纳米组装相变储热材料的热设计前沿

冯妍卉; 冯黛丽; 褚福强; 邱琳; 孙方远; 林林; 张欣欣

doi:10.7498/aps.71.20211776

摘要

本文简单回顾了固液相变储热材料发展历程, 重点针对纳米多孔定形相变材料, 从材料层面的研发设计, 到热物理层面的微观限域空间负载、结晶、导热机理, 乃至围绕异相/异质匹配提出的显著提升相变蓄传热性能的强化手段进行了总结. 同时, 指出了目前受制于单一尺度孔径无法兼顾储释热的密度和速率的现状, 并探讨在此基础上借助新型多级尺度孔径的骨架材料以突破瓶颈的可能. 最后, 系统梳理了与之伴随的一系列亟待解决的科学问题、机遇和挑战.

关键词:

相变 /
纳米组装材料 /
热设计 /
前沿

Abstract

The present paper briefly reviews the development progress of solid-liquid phase change materials, particularly the nano-porous shape-stabilized phase change materials. We outline the designs and syntheses of the heat storage functional materials and the thermophysical mechanism of loading, crystallization, and thermal transport in nano-confined space. Besides, the remarkable methods to enhance the heat storage and release performance of heterogeneous materials are included. However, at present, the single-size porous materials cannot satisfy the requirements for high heat storage/release rate and great thermal energy density simultaneously. Based on this, the novel hierarchical porous frameworks materials are explored to overcome these obstacles. For this purpose, some scientific problems, opportunities, and challenges are summarized at the end of this paper.

Keywords:

作者及机构信息

北京科技大学能源与环境工程学院, 北京　100083

通信作者: 冯妍卉, yhfeng@me.ustb.edu.cn

基金项目: 国家重点研发计划(批准号: 2018YFA0702300)、国家自然科学基金(批准号: 51876007, 52176054)和北京市自然科学基金(批准号: 3192022)资助的课题

Authors and contacts

School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China

Corresponding author: Feng Yan-Hui, yhfeng@me.ustb.edu.cn

Funds: Project supported by the National Key Research and Development Program of China (Grant No. 2018YFA0702300), the National Natural Science Foundation of China (Grant Nos. 51876007, 52176054), and the Natural Science Foundation of Beijing, China (Grant No. 3192022).

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参考文献

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施引文献

图 1 纳米孔组装相变材料机理探究工作

Fig. 1. Research on the mechanism of nanopore assembly phase change materials.

下载: 全尺寸图片幻灯片

map

[1]	Feng D, Feng Y, Qiu L, Li P, Zang Y, Zou H, Yu Z, Zhang X 2019 Renew. Sust. Energ. Rev. 109 578 Google Scholar
[2]	Feng D, Li P, Feng Y, Yan Y, Zhang X 2021 Micropor. Mesopor. Mat. 310 110631 Google Scholar
[3]	Li A, Wang J, Dong C, Dong W, Atinafu D, Chen X, Gao H, Wang G. 2018 Appl. Energ. 217 369 Google Scholar
[4]	Yu Z, Feng Y, Feng D, Zhang X 2021 Micropor. Mesopor. Mat. 312 110781 Google Scholar
[5]	Feng D, Feng Y, Zang Y, Li P, Zhang X 2019 Micropor. Mesopor. Mat. 280 124 Google Scholar
[6]	Zhang J, Feng Y, Yuan H, Feng D, Zhang X, Wang G 2015 Comp. Mater. Sci. 109 300 Google Scholar
[7]	Feng D, Feng Y, Li P, Zang Y, Wang C, Zhang X 2020 Micropor. Mesopor. Mat. 292 109756 Google Scholar
[8]	Qiu L, Zou H, Wang X, Feng Y, Zhang X, Zhao J, Zhang X, Li Q 2019 Carbon 141 497 Google Scholar
[9]	Xu D, Hanus R, Xiao Y, Wang S, Synder G, Hao Q 2018 Mater. Today Phys. 6 53 Google Scholar
[10]	Qiu L, Guo P, Kong Q, Tan C, Liang K, Wei J, Tey J, Feng Y, Zhang X, Tay B 2019 Carbon 145 725 Google Scholar
[11]	Xu Y, Wang X, Hao Q 2021 Compos. Commum. 24 100617 Google Scholar
[12]	Zheng K, Sun F, Zhu J, Ma Y, Li X, Tang D, Wang F, Wang X 2016 ACS Nano. 10 7792 Google Scholar
[13]	Zhou Y, Wu S, Zhu P, Wu F, Liu F, Murugadoss V, Winchester W, Nautiyal A, Wang Z, Guo Z 2020 ES Mater. Manuf. Mass. Tran. 7 4 Google Scholar
[14]	Chang G, Sun F, Wang L, Che Z, Wang X, Wang J, Kim M, Zheng H 2019 ACS Appl. Mater. Inter. 11 26507 Google Scholar
[15]	Wang S, Xu D, Gurunathan R, Snyder G, Hao Q 2020 J. Materiomics. 6 248 Google Scholar
[16]	Hao Q, Garg J 2021 ES Mater. Manuf. Mass. Tran. 14 36 Google Scholar
[17]	Feng D, Zang Y, Li P, Feng Y, Yan Y, Zhang X 2021 Compos. Sci. Technol. 210 108832 Google Scholar
[18]	Tang J, Yang M, Yu F, Chen X, Tan L, Wang G 2017 Appl. Energ. 187 514 Google Scholar
[19]	Wang H, Xu Q, Luo Q, Song Y, Tian Y, Chen M, Xuan Y, Jin Y, Jia Y, Li Y, Ding Y 2021 Int. J. Heat. Mass. Tran. 175 121405 Google Scholar
[20]	Feng D, Nan J, Feng Y, Yan Y, Zhang X 2021 Int. J. Heat. Mass. Tran. 179 121748 Google Scholar

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纳米组装相变储热材料的热设计前沿