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本文对一类相变的Landau-deGennes模型(以下简称L-deG模型)进行了高斯近似和平均场近似计算,获得一些“临界指数”的数值。例如,在高斯近似下,α=0.5≠α',γ=1≠γ',ν=0.5≠ν'等等。我们计算了比热,并与液晶MBBA的实验进行了比较,讨论了向列相-各向同性液相相变与三重临界点的关系。文中特别着重讨论了一类与二类相变临界行为的异同。我们认为,二类相变的标度律结果不能简单地挪用到一类相变的情况。Calculations in Gaussian approximation and mean-field approximation are performed with the Landau-deGennes model of first order phase transitions. Some "critical exponents" are obtained. For example, in the Gaussian approximation, α = 0.5 ≠ α',γ= 1 ≠ γ', ν = 0.5 ≠ν', etc. Specific heat is calculated and compared with experimental results of liquid crystal MBBA. The nematic-isotropic phase transition is discussed in relation to tricritical points. In this paper, the similarities and differences of the critical properties between first and second order phase transitions are emphasized and discussed. In our opinion, results from scaling laws of second order transitions cannot be simply applied to the case of first order transitions.
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