新型电子俘获型材料β-Sr2SiO4:Eu2+, La3+长余辉和光激励发光性能的研究

程帅; 徐旭辉; 王鹏久; 邱建备

doi:10.7498/aps.64.017802

摘要

通过高温固相法在还原气体保护下制备出β-Sr2SiO4: Eu2+, La3+系列样品. 通过样品光谱显示, 光致发光、余辉及光激励发光中心均来自于Eu2+离子; 并且La3+ 的掺入有效增强光致发光、余辉及光激励发光强度. 热释光与余辉衰减测试证明, 与单掺Eu2+样品所具备的缺陷数量相比, 共掺La3+样品在浅陷阱区(T1区)较多的俘获中心数量是导致其余辉性能优化的主要因素; 其光激励发光强度的增强则归因于在深陷阱(T3区)的俘获中心数量增加. 共掺样品放置15h并在980nm红外激光激励后, 表现出光激励长余辉发光现象. 此现象的出现, 为电子俘获型材料的浅陷阱对深陷阱中的载流子再俘获过程的存在提供了直接证据. 因此, β-Sr2 SiO4: Eu2+, La3+ 材料可视为一种潜在的长余辉和光激励发光材料.

关键词:

长余辉 /
光激励 /
热释光

Abstract

A series of β-Sr2SiO4: Eu2+, La3+ phosphors have been synthesized via high temperature solid state reaction. Photoluminescence (PL), long persistent luminescence (LPL), and the photo-stimulated luminescence (PSL) suggest that Eu2+ ions occupy Sr(1) and Sr(2) sites. Significant enhancement of PL, LPL and PSL has been observed by co-doping La3+ in β-Sr2SiO4: Eu2+, La3+. Meanwhile, the introduction of La3+ ions increases significantly the intensities of the TL bands (T1 and T3 regions), and promotes the formation of a large number of traps in LPL and PSL. In addition, the observation of the PSPL(photo-stimulated long persistent luminescence) phenomenon demonstrates the occurrence of electrons which are retrapped by the shallow traps in the LPL process.

Keywords:

作者及机构信息

1.
云南省新材料制备与加工重点实验室, 昆明理工大学材料科学与工程学院, 昆明 650093

基金项目: 国家自然科学基金(批准号: 51272097, 61265004, 11204113)和云南省自然科学基金(批准号: 2011C13211709)资助的课题.

Authors and contacts

1.
Key Laboratory of Advanced Materials of Yunnan Province, College of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51272097, 61265004, 11204113), and the Natural Science Foundation of Yunnan Province, China (Grant No. 2011C13211709).

参考文献

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[3]	Nanto H, Hirai Y, Ikeda M, Kadota M, Nishishita J, Nasu S, Douguchi Y 1996 Sensor and Actuators A:Physical 53 223
[4]	Nanto H, Douguchi Y, Nishishita J, Kadota M, Kashiwagi N, Shinkawa T, and Nasu S 1997 Jpn. J. Appl. Phys. 36 421
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[7]	Sun X Y, Zhang J H, Zhang X, Luo Y S, and Wang X J 2008 J. Phys. D 41 195414
[8]	Sun X Y, Zhang J H, Zhang X, Luo Y S, Hao Z D, Wang X J 2009 J. Appl. Phys. 105 013501
[9]	Matsuzawa T, Aoki Y, Takeuchi N, Maruyama Y 1996 J. Electrochem. Soc. 143 2670
[10]	Lei B, Li B, Zhang H, Li W 2007 Opt. Mater. 29 1491
[11]	Qin Q S, Ma X L, Shao Y, Yang X Y, Sheng H F, Yang J Z, Yin Y, Zhang J C 2012 Acta Phys. Sin. 61 097804 (in Chinese) [秦青松, 马新龙, 邵宇, 杨星瑜, 盛鸿飞, 杨靖忠, 尹瑶, 张加驰 2012 61 097804]
[12]	Park J K, Lim M A, Kim C H, Park H D, Park J T, Choi S Y 2007 Appl. Phys. Lett. 82 683
[13]	Kim J S, Park Y H, Kim S M, Choi J C, Park H L 2005 Solid State Communications 133 445
[14]	Wang Z J, Yang Z P, Guo Q L, Li P L, Fu G S 2009 Chin. Phys. B 18 2068
[15]	Nag A, Kutty T R N 2004 J. Mater. Chem. 14 1598
[16]	Lakshminarasimhan N, Varadaraju U V 2005 J. Electrochem. Soc. 152 H152
[17]	Kim J S, Jeon P E Choi J C, Park H L 2005 Solid-State Commun. 133 187
[18]	Liu X, Zhang J H, Zhang X, Hao Z D, Qiao J, Dong X L 2013 Opt. let. 38 148

施引文献

[1]	Johnson E J, Kafalas J, Dyes W A 1982 Appl Phys. Lett. 40 993
[2]	Cho Y, Kim D S, Choe B, Lim H, Kim D 1997 Phys. Rev. B 56 R4375
[3]	Nanto H, Hirai Y, Ikeda M, Kadota M, Nishishita J, Nasu S, Douguchi Y 1996 Sensor and Actuators A:Physical 53 223
[4]	Nanto H, Douguchi Y, Nishishita J, Kadota M, Kashiwagi N, Shinkawa T, and Nasu S 1997 Jpn. J. Appl. Phys. 36 421
[5]	Yamashita S A, Ogawa N 1989 Phys. Status. Solidi B 118 89
[6]	Wang Y S, Wang J Y, Zhang X Q, Zhang G Y, Liu J, Li Z F, Li J, Xiong G N, Xu Z, Xu S R 1996 Acta Phys. Sin. 45 635 (in Chinese) [王永生, 王吉有, 张雪强, 张光寅, 刘健, 李增发, 李加, 熊光楠, 徐征, 徐舒瑢 1996 45 635]
[7]	Sun X Y, Zhang J H, Zhang X, Luo Y S, and Wang X J 2008 J. Phys. D 41 195414
[8]	Sun X Y, Zhang J H, Zhang X, Luo Y S, Hao Z D, Wang X J 2009 J. Appl. Phys. 105 013501
[9]	Matsuzawa T, Aoki Y, Takeuchi N, Maruyama Y 1996 J. Electrochem. Soc. 143 2670
[10]	Lei B, Li B, Zhang H, Li W 2007 Opt. Mater. 29 1491
[11]	Qin Q S, Ma X L, Shao Y, Yang X Y, Sheng H F, Yang J Z, Yin Y, Zhang J C 2012 Acta Phys. Sin. 61 097804 (in Chinese) [秦青松, 马新龙, 邵宇, 杨星瑜, 盛鸿飞, 杨靖忠, 尹瑶, 张加驰 2012 61 097804]
[12]	Park J K, Lim M A, Kim C H, Park H D, Park J T, Choi S Y 2007 Appl. Phys. Lett. 82 683
[13]	Kim J S, Park Y H, Kim S M, Choi J C, Park H L 2005 Solid State Communications 133 445
[14]	Wang Z J, Yang Z P, Guo Q L, Li P L, Fu G S 2009 Chin. Phys. B 18 2068
[15]	Nag A, Kutty T R N 2004 J. Mater. Chem. 14 1598
[16]	Lakshminarasimhan N, Varadaraju U V 2005 J. Electrochem. Soc. 152 H152
[17]	Kim J S, Jeon P E Choi J C, Park H L 2005 Solid-State Commun. 133 187
[18]	Liu X, Zhang J H, Zhang X, Hao Z D, Qiao J, Dong X L 2013 Opt. let. 38 148

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