The temperature dependencies of electrical conductivity of sulfur-doped C60 films were measured after annealing at 433K. The results showed that the conductive activation energy decreased and electrical conductivity of C60 films increased after sulfur-doping. From the logarithmic curve of the electrical conductivity versus temperature,a transition zone was seen where the conductivity did not vary with temperature exponentially;however,when above 388K or below 368K,sulfur-doped C60 films showed obvious semiconductive properties. This phenomenon is due to the phase transformation of sulfur molecules in the film.