基于OH自由基A2Σ + →X2Πr 电子带系发射光谱的温度测量技术

彭志敏; 丁艳军; 杨乾锁; 姜宗林

doi:10.7498/aps.60.053302

摘要

本文基于OH自由基所固有的分子结构特征,通过分子光谱理论系统地分析和计算了OH自由基A2Σ + →X2Πr 电子带系发射光谱的谱线跃迁频率、能级分布以及爱因斯坦自发发射跃迁概率等重要参数.同时结合实际的光谱实验,分析了谱线的自然展宽、碰撞展宽、多普勒展宽以及仪器展宽等各种展宽因素对谱线线型的影响,从理论上计算了任意转动温度、振动温度以及谱线展宽条件下OH自由基A2Σ

关键词:

Based on the inherent molecular structure characteristics of the OH radicals, the energy level distribution, the transition frequency and Einstein spontaneous emission transition probability are systematically analyzed and numerically studied. Meanwhile, combined with the spectra experiments, the natural broadening, collision broadening, Doppler broadening and instrumental broadening effects on spectral line shape are analyzed. The dependence of the spectral profile on the rotational temperature, the vibrational temperature, and the spectral function are numerically explored in certain ranges. The corresponding numerical results are also discussed for the emission spectra thermometry, which provides a theoretical basis for the emission thermometry. In experimental, the emission spectra of OH (A2Σ+→X2Πr) system of the hydrogen flames are recorded by the optical multi-channel analyzer and studied. By the fitting of the experimental spectra to the numerically calculated spectra, the corresponding rotational and vibrational temperatures of the hydrogen flames are determined, respectively.

Keywords:

emission spectroscopy /
rotational temperature /
vibrational temperature /
Einstein spontaneous emission transition probability

作者及机构信息

(1)清华大学热能系,电力系统与发电设备控制与仿真国家重点实验室,北京 100084; (2)中国科学院力学研究所,高温气体动力学重点实验室,北京 100190

Authors and contacts

(1)Laboratory of High Temperature Gas Dynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China; (2)State Key Laboratory of Power Systems, Dept of Thermal Engineering, Tsinghua University, Beijing 100084, China

参考文献

[1]	Levin D A 1999 AIAA paper 3567 1
[2]	Anokhin E M, Ivanova T Y, Koudriavtsev N N, Starikovskii A Y 2007 AIAA paper 814 1
[3]	Hyun S Y, Chul P, Chang K S 2008 AIAA paper 1276 1
[4]	Sharma S P, Gillespie W 1991 J. Thermophys Heat Transfer 5 257
[5]	Djameel R, Michel D, Raymond B 1999 J. Thermophys Heat Transfer 13 219
[6]	Jeong E, Jeung I S, Byrne S O, Houwing A F 2008 J. Propul Power 24 1258
[7]	Griffiths A D, Houwing A F P 2005 Appl. Opt. 44 6653
[8]	Liu D B, Yang D, Jiang R G, Li Y, Wang J D 2002 Spectrosc Spect Anal. 23 670 (in Chinese) [刘大斌、杨栋、蒋荣光、李燕、王俊德 2002 光谱学与光谱分析 23 670]
[9]	Dong L F, Ran J X, Yin Z Q, Mao Z G 2002 Spectrosc Spect Anal. 25 1184 (in Chinese) [董丽芳、冉俊霞、尹增谦、毛志国 2005 光谱学与光谱分析 25 1184]
[10]	Laux C O, Kruger C H, Zare R N 2003 Plasma Sources Sci. T. 12 125
[11]	Laux C O, Gessman R J, Kruger C H, Roux F, Michaud F, Davis S P 2001 J. Quant Spectrosc RA 68 473
[12]	Chun F S, Tracy M, Fang Y Y 2003 AIAA paper 3750 1
[13]	James S, Serguei Z U. S. Patent 6914246b2
[14]	Chul P 1985 NASA TM 86707
[15]	Laux C O 1993 Ph. D. Thesis (US: Stanford University)
[16]	Fujita K, Takashi A B E 1997 The Institute of Space and Astronautical Science Report 669 1
[17]	Liu L Y, Zhang J L, Ma T C, Deng X L 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [刘莉莹、张家良、马腾才、邓新绿 2002 光谱学与光谱分析 22 1013] [18] Zhang J L 2002 Ph. D. Thesis (Dalian: Dalian University of Technology) (in Chinese) [张家良 2002 博士学位论文(大连理工大学)]
[18]	Tu X, Lu S Y, Yan J H, Ma Z Y, Pan X C, Cen K F 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [屠昕、陆胜勇、严建华、马增益、潘新潮、岑可法 2006 光谱学与光谱分析 26 1785]
[19]	Tu X 2007 Ph. D. Thesis (Hangzhou: ZheJiang University) (in Chinese) [屠昕 2007 博士学位论文(浙江大学)]
[20]	Dong L F, Li Y H, Chen W J, Li X C 2007 Spectrosc Spect Anal. 27 2406 (in Chinese) [董丽芳、李永辉、陈文军、李雪辰 2007 光谱学与光谱分析 27 2406] [22] Jorge L, David R C 1996 SRI Report No. MP 96-001
[21]	Jorge L, David R C 1998 J. Chem. Phys. 109 439
[22]	Kristen L S, Jorge L, Jay B. J, David R C 1997 J. Chem. Phys. 106 6262
[23]	Charles D I 2000 J. Phys. D: Appl. Phys. 33 1697
[24]	Dieke G H, Crosswhite H M 1962, J. Quant Spectrosc RA 2 97
[25]	Lawrence S B, Yu H C, James A G, Broadfoot A L, Rainer A D, Edmond M 2004 AIAA paper 1257 1
[26]	Hinkley R K, Hall J A, Walker T E H, Richards W G 1972 J. Phys. B: Atom. Molec. Phys. 5 204
[27]	David G D, Michael F A 1982 The Astrophysical Journal 258 864
[28]	Bennett R F M 1970 Mon. Not. R. astr. Soc. 47 35
[29]	Peng Z M 2010 Ph. D. Thesis (Beijing: Institute of Mechanics, Chinese Academy of Sciences) (in Chinese) [彭志敏 2010 博士学位论文(中国科学院力学研究所)]

