The collisional energy pooling process in a sodium vapor [ Na(3PJ)+Na(3PJ′)→Na(nLJ″)+Na(3S1/2)] is experimentally investigated. At sufficiently low sodium densities,such that only the optically excited 3PJ state is significantly populated, the ratios of nLJ″ fluorescence intensities and the relative density of Na(3P1/2) versus the density of Na(3P3/2) are measured. The ratios of rate coefficients k(nLJ′)(J, J′) relative to k5S(3/2,3/2) are given for nLJ″= 4D3/2, 4D5/2, 4F5/2, 4F7/2, and 5S1/2, each for J = J′ =1/2 and 3/2. At high sodium densities, the 3P states are populated in nearly statistical ratios, the ratios of the k(nLJ″)(1/2,3/2) relative to k5S(3/2,3/2) are obtained.