蠕变镍基单晶高温合金微观结构与界面特征的X射线小角散射研究

孙光爱; 陈波; 吴二冬; 闫冠云; 黄朝强; 李武会; 吴忠华; 柳义; 王劼

doi:10.7498/aps.60.016102

摘要

利用SAXS技术对蠕变过程中不同尺度范围的微观结构变化分析表明X射线小角散射(SAXS)与中子小角散射(SANS)测量的二维散射图具有明显的差异,由散射强度曲线的变化说明了蠕变过程中二次析出γ'相形貌和不同区域尺寸特征的改变情况.分析结果表明二次析出γ'相存在两类特征尺寸,在蠕变过程中沿[100]或[010]方向的变化趋势类似,均是在第一和第二阶段有所减小,在第三阶段又有所增大,相较而言,特征尺寸较大的γ'相变化也较为显著.二次析出γ'相在蠕变第二阶段元素扩散最严重,相表面最粗糙,在第三阶段两相界面又进一

关键词:

Abstract

The two-dimensional scattering patterns for micro-structural changes during creep observed by SAXS are different from that obtained by SANS technique. The changes in morphology and size characteristics of different regions of the secondary γ' precipitates have been demonstrated by the variation of SAXS scattering intensity. The results show that the secondary γ' precipitates have two types of feature sizes, which have similar trends of change during the creep process characterized by decreasing in the first and second stage and increasing in the final stage. As comparison shows, the larger γ' precipitates have more noticeable changes. The elements of the secondary γ' precipitates diffuse seriously in the second stage with the character of creep 15 h, the surfaces of γ' phase are blurred, and interfaces of two-phase become clear again in the final stage. Due to the increasing size or the reducing number of the secondary γ' phase, the total ares of interfaces between the secondary γ' precipitates and matrix phase then decreases.

Keywords:

作者及机构信息

(1)中国工程物理研究院核物理与化学研究所,绵阳 621900; (2)中国科学院高能物理研究所同步辐射国家实验室,北京 100049; (3)中国科学院金属研究所材料科学国家实验室,沈阳 110016; (4)中国科学院上海应用物理研究所上海光源国家科学中心,上海 201800

基金项目: 国家高技术研究发展计划(批准号:2009AA03Z535)和中国工程物理研究院核物理与化学研究所创新基金 (批准号:2009CX01)资助的课题.

Authors and contacts

(1)Insitute of High Energy Physics, CAS, Beijings 100049, China; (2)Institute of Nuclear Physics and Chemistry, CAEP, Mianyang 621900, China; (3)Institute of Shanghai Apply Physics, CAS, Shanghai 201800, China; (4)National Laboratory for Materials Science, IMR CAS, Sehnyang 110016, China

