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We present a new glass able to produce ultra-broadband yellow fluorescence. The luminescence system is Ce3+ doped low silica calcium aluminosilica glass excited by blue light emitting diode (LED). The glass is prepared by the conventional melting process. We analyze the luminescence properties of the samples by measuring their absorption spectra, excitation spectra, fluorescence spectra. Furthermore, we study the influence of excitation wavelength on the fluorescence intensity and peak wavelength. The doped glass combined with blue LED to obtain the white lighting is achieved. Besides we calculate the Commission Internationale de I'Eclairage chromaticity coordinate. Therefore these glasses have large potentials to be used as white lighting phosphor materials.
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Keywords:
- yellow emission /
- spectral characteristic /
- luminescent glass
[1] Li P L, Wang Z J, Wang Y, Yang Z P, Guo Q L, Li X, Yang Y M, Fu G S 2009 Acta Phys. Sin. 58 5831 (in Chinese) [李盼来, 王志军, 王颖, 杨志平, 郭庆林, 李旭, 杨艳民, 傅广生 2009 58 5831]
[2] Jayasimhadri M, Jang K, Lee H, Chen B, Yi S, Jeong J 2009 J. Appl. Phys. 106 3105
[3] Chen D P, Miyoshi H, Akai T, Yazawa T 2005 Appl. Phys. Lett. 86 231908
[4] Liu W, Chen D P, Miyoshi H, Kadono K, Akai T 2005 Chem. Lett. 34 1176
[5] Liu Y H, Qing W D, Gao W G, Hu Y S, He T, He H Q 2010 Acta Phys. Sin. 59 8200 (in Chinese) [刘元红, 庆卫东, 高文贵, 胡运生, 何涛, 何华强 2010 59 8200]
[6] Yang L Y, Yamashita M, Akai T 2009 Opt. Express 17 6688
[7] Babu P, Jang K H, Kim E S, Shi L, Seo H J, Lopez F E, Rodriguez-Mendoza U R, Lavin V, Vijaya R, Jayasankarm C K, Moorthy L R 2009 J. Appl. Phys. 105 013516
[8] Luo Q, Qiao X, Fan X, Yang H, Zhang X, Cui S, Wang L, Wang G 2009 J. Appl. Phys. 105 043506
[9] Gouveia-Neto A S, Bueno L A, do Nascimento R F, da Silva E A, da Costa E B, do Nascimento V B 2007 Appl. Phys. Lett. 91 091114
[10] Liu S, Zhao G, Lin X, Ying H, Liu J, Wang J, Han G 2008 J. Solid State Chem. 181 2725
[11] Fujita S, Sakamoto A, Tanabe S 2008 IEEE J. Sel. Top Quantum Electron. 14 1387
[12] Nishiura S, Tanabe S, Fujioka K, Fujimoto Y 2011 Opt. Mater. 33 688
[13] Sampaio J A, Catunda T, Gandra F, Gama S, Bento A C, Miranda L, Baesso M L 1999 J. Non-Cryst. Solids 247 202
[14] Jang H S, Young D 2007 Appl. Phys. Lett. 90 041906
[15] Jang H S, Kang J H, Won Y H, Lee S, Jeon D Y 2007 Appl. Phys. Lett. 90 71908
[16] Liu Z J, Dai N, Luan H, Sheng Y, Peng J, Jiang Z, Li H, Yang L, Li J 2010 Opt. Express 18 21138
[17] Sampaio J A, Gama S, Baesso M L, Catunda T 2005 J. Non-Cryst. Solids 351 1594
[18] de Sousa D F, Sampaio J A, Nunes L, Baesso M L, Bento A C, Miranda L 2000 Phys. Rev. B 62 3176