施引文献

[1]	Levin D A 1999 AIAA paper 3567 1
[2]	Anokhin E M, Ivanova T Y, Koudriavtsev N N, Starikovskii A Y 2007 AIAA paper 814 1
[3]	Hyun S Y, Chul P, Chang K S 2008 AIAA paper 1276 1
[4]	Sharma S P, Gillespie W 1991 J. Thermophys Heat Transfer 5 257
[5]	Djameel R, Michel D, Raymond B 1999 J. Thermophys Heat Transfer 13 219
[6]	Jeong E, Jeung I S, Byrne S O, Houwing A F 2008 J. Propul Power 24 1258
[7]	Griffiths A D, Houwing A F P 2005 Appl. Opt. 44 6653
[8]	Liu D B, Yang D, Jiang R G, Li Y, Wang J D 2002 Spectrosc Spect Anal. 23 670 (in Chinese) [刘大斌、杨栋、蒋荣光、李燕、王俊德 2002 光谱学与光谱分析 23 670]
[9]	Dong L F, Ran J X, Yin Z Q, Mao Z G 2002 Spectrosc Spect Anal. 25 1184 (in Chinese) [董丽芳、冉俊霞、尹增谦、毛志国 2005 光谱学与光谱分析 25 1184]
[10]	Laux C O, Kruger C H, Zare R N 2003 Plasma Sources Sci. T. 12 125
[11]	Laux C O, Gessman R J, Kruger C H, Roux F, Michaud F, Davis S P 2001 J. Quant Spectrosc RA 68 473
[12]	Chun F S, Tracy M, Fang Y Y 2003 AIAA paper 3750 1
[13]	James S, Serguei Z U. S. Patent 6914246b2
[14]	Chul P 1985 NASA TM 86707
[15]	Laux C O 1993 Ph. D. Thesis (US: Stanford University)
[16]	Fujita K, Takashi A B E 1997 The Institute of Space and Astronautical Science Report 669 1
[17]	Liu L Y, Zhang J L, Ma T C, Deng X L 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [刘莉莹、张家良、马腾才、邓新绿 2002 光谱学与光谱分析 22 1013] [18] Zhang J L 2002 Ph. D. Thesis (Dalian: Dalian University of Technology) (in Chinese) [张家良 2002 博士学位论文(大连理工大学)]
[18]	Tu X, Lu S Y, Yan J H, Ma Z Y, Pan X C, Cen K F 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [屠昕、陆胜勇、严建华、马增益、潘新潮、岑可法 2006 光谱学与光谱分析 26 1785]
[19]	Tu X 2007 Ph. D. Thesis (Hangzhou: ZheJiang University) (in Chinese) [屠昕 2007 博士学位论文(浙江大学)]
[20]	Dong L F, Li Y H, Chen W J, Li X C 2007 Spectrosc Spect Anal. 27 2406 (in Chinese) [董丽芳、李永辉、陈文军、李雪辰 2007 光谱学与光谱分析 27 2406] [22] Jorge L, David R C 1996 SRI Report No. MP 96-001
[21]	Jorge L, David R C 1998 J. Chem. Phys. 109 439
[22]	Kristen L S, Jorge L, Jay B. J, David R C 1997 J. Chem. Phys. 106 6262
[23]	Charles D I 2000 J. Phys. D: Appl. Phys. 33 1697
[24]	Dieke G H, Crosswhite H M 1962, J. Quant Spectrosc RA 2 97
[25]	Lawrence S B, Yu H C, James A G, Broadfoot A L, Rainer A D, Edmond M 2004 AIAA paper 1257 1
[26]	Hinkley R K, Hall J A, Walker T E H, Richards W G 1972 J. Phys. B: Atom. Molec. Phys. 5 204
[27]	David G D, Michael F A 1982 The Astrophysical Journal 258 864
[28]	Bennett R F M 1970 Mon. Not. R. astr. Soc. 47 35
[29]	Peng Z M 2010 Ph. D. Thesis (Beijing: Institute of Mechanics, Chinese Academy of Sciences) (in Chinese) [彭志敏 2010 博士学位论文(中国科学院力学研究所)]

