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声悬浮条件下环己烷液滴的蒸发凝固

杜人君 解文军

引用本文:
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声悬浮条件下环己烷液滴的蒸发凝固

杜人君, 解文军

Evaporation induced solidification of cyclohexane drops under acoustic levitation condition

Du Ren-Jun, Xie Wen-Jun
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  • 采用单轴式声悬浮方法研究了环己烷液滴的蒸发过程,发现环己烷液滴的蒸发可以使自身温度降至熔点以下并发生凝固.高速摄像实时观测表明,环己烷晶核开始形成于液滴赤道附近,并以枝晶方式长大,平均生长速度为12.5160.4 mm/s.进一步研究发现,声悬浮条件下平均Sherwood数与平均Nusselt数的比值Sh/Nu是在自然对流条件下的1.3倍,这表明声流边界层有效提高了环己烷液滴的蒸发速率而对传热的促进作用相对较小,因而可以使液滴降至更低温度,进而发生凝固.据此,提出了挥发性液体在声悬浮条件下发生蒸发凝固的必要条件.
    The evaporation process of a cyclohexane drop is investigated by single-axis acoustic levitation method. It is found that the evaporation of the cyclohexane drop results in the decrease of its temperature below the melting point, and leading to solidification. The real-time observation with a high speed camera shows that the cyclohexane nucleates near the equator of the drop surface and grows dendritically with an average velocity ranging from 12.5 to 160.4 mm/s. Further studies indicate that the ratio Sh/Nu of the average Sherwood number to Nusselt number under acoustic levitation condition is 1.3 times of that under natural convection condition. This suggests that the acoustic streaming boundary layer effectively strengthens the evaporation but has less promotion effect on the heat transfer. Therefore, the drop temperature declines to a lower value and the evaporation induced solidification occurs under acoustic levitation condition. Accordingly, a necessary condition for the occurrence of evaporation induced solidification of volatile liquids is proposed.
    • 基金项目: 国家自然科学基金(批准号:51071126)资助的课题.
    [1]

    Brandt E H 2001 Nature 413 474

    [2]

    Ohsaka K, Trinh E H 1989 J.Cryst. Growth 96 973

    [3]

    Trinh E H 1985 Rev. Sci. Instrum. 56 2059

    [4]

    Ohsaka K, Trinh E H 1990 J. Cryst. Growth 106 191

    [5]

    Trinh E H, Ohsaka K 1995 Int. J. Thermophy. 16 545

    [6]

    Santesson S, Nilsson S 2004 Anal. Bioanal. Chem. 378 1704

    [7]

    Shen C L, Xie W J, Wei B 2010 Phys. Rev. E 81 046305

    [8]

    Xie W J, Cao C D, Lü Y J, Wei B 2002 Phys. Rev. E 66 061601

    [9]

    Wang X D, Dong P, Yi G Y 2006 Acta Phys. Sin. 55 2092 (in Chinese) [王晓冬、董 鹏、仪桂云 2006 55 2092]

    [10]

    Hou H H, Sun X L, Shen Y M, Shao J D, Fan Z X, Yi K 2006 Acta Phys. Sin. 55 3124 (in Chinese) [侯海虹、孙喜莲、申雁鸣、邵建达、范正修、易 葵 2006 55 3124]

    [11]

    Zhang H Y, Chen K X, Zhu Y J, Chen Y M, He Y Y, Wu C Y, Wang J H, Liu S H 2002 Acta Phys. Sin. 51 444 (in Chinese) [张海燕、陈可心、朱燕娟、陈易明、何艳阳、伍春燕、王金华、刘颂豪 2002 51 444]

    [12]

    Trinh E H, Robey J I 1994 Phys. Fluids 6 3567

    [13]

    Yarin A L, Brenn G, Kastner O, Rensink D, Tropea C 1999 J. Fluid Mech. 399 151

    [14]

    Kawahara N, Yarin A L, Brenn G, Kastner O, Durst F 2000 Phys.Fluids 12 912

    [15]

    Tuckermann R, Puskar L, Zavabeti M, Sekine R, McNaughton D 2009 Anal. Bioanal. Chem. 394 1433

    [16]

    Deliβen F, Leiterer J, Bienert R, Emmerling F, Thünemann A F 2008 Anal. Bioanal. Chem. 392 161

    [17]

