Dong R, Li X M, Zhang W Q 2006 Phys. Rev. B 73 245427
[57]
[58]	Jiao Z K, Cao G H 2005 Magnetoelectronics (Zhejiang: Zhejiang University Press) p355 (in Chinese) [焦正宽、曹光旱 2005 磁电子学 (浙江:浙江大学出版社) 第355页]
[59]
[60]
[61]	Chen S S, Yang C P, Ren C L, Wang R L, Wang H 2011 B.Mater.Sci. 34 1
[62]	Nakamura T, Homma K, Yakashi Y, Tai R, Nishio A, Tachibana K 2007 Surf. Coat. Technol. 201 9275
[63]
[64]	Deng H, Yang C P, Huang C,Xu L F, Sun Z G 2010 Acta Phys. Sin. 59 7390 (in Chinese) [邓恒、杨昌平、黄昌、徐玲芳、孙志刚 2010 59 7390]
[65]

施引文献

[1]	Tokura Y, Tomioka Y 2000 J. Magn. Magn. Mater. 1999 1
[2]	Liu J M, Wang K F 2005 Prog. in Phys. 25 82 (in Chinese) [刘俊明、王克锋 2005 物理学进展 25 82]
[3]
[4]	Zhao Y G, Wang Y H, Zhang G M, Zhang B, Zhang X P, Yang C X, Lang P L, Zhu M H, Guan P C 2005 Appl. Phys. Lett. 86 122502
[5]
[6]
[7]	Hu F X, Gao J, Wu X S 2005 Phys. Rev. B 72 064428
[8]
[9]	Chen S S, Yang C P, Deng H, Sun Z G 2008 Acta Phys. Sin. 57(6) 3798 (in Chinese) [陈顺生、杨昌平、邓恒、孙志刚 2008 57 3798]
[10]
[11]	Gao J, Hu F X 2005 J. Appl. Phys. 97 10H706
[12]
[13]	Yang C P, Chen S S, Dai Q, Guo D H, Wang H 2007 Acta Phys. Sin. 56 4908 (in Chinese) [杨昌平、陈顺生、戴琪、郭定和、王浩 2007 56 4908].
[14]
[15]	Chen S S, Wang R L, Wang H, Yang C P 2010 J. Rare Earth 28 251
[16]	Chen S S, Yang C P, Wang H, Medvedeva I V, Brner K 2010 Mat. Sci. Eng. B 172 167
[17]
[18]	Liu S Q, Wu N J, Ignative A 2000 Appl. Phys. Lett. 76 2749
[19]
[20]
[21]	Sawa A, Fujii T, Kawasaki M, Tokura Y 2004 Appl. Phys. Lett. 85 4073
[22]	Baikalov A, Wang Y Q, Shen B, Lorenz B, Tsui S, Sun Y Y, Xue Y Y, Chu C W 2003 Appl. Phys. Lett. 83 957
[23]
[24]	Chen S S, Yang C P, Xiong L B, Wang R L, Yang F J, Wang H, Brner K 2010 Sol. Sta. Commun. 150 240
[25]
[26]
[27]	Tsui S, Baikalov A, Cmaidalka J, Sun Y Y, Wang Y Q, Xue Y Y, Chu C W, Chen L, Jacobson A J 2004 Appl. Phys. Lett. 85 317
[28]	Rozenberg M J, Inoue I H, Sanchez M J 2004 Phys. Rev. Lett. 92 178302
[29]
[30]
[31]	Strukov D B, Snider G S, Stewart D R, Williams R S 2008 Nature 453 80
[32]	Aoyama K, Waku K, Asanuma A, Uesu Y, Katsufuji T 2004 Appl. Phys. Lett. 85 1208
[33]
[34]	Yang R, Li M X, Yu W D, Gao X D, Shang D S, Liu X J, Cao X, Wang Q, Chen L D 2009 Appl. Phys. Lett. 95 072105
[35]
[36]
[37]	Tan G T, Chen Z H, Zhang X Z 2005 Acta Phys. Sin. 54 0379 (in Chinese) [谈国太、陈正豪、章晓中 2005 54 0379]
[38]
[39]	Venkataiah G, Krishna D C, Vithal M, Rao S S, Bhat S V, Prasad V, Subramanyam S V, Venugopal Reddy P 2005 Physic B 357 370
[40]	Kalyana Lakshmi Y, Venugopal Reddy P 2010 Sol. Sta. Sci. 12 1731
[41]
[42]
[43]	Muroi M, Street R, McCormick P G 2000 J. Appl. Phys. 87 3424
[44]	Zhang Q W, Saito Fumio 2000 J. Alloys Comps. 297 99
[45]
[46]
[47]	Chen S S 2010 MS Thesis (Wuhan: Hubei University) (in Chinese) [陈顺生 2010 硕士学位论文 (武汉:湖北大学)]
[48]	Hsu Daniel, Lin J G, Wu W F 2007 J. Magn. Magn. Mater. 310 978
[49]
[50]
[51]	Manuel V, Gabriel J, Silvia P D H, David C 2007 Physica B 398 321
[52]
[53]	Beck A, Bednorz J G, Gerber Ch, Rossel C, Widmer D 2000 Appl. Phys. Lett. 77 139
[54]	Sawa A, Fujii T, Kawasaki M, Tokura Y 2006 Appl. Phys. Lett. 88 232112
[55]
[56]	Shang D S, Wang Q, Chen L D, Dong R, Li X M, Zhang W Q 2006 Phys. Rev. B 73 245427
[57]
[58]	Jiao Z K, Cao G H 2005 Magnetoelectronics (Zhejiang: Zhejiang University Press) p355 (in Chinese) [焦正宽、曹光旱 2005 磁电子学 (浙江:浙江大学出版社) 第355页]
[59]
[60]
[61]	Chen S S, Yang C P, Ren C L, Wang R L, Wang H 2011 B.Mater.Sci. 34 1
[62]	Nakamura T, Homma K, Yakashi Y, Tai R, Nishio A, Tachibana K 2007 Surf. Coat. Technol. 201 9275
[63]
[64]	Deng H, Yang C P, Huang C,Xu L F, Sun Z G 2010 Acta Phys. Sin. 59 7390 (in Chinese) [邓恒、杨昌平、黄昌、徐玲芳、孙志刚 2010 59 7390]
[65]