[19] Baesso M L, Bento A C, Duarte A R, Neto A M, Miranda L, Sampaio J A, Catunda T, Gama S, Gandra F 1999 J. Appl. Phys. 85 8112
[20] Utegulov Z N, Eastman M A, Prabakar S, Mueller K T, Hamad A Y, Wicksted J P, Dixon G S 2003 J. Non-Cryst. Solids 315 43
[21] Blasse G, Grabmaier B C 1994 Luminescent Materials (Berlin: Springer)
[22] Zeng X H, Zhao G J, Zhang L H, He X M, Hang Y, Li H J, Xu J 2005 Acta Phys. Sin. 54 612 (in Chinese) [曾雄辉, 赵广军, 张连翰, 何晓明, 杭寅, 李红军, 徐军 2005 54 612]
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[1] Li P L, Wang Z J, Wang Y, Yang Z P, Guo Q L, Li X, Yang Y M, Fu G S 2009 Acta Phys. Sin. 58 5831 (in Chinese) [李盼来, 王志军, 王颖, 杨志平, 郭庆林, 李旭, 杨艳民, 傅广生 2009 58 5831]
[2] Jayasimhadri M, Jang K, Lee H, Chen B, Yi S, Jeong J 2009 J. Appl. Phys. 106 3105
[3] Chen D P, Miyoshi H, Akai T, Yazawa T 2005 Appl. Phys. Lett. 86 231908
[4] Liu W, Chen D P, Miyoshi H, Kadono K, Akai T 2005 Chem. Lett. 34 1176
[5] Liu Y H, Qing W D, Gao W G, Hu Y S, He T, He H Q 2010 Acta Phys. Sin. 59 8200 (in Chinese) [刘元红, 庆卫东, 高文贵, 胡运生, 何涛, 何华强 2010 59 8200]
[6] Yang L Y, Yamashita M, Akai T 2009 Opt. Express 17 6688
[7] Babu P, Jang K H, Kim E S, Shi L, Seo H J, Lopez F E, Rodriguez-Mendoza U R, Lavin V, Vijaya R, Jayasankarm C K, Moorthy L R 2009 J. Appl. Phys. 105 013516
[8] Luo Q, Qiao X, Fan X, Yang H, Zhang X, Cui S, Wang L, Wang G 2009 J. Appl. Phys. 105 043506
[9] Gouveia-Neto A S, Bueno L A, do Nascimento R F, da Silva E A, da Costa E B, do Nascimento V B 2007 Appl. Phys. Lett. 91 091114
[10] Liu S, Zhao G, Lin X, Ying H, Liu J, Wang J, Han G 2008 J. Solid State Chem. 181 2725
[11] Fujita S, Sakamoto A, Tanabe S 2008 IEEE J. Sel. Top Quantum Electron. 14 1387
[12] Nishiura S, Tanabe S, Fujioka K, Fujimoto Y 2011 Opt. Mater. 33 688
[13] Sampaio J A, Catunda T, Gandra F, Gama S, Bento A C, Miranda L, Baesso M L 1999 J. Non-Cryst. Solids 247 202
[14] Jang H S, Young D 2007 Appl. Phys. Lett. 90 041906
[15] Jang H S, Kang J H, Won Y H, Lee S, Jeon D Y 2007 Appl. Phys. Lett. 90 71908
[16] Liu Z J, Dai N, Luan H, Sheng Y, Peng J, Jiang Z, Li H, Yang L, Li J 2010 Opt. Express 18 21138
[17] Sampaio J A, Gama S, Baesso M L, Catunda T 2005 J. Non-Cryst. Solids 351 1594
[18] de Sousa D F, Sampaio J A, Nunes L, Baesso M L, Bento A C, Miranda L 2000 Phys. Rev. B 62 3176
[19] Baesso M L, Bento A C, Duarte A R, Neto A M, Miranda L, Sampaio J A, Catunda T, Gama S, Gandra F 1999 J. Appl. Phys. 85 8112
[20] Utegulov Z N, Eastman M A, Prabakar S, Mueller K T, Hamad A Y, Wicksted J P, Dixon G S 2003 J. Non-Cryst. Solids 315 43
[21] Blasse G, Grabmaier B C 1994 Luminescent Materials (Berlin: Springer)
[22] Zeng X H, Zhao G J, Zhang L H, He X M, Hang Y, Li H J, Xu J 2005 Acta Phys. Sin. 54 612 (in Chinese) [曾雄辉, 赵广军, 张连翰, 何晓明, 杭寅, 李红军, 徐军 2005 54 612]
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