[1]	杨文斌, 张华磊, 齐新华, 车庆丰, 周江宁, 白冰, 陈爽, 母金河. 非平衡等离子体流场相干反斯托克斯拉曼散射光谱计算及振转温度测量. , 2024, 73(15): 154202. doi: 10.7498/aps.73.20240455
[2]	杜永权, 刘文耀, 朱爱民, 李小松, 赵天亮, 刘永新, 高飞, 徐勇, 王友年. 双频容性耦合等离子体相分辨发射光谱诊断. , 2013, 62(20): 205208. doi: 10.7498/aps.62.205208
[3]	宁凯杰, 张庆礼, 周鹏宇, 杨华军, 许兰, 孙敦陆, 殷绍唐. Yb3+:Gd2SiO5晶体的结构和光谱性能. , 2012, 61(12): 128102. doi: 10.7498/aps.61.128102
[4]	王琪, 樊群超, 孙卫国, 冯灏. 精确研究NbN分子d1+b1+电子态跃迁的P线系发射光谱. , 2012, 61(4): 043301. doi: 10.7498/aps.61.043301
[5]	翟晓东, 丁艳军, 彭志敏, 罗锐. N2第二正带系发射光谱的理论计算及实验研究. , 2012, 61(12): 123301. doi: 10.7498/aps.61.123301
[6]	樊群超, 孙卫国, 李会东, 冯灏. CO电子基态P线系跃迁谱线的理论研究. , 2011, 60(6): 063301. doi: 10.7498/aps.60.063301
[7]	蒲昱东, 杨家敏, 靳奉涛, 张璐, 丁永坤. 辐射输运实验中的Al等离子体发射光谱研究. , 2011, 60(4): 045210. doi: 10.7498/aps.60.045210
[8]	郭卿超, 张家良, 刘莉莹, 王德真. 大气压Ar射频容性放电模式转变的温度表征. , 2011, 60(2): 025207. doi: 10.7498/aps.60.025207
[9]	朱竹青, 王晓雷. 飞秒激光空气等离子体发射光谱的实验研究. , 2011, 60(8): 085205. doi: 10.7498/aps.60.085205
[10]	高勋, 宋晓伟, 郭凯敏, 陶海岩, 林景全. 飞秒激光烧蚀硅表面产生等离子体的发射光谱研究. , 2011, 60(2): 025203. doi: 10.7498/aps.60.025203
[11]	彭志敏, 丁艳军, 翟晓东. 基于火焰发射光谱的转动温度和振动温度的测量. , 2011, 60(10): 104702. doi: 10.7498/aps.60.104702
[12]	唐京武, 黄笃之, 易有根. Au激光等离子体X射线发射光谱的理论研究. , 2010, 59(11): 7769-7774. doi: 10.7498/aps.59.7769
[13]	哈静, 何寿杰, 段平光, 李霞, 韩育宏, 王龙. 有机溶液中圆锥泡声致发光. , 2009, 58(1): 602-606. doi: 10.7498/aps.58.602
[14]	董丽芳, 杨丽, 李永辉, 张彦召, 岳晗. 空气介质阻挡放电单个微放电通道发光强度及振动激发温度的空间分布. , 2009, 58(12): 8461-8466. doi: 10.7498/aps.58.8461
[15]	丁君, 杨秋红, 唐在峰, 徐军, 苏良碧. Er3+/Yb3+共掺的氧化镧钇透明陶瓷的光谱性能研究. , 2007, 56(4): 2207-2211. doi: 10.7498/aps.56.2207
[16]	牛田野, 曹金祥, 刘磊, 刘金英, 王艳, 王亮, 吕铀, 王舸, 朱颖. 低温氩等离子体中的单探针和发射光谱诊断技术. , 2007, 56(4): 2330-2336. doi: 10.7498/aps.56.2330
[17]	董丽芳, 冉俊霞, 毛志国. 大气压氩气微放电通道中电子激发温度的时间演化. , 2005, 54(5): 2167-2171. doi: 10.7498/aps.54.2167
[18]	黄松, 辛煜, 宁兆元. 使用发射光谱对感应耦合CF4/CH4等离子体中C2基团形成机理的研究. , 2005, 54(4): 1653-1658. doi: 10.7498/aps.54.1653
[19]	王志军, 董丽芳, 尚勇. 电子助进化学气相沉积金刚石中发射光谱的蒙特卡罗模拟. , 2005, 54(2): 880-885. doi: 10.7498/aps.54.880
[20]	宋峰, 谭浩, 商美茹, 张光寅, 程振祥, 陈焕矗. 掺Er3+的NaY(WO4)2晶体的光谱特性. , 2002, 51(10): 2375-2379. doi: 10.7498/aps.51.2375

计量

文章访问数: 11639
PDF下载量: 1000
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板