参考文献

[1]	Mughrabi H, Tetzlaff U 2000 Adv. Eng. Mater. 2 319
[2]	Roger C R 2006 The superalloys fundamentals and applications (Cambridge: Cambridge University Press) p91
[3]	Ma S, Brown D, Bourke M A M, Daymond M R, Majumdar B S 2005 Mater. Sci. Eng. A 399 144
[4]	Wu E D, Zhang J, Chen B, Sun G A, Ji V, Hughes D, Pirling T 2008 J. Phys.: Condens. Matter 20 104255
[5]	Sun G A, Chen B, Chen H, Wu E D, Zhang J, Ji V, Hughes D, Pirling T 2009 Acta Phys. Sin. 58 2549 (in Chinese)[孙光爱、陈波、陈华、吴二冬、张俊、稽宁、Hughes D、 Pirling T 2009 58 2549]
[6]	Yu Q M, Yue Z F, Wen Z X 2008 Mater. Sci. Eng. A 477 319
[7]	Wu E, Li J C, Zhang J, Wang S C, Xie G, Zhang J, Chen B, Sun G A, Ji V, Hughes D, Pirling T 2008 Metall. Mater. Trans. A 39 3141
[8]	Jacques A, Diologent F, Bastie P 2004 Mater. Sci. Eng. A 387-389 944
[9]	Gilles R, Mukherji D, Hoelzel M, Strunz P 2006 Acta Mater. 54 1307
[10]	Biermann H, Strehler M, Mughrabi H 1996 Metall. Mater. Trans. A 27 1003
[11]	Link T, Epishin A, Bruckner U, Portella P 2000 Acta Mater. 48 1981
[12]	Guinier A, Fournet G 1955 Small-angle scattering of X-rays (New York: Wiley Press)
[13]	Zhang J X, Wang J C, Harada H, Koizumi Y 2005 Acta Materialia 53 4623
[14]	Yu J J, Sun X F, Zhao N R, Jin T, Guan H R, Hu Z Q 2007 Mater. Sci. Eng. A 460-461 420
[15]	Zhang J X, Murakumo T, Koizumi Y, Kobayashi T, Harada H 2003 Acta Mater. 51 5073
[16]	Zrnik J, Strunz P, Maldini M, Wiedenmann A, Davydov V 2008 J. Phys.Condens.Matter 20 104261
[17]	Ratel N, Bruno G, Deme B 2005 J. Phys.Condens.Matter 17 7061
[18]	Rogante M, Lebedev V T 2008 Mater. Desig. 29 1060
[19]	Veron M, Bastie P 1997 Acta Mater. 45 3277
[20]	Du X M, Wu E D, Dong B Z, Wu Z H, Yuan X Z 2008 Acta Phys. Sin. 57 5782 (in Chinese) [杜晓明、吴二冬、董宝中、吴忠华、苑学众 2008 57 5782]
[21]	Ratel N 2007 Investigation of the strain induced rafting of γ' particles in single crystals nickel based superalloys p72, Dissertation, Joseph Fourier University.
[22]	Gilles R, Mukherji D, Strunz P, Barbier B, Wiedenmann A, Wahi R P 1998 Scripta Mater. 38 803
[23]	Qin X Z, Guo J T, Yuan C, Hou J S, Ye H Q 2008 Mater. Lett. 62 258
[24]	Gilles R, Mukherji D, Strunz P, Barbier B, Wiedenmann A, Wahi R P 1998 Phys. B 241-243 347
[25]	Gilles R, Mukherji D, Strunz P, Lieske S, Wiedenmann A, Wahi R P 1998 Scripta Mater. 39 715
[26]	Zhu Y P 2008 X-ray Small Angle Scattering- theory, testing, calculation and application (Beijing: Chemical Industry Press)p39 (in Chinese)[朱育平 2008 小角X射线散射─理论、测试、计算及应用 (北京:化学工业出版社)第39页]
[27]	Ratel N, Deme B, Bastie P, Caron P 2008 Scripta Mater. 59 1167
[28]	Brass A M, Chene J 2000 Scripta Mater. 43 913
[29]	Strunz P, Mukherji D, Nath O, Gilles R, Rosler J 2006 Phys. B 385-386 626
[30]	Schmidt P W 1991 J. Appl. Cryst. 24 414
[31]	Nabarro F R N 1996 Metall. Mater. Trans. A 27 513
[32]	Svoboda J, Lukas P 1996 Acta Mater. 44 2557
[33]	Meng Z F 1996 Small-angle X-ray scattering theory and application (Changchun: Jilin Science and Technology Press)p126(in Chinese)[孟昭富 1996 小角X射线散射理论及应用(长春:吉林科学技术出版社)第126页]