[1]	徐晗, 张璐. 空间电荷层效应对固体氧化物燃料电池三相界面附近氧空位传输的影响. , 2021, 70(12): 128801. doi: 10.7498/aps.70.20210012
[2]	徐晗, 张璐. 考虑空间电荷层效应的氧离子导体电解质内载流子传输特性. , 2021, 70(6): 068801. doi: 10.7498/aps.70.20201651
[3]	刘康淋, 廖瑞金, 赵学童. 声脉冲法空间电荷测量系统的研究. , 2015, 64(16): 164301. doi: 10.7498/aps.64.164301
[4]	吴美玲, 石大为, 阚芝兰, 王瑞龙, 丁益民, 肖海波, 杨昌平. La0.5Ca0.5MnO3内禀与界面电脉冲诱导电阻转变效应的比较. , 2013, 62(20): 207302. doi: 10.7498/aps.62.207302
[5]	石大为, 吴美玲, 杨昌平, 任春林, 肖海波, 王开鹰. Pr0.7Ca0.3MnO3陶瓷晶界势垒的交流特性. , 2013, 62(2): 026201. doi: 10.7498/aps.62.026201
[6]	安振连, 刘晨霞, 陈暄, 郑飞虎, 张冶文. 表层氟化聚乙烯中的空间电荷. , 2012, 61(9): 098201. doi: 10.7498/aps.61.098201
[7]	陈顺生, 杨昌平, 肖海波, 徐玲芳, 马厂. Nd1-xSrxMnO3中掺杂浓度对电脉冲诱导电阻转变效应的影响. , 2012, 61(14): 147301. doi: 10.7498/aps.61.147301
[8]	李飞, 肖刘, 刘濮鲲, 易红霞, 万晓声. 同心球之间空间电荷限制电流的简单理论. , 2011, 60(9): 097901. doi: 10.7498/aps.60.097901
[9]	曹蕾, 刘鹏, 周剑平, 王亚娟, 苏丽娜, 刘成. CaCu3Ti4O12-MgTiO3陶瓷的介电性能与I-V非线性特征. , 2011, 60(3): 037701. doi: 10.7498/aps.60.037701
[10]	陈曦, 王霞, 吴锴, 彭宗仁, 成永红. 温度梯度场对电声脉冲法空间电荷测量波形的影响. , 2010, 59(10): 7327-7332. doi: 10.7498/aps.59.7327
[11]	邓恒, 杨昌平, 黄昌, 徐玲芳. 双层钙钛矿La1.8Ca1.2Mn2O7磁性相关I-V非线性与电输运性质. , 2010, 59(10): 7390-7395. doi: 10.7498/aps.59.7390
[12]	赵敏, 安振连, 姚俊兰, 解晨, 夏钟福. 孔洞聚丙烯驻极体膜中空间电荷与孔洞击穿电荷的俘获特性. , 2009, 58(1): 482-487. doi: 10.7498/aps.58.482
[13]	杨强, 安振连, 郑飞虎, 张冶文. 线性低密度聚乙烯中空间电荷陷阱的能量分布与空间分布的关系. , 2008, 57(6): 3834-3839. doi: 10.7498/aps.57.3834
[14]	李倩, 王之国, 刘甦, 邢钟文, 刘楣. 钙钛矿结构Pr1－xCaxMnO3薄膜中电脉冲诱导电阻值变化的理论研究. , 2007, 56(3): 1637-1642. doi: 10.7498/aps.56.1637
[15]	杨学文, 郑家贵, 张静全, 冯良桓, 蔡伟, 蔡亚平, 李卫, 黎兵, 雷智, 武莉莉. CdTe/CdS太阳电池I-V，C-V特性研究. , 2006, 55(5): 2504-2507. doi: 10.7498/aps.55.2504
[16]	肖刘, 苏小保, 刘濮鲲. 基于行波管螺旋导电面模型的空间电荷场研究. , 2006, 55(10): 5150-5156. doi: 10.7498/aps.55.5150
[17]	郑飞虎, 张冶文, 吴长顺, 李吉晓, 夏钟福. 用于固体介质中空间电荷的压电压力波法与电声脉冲法. , 2003, 52(5): 1137-1142. doi: 10.7498/aps.52.1137
[18]	刘曾荣, 江霞妹, 韩志斌, 顾国庆. Josephson结的I-V曲线的子台阶. , 1990, 39(5): 823-829. doi: 10.7498/aps.39.823
[19]	钱敏, 潘涛, 刘曾荣. Josephson结的I-V曲线的理论分析. , 1987, 36(2): 149-156. doi: 10.7498/aps.36.149
[20]	谢家麟. 多次聚束的空间电荷波理论. , 1957, 13(1): 16-29. doi: 10.7498/aps.13.16

计量

文章访问数: 8230
PDF下载量: 645
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板