Cr4+掺杂Li1.14Zn1.43SiO4透明微晶玻璃近红外宽带光谱特性

马红萍; 刘平; 杨清华; 邓德刚

doi:10.7498/aps.62.177801

摘要

采用高温熔融法和热处理制备了Cr4+掺杂Li1.14Zn1.43SiO4微晶玻璃, 探讨了不同热处理温度下样品的物相、微观形貌及发光性能. 结果表明: 580℃热处理2h得到的微晶玻璃, Li1.14Zn1.43SiO4微晶的粒径约为5nm, 在808nm的二极管激发下, 可观察到中心波长位于1226nm, 半高宽为230nm的近红外宽带发射峰, 荧光寿命约为200.731.71s. 随着热处理温度的升高, Cr4+离子所处的晶体场环境发生了变化, 且可以观察到样品吸收光谱发生微弱的蓝移, 而荧光光谱发生少量的红移, 分析了晶体场环境变化对样品发光性能的影响.

关键词:

Abstract

Cr4+-doped transparent Li1.14Zn1.43SiO4 glass-ceramics were prepared by high-temperature melting and subsequent heat-treatment, and the crystalline, microstructural, and luminescence properties of the products prepared by different-temperature heat-treatment were investigated. Results showed that the glass-ceramics heat-treated at 580 ℃ for 2 h contained nano crystallines of about 5 nm in size, and a broadband infrared emission centered at 1226nm with full width at half maximum of more than 230 nm and a decay time of about 200.07 s were observed by exciting with an 808 nm laser diode. Mean while, it is believed that the crystalline field environment of Cr4+ is changed with the increase of heat-treatment temperature, which results in blue shift and red shift of absorption and fluorescence spectra, respectively.

Keywords:

作者及机构信息

1.
上海理工大学材料科学与工程学院, 上海 200093;

2.
浙江科技学院机械与汽车工程学院, 杭州 310012;

3.
中国计量学院材料科学与工程学院, 杭州 310018

基金项目: 国家自然科学基金(批准号: 61008042)资助的课题.

Authors and contacts

1.
Colllege of Materials Science and Engineering, University of Shanghai for Science and Tecnology, Shanghai 200093, Chian;

2.
School of Mechanical & automotive Engineering, Zhejiang University of Science and Technology, Hangzhou 310012, China;

3.
College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, Chian

Funds: Project supported by the National Nature Science Foundation of China (Grant Nos. 61008042).

参考文献

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[3]	Mori A, Ohishi Y, Sudo S 1997 Electron. Lett. 33 863
[4]	Němec P, Frumar M 2002 J. Non-cryst. Solids 299-302 1018
[5]	Shen X, Nie Q H, X T F, G Y 2005 Acta Phys. Sin. 54 2379 (in Chinese) [沈祥, 聂秋华, 徐铁峰, 高媛 2005 54 2379]
[6]	Xu S Q, Yang Z M, Dai S X, Yang J H, Hu L L, Jiang Z H 2003 J. Alloys Comp. 313 311
[7]	Kuck S 2001 Appl. Phys. B 72 515
[8]	Petricevic V, Gayen S, Alfano R 1988 Appl. Phys. Lett. 53 2590
[9]	Kuck S, Petermann K, Pohlmann U, Huber G 1995 Phys. Rev. B 51 17323
[10]	Petricevic V, Gayen S, Alfano R 1989 Opt. Lett. 14 612
[11]	Lo C, Huang K, Chen J, Chuang C, Lai C, Huang S, Lin Y, Yeh P 2005 Opt. Lett. 30 129
[12]	Sharonov M, Bykov A, Owen S, Petricevic V, Alfano R, Beall G, Borrelli N 2004 J. Opt. Soc. Am. B Opt. Phys. 21 2046
[13]	Bykov A, Sharonov M, Petricevic V, Popovb I, Isaacs L, Steiner J, Alfano R 2006 J. Non-Crys. Solids 352 5508
[14]	Yamazaki H, Tanabe S P 2003 Amplifiers and their Applications Otaru, Japan, July 6, 2003 pWC1
[15]	Pinckney L, Beall G Proc SPIE 4452, Inorganic Optical Materials III Transition San Diego, Canada, November 2 2001 p93
[16]	Sakata S, Uedab N, Fujiia I, Kawazoe H 1994 J. Non-Crys. Solids 178 98
[17]	Caird J A, Payne T A, Staver P R, Ramponi A J, Chase L L 1988 J. Quant. Electron. 24 1077
[18]	Takahiro M, Masanori T, Hiromichi T, Kenji M 1997 J. Non-Crys. Solids 220 139
[19]	Jousseaume C, Vivien D, Kahn-Harari A, Malkin B 2003 Opt. Mater. 24 143
[20]	Zhu S X, Yang B C, Lin Y J, Pan P C, Zhu J K 1992 Acta Phys. Sin. 41 1234 (in Chinese) [祝生祥, 杨宝成, 林远济, 潘佩聪, 祝继康 1992 41 1234]
[21]	Peng X, Tanabe S 2002 Opt. Mater. 20 63
[22]	Henderson B, Imbusch G F 1989 Optical Spectroscopy of Inorganic Solids (Oxford: Clarendon Press) p51
[23]	Lever A B P 1984 Inorganic Electronic Spectroscopy (Amsterdam: Elsevier Press) p115
[24]	Sugano S, Tanabe Y, Kamimura H 1970 Multiplets of Transition-Metal Ions in Crystals (New York and London: Academic Press) p521
[25]	Zhuang Y, Teng Y, Luo J, Zhu B, Chi Y, Wu E, Zeng H, Qiu J 2009 Appl. Phys. Lett. 95 111913
[26]	Jousseaume C, Vivien D, Kahn-Harari A, Derouet J 2003 J. Appl. Phys. 93 600
[27]	Cao G X, Hu H F, Zhou S 2002 Acta Opt. Sinica 22 226 (in Chinese) [曹国喜, 胡和方, 周世 2002 光学学报 22 226]
[28]	Zhou S F 2008 Ph. D. Dissertation (Hangzhou: Zhejiang University) (in Chinese) [周时凤 2008 博士学位论文 (杭州: 浙江大学) ]
[29]	Duan X L, Yuan D R, Cheng X F, Wang Z M, Sun Z H, Luan C N, Xu D, Lv M K 2004 Opt. Mater. 25 69
[30]	Calvez L, Ma H L, Lucas J, Zhang X H 2007 Adv. Mater. 19 12