    Tuckermann R, Bauerecker S, Cammenga H K 2007 J. Colloid Interface Sci. 310 559

    [18]

    Xie W J, Cao C D, Wei B B 1999 Acta Phys. Sin. 48 250 (in Chinese) [解文军、曹崇德、魏炳波 1999 48 250]

    [19]

    Xie W J, Wei B 2004 Phys. Rev. E 70 046611

    [20]

    Poling B E, Prausnitz J M, O’Connell J P (Translated by Zhao H L, Wang F K, Chen S K) 2006 The Properties of Gases and Liquids (Beijing: Chemical Industry Press) p171 (in Chinese) [波林 B. E.、普劳斯尼茨 J. M.、奥康奈尔 J. P.著 赵红玲、王凤坤、陈圣坤译 2006 气液物性估算手册(北京:化学工业出版社)第171页]

    [21]

    Crank J 1975 The Mathematics of Diffusion (2nd ed) (Oxford: Clarendon Press) p169

  • [1]

    Brandt E H 2001 Nature 413 474

    [2]

    Ohsaka K, Trinh E H 1989 J.Cryst. Growth 96 973

    [3]

    Trinh E H 1985 Rev. Sci. Instrum. 56 2059

    [4]

    Ohsaka K, Trinh E H 1990 J. Cryst. Growth 106 191

    [5]

    Trinh E H, Ohsaka K 1995 Int. J. Thermophy. 16 545

    [6]

    Santesson S, Nilsson S 2004 Anal. Bioanal. Chem. 378 1704

    [7]

    Shen C L, Xie W J, Wei B 2010 Phys. Rev. E 81 046305

    [8]

    Xie W J, Cao C D, Lü Y J, Wei B 2002 Phys. Rev. E 66 061601

    [9]

    Wang X D, Dong P, Yi G Y 2006 Acta Phys. Sin. 55 2092 (in Chinese) [王晓冬、董 鹏、仪桂云 2006 55 2092]

    [10]

    Hou H H, Sun X L, Shen Y M, Shao J D, Fan Z X, Yi K 2006 Acta Phys. Sin. 55 3124 (in Chinese) [侯海虹、孙喜莲、申雁鸣、邵建达、范正修、易 葵 2006 55 3124]

    [11]

    Zhang H Y, Chen K X, Zhu Y J, Chen Y M, He Y Y, Wu C Y, Wang J H, Liu S H 2002 Acta Phys. Sin. 51 444 (in Chinese) [张海燕、陈可心、朱燕娟、陈易明、何艳阳、伍春燕、王金华、刘颂豪 2002 51 444]

    [12]

    Trinh E H, Robey J I 1994 Phys. Fluids 6 3567

    [13]

    Yarin A L, Brenn G, Kastner O, Rensink D, Tropea C 1999 J. Fluid Mech. 399 151

    [14]

    Kawahara N, Yarin A L, Brenn G, Kastner O, Durst F 2000 Phys.Fluids 12 912

    [15]

    Tuckermann R, Puskar L, Zavabeti M, Sekine R, McNaughton D 2009 Anal. Bioanal. Chem. 394 1433

    [16]

    Deliβen F, Leiterer J, Bienert R, Emmerling F, Thünemann A F 2008 Anal. Bioanal. Chem. 392 161

    [17]

    Tuckermann R, Bauerecker S, Cammenga H K 2007 J. Colloid Interface Sci. 310 559

    [18]

    Xie W J, Cao C D, Wei B B 1999 Acta Phys. Sin. 48 250 (in Chinese) [解文军、曹崇德、魏炳波 1999 48 250]

    [19]

    Xie W J, Wei B 2004 Phys. Rev. E 70 046611

    [20]

    Poling B E, Prausnitz J M, O’Connell J P (Translated by Zhao H L, Wang F K, Chen S K) 2006 The Properties of Gases and Liquids (Beijing: Chemical Industry Press) p171 (in Chinese) [波林 B. E.、普劳斯尼茨 J. M.、奥康奈尔 J. P.著 赵红玲、王凤坤、陈圣坤译 2006 气液物性估算手册(北京:化学工业出版社)第171页]

    [21]

    Crank J 1975 The Mathematics of Diffusion (2nd ed) (Oxford: Clarendon Press) p169

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出版历程
  • 收稿日期:  2010-12-17
  • 修回日期:  2011-02-10
  • 刊出日期:  2011-11-15

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