施引文献

[1]	Snitzer E, Woodcock R 1965 Appl. Phys. Lett. 6 45
[2]	Mears R, Reekie L, Poole S, Payne D 1986 Electron. Lett. 22 159
[3]	Mori A, Ohishi Y, Sudo S 1997 Electron. Lett. 33 863
[4]	Němec P, Frumar M 2002 J. Non-cryst. Solids 299-302 1018
[5]	Shen X, Nie Q H, X T F, G Y 2005 Acta Phys. Sin. 54 2379 (in Chinese) [沈祥, 聂秋华, 徐铁峰, 高媛 2005 54 2379]
[6]	Xu S Q, Yang Z M, Dai S X, Yang J H, Hu L L, Jiang Z H 2003 J. Alloys Comp. 313 311
[7]	Kuck S 2001 Appl. Phys. B 72 515
[8]	Petricevic V, Gayen S, Alfano R 1988 Appl. Phys. Lett. 53 2590
[9]	Kuck S, Petermann K, Pohlmann U, Huber G 1995 Phys. Rev. B 51 17323
[10]	Petricevic V, Gayen S, Alfano R 1989 Opt. Lett. 14 612
[11]	Lo C, Huang K, Chen J, Chuang C, Lai C, Huang S, Lin Y, Yeh P 2005 Opt. Lett. 30 129
[12]	Sharonov M, Bykov A, Owen S, Petricevic V, Alfano R, Beall G, Borrelli N 2004 J. Opt. Soc. Am. B Opt. Phys. 21 2046
[13]	Bykov A, Sharonov M, Petricevic V, Popovb I, Isaacs L, Steiner J, Alfano R 2006 J. Non-Crys. Solids 352 5508
[14]	Yamazaki H, Tanabe S P 2003 Amplifiers and their Applications Otaru, Japan, July 6, 2003 pWC1
[15]	Pinckney L, Beall G Proc SPIE 4452, Inorganic Optical Materials III Transition San Diego, Canada, November 2 2001 p93
[16]	Sakata S, Uedab N, Fujiia I, Kawazoe H 1994 J. Non-Crys. Solids 178 98
[17]	Caird J A, Payne T A, Staver P R, Ramponi A J, Chase L L 1988 J. Quant. Electron. 24 1077
[18]	Takahiro M, Masanori T, Hiromichi T, Kenji M 1997 J. Non-Crys. Solids 220 139
[19]	Jousseaume C, Vivien D, Kahn-Harari A, Malkin B 2003 Opt. Mater. 24 143
[20]	Zhu S X, Yang B C, Lin Y J, Pan P C, Zhu J K 1992 Acta Phys. Sin. 41 1234 (in Chinese) [祝生祥, 杨宝成, 林远济, 潘佩聪, 祝继康 1992 41 1234]
[21]	Peng X, Tanabe S 2002 Opt. Mater. 20 63
[22]	Henderson B, Imbusch G F 1989 Optical Spectroscopy of Inorganic Solids (Oxford: Clarendon Press) p51
[23]	Lever A B P 1984 Inorganic Electronic Spectroscopy (Amsterdam: Elsevier Press) p115
[24]	Sugano S, Tanabe Y, Kamimura H 1970 Multiplets of Transition-Metal Ions in Crystals (New York and London: Academic Press) p521
[25]	Zhuang Y, Teng Y, Luo J, Zhu B, Chi Y, Wu E, Zeng H, Qiu J 2009 Appl. Phys. Lett. 95 111913
[26]	Jousseaume C, Vivien D, Kahn-Harari A, Derouet J 2003 J. Appl. Phys. 93 600
[27]	Cao G X, Hu H F, Zhou S 2002 Acta Opt. Sinica 22 226 (in Chinese) [曹国喜, 胡和方, 周世 2002 光学学报 22 226]
[28]	Zhou S F 2008 Ph. D. Dissertation (Hangzhou: Zhejiang University) (in Chinese) [周时凤 2008 博士学位论文 (杭州: 浙江大学) ]
[29]	Duan X L, Yuan D R, Cheng X F, Wang Z M, Sun Z H, Luan C N, Xu D, Lv M K 2004 Opt. Mater. 25 69
[30]	Calvez L, Ma H L, Lucas J, Zhang X H 2007 Adv. Mater. 19 12

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