施引文献

[1]	Mughrabi H, Tetzlaff U 2000 Adv. Eng. Mater. 2 319
[2]	Roger C R 2006 The superalloys fundamentals and applications (Cambridge: Cambridge University Press) p91
[3]	Ma S, Brown D, Bourke M A M, Daymond M R, Majumdar B S 2005 Mater. Sci. Eng. A 399 144
[4]	Wu E D, Zhang J, Chen B, Sun G A, Ji V, Hughes D, Pirling T 2008 J. Phys.: Condens. Matter 20 104255
[5]	Sun G A, Chen B, Chen H, Wu E D, Zhang J, Ji V, Hughes D, Pirling T 2009 Acta Phys. Sin. 58 2549 (in Chinese)[孙光爱、陈波、陈华、吴二冬、张俊、稽宁、Hughes D、 Pirling T 2009 58 2549]
[6]	Yu Q M, Yue Z F, Wen Z X 2008 Mater. Sci. Eng. A 477 319
[7]	Wu E, Li J C, Zhang J, Wang S C, Xie G, Zhang J, Chen B, Sun G A, Ji V, Hughes D, Pirling T 2008 Metall. Mater. Trans. A 39 3141
[8]	Jacques A, Diologent F, Bastie P 2004 Mater. Sci. Eng. A 387-389 944
[9]	Gilles R, Mukherji D, Hoelzel M, Strunz P 2006 Acta Mater. 54 1307
[10]	Biermann H, Strehler M, Mughrabi H 1996 Metall. Mater. Trans. A 27 1003
[11]	Link T, Epishin A, Bruckner U, Portella P 2000 Acta Mater. 48 1981
[12]	Guinier A, Fournet G 1955 Small-angle scattering of X-rays (New York: Wiley Press)
[13]	Zhang J X, Wang J C, Harada H, Koizumi Y 2005 Acta Materialia 53 4623
[14]	Yu J J, Sun X F, Zhao N R, Jin T, Guan H R, Hu Z Q 2007 Mater. Sci. Eng. A 460-461 420
[15]	Zhang J X, Murakumo T, Koizumi Y, Kobayashi T, Harada H 2003 Acta Mater. 51 5073
[16]	Zrnik J, Strunz P, Maldini M, Wiedenmann A, Davydov V 2008 J. Phys.Condens.Matter 20 104261
[17]	Ratel N, Bruno G, Deme B 2005 J. Phys.Condens.Matter 17 7061
[18]	Rogante M, Lebedev V T 2008 Mater. Desig. 29 1060
[19]	Veron M, Bastie P 1997 Acta Mater. 45 3277
[20]	Du X M, Wu E D, Dong B Z, Wu Z H, Yuan X Z 2008 Acta Phys. Sin. 57 5782 (in Chinese) [杜晓明、吴二冬、董宝中、吴忠华、苑学众 2008 57 5782]
[21]	Ratel N 2007 Investigation of the strain induced rafting of γ' particles in single crystals nickel based superalloys p72, Dissertation, Joseph Fourier University.
[22]	Gilles R, Mukherji D, Strunz P, Barbier B, Wiedenmann A, Wahi R P 1998 Scripta Mater. 38 803
[23]	Qin X Z, Guo J T, Yuan C, Hou J S, Ye H Q 2008 Mater. Lett. 62 258
[24]	Gilles R, Mukherji D, Strunz P, Barbier B, Wiedenmann A, Wahi R P 1998 Phys. B 241-243 347
[25]	Gilles R, Mukherji D, Strunz P, Lieske S, Wiedenmann A, Wahi R P 1998 Scripta Mater. 39 715
[26]	Zhu Y P 2008 X-ray Small Angle Scattering- theory, testing, calculation and application (Beijing: Chemical Industry Press)p39 (in Chinese)[朱育平 2008 小角X射线散射─理论、测试、计算及应用 (北京:化学工业出版社)第39页]
[27]	Ratel N, Deme B, Bastie P, Caron P 2008 Scripta Mater. 59 1167
[28]	Brass A M, Chene J 2000 Scripta Mater. 43 913
[29]	Strunz P, Mukherji D, Nath O, Gilles R, Rosler J 2006 Phys. B 385-386 626
[30]	Schmidt P W 1991 J. Appl. Cryst. 24 414
[31]	Nabarro F R N 1996 Metall. Mater. Trans. A 27 513
[32]	Svoboda J, Lukas P 1996 Acta Mater. 44 2557
[33]	Meng Z F 1996 Small-angle X-ray scattering theory and application (Changchun: Jilin Science and Technology Press)p126(in Chinese)[孟昭富 1996 小角X射线散射理论及应用(长春:吉林科学技术出版社)第126页]

[1]	刘昱, 贺西平, 贺升平. 多晶材料散射模型及识别实验研究. , 2024, 73(3): 034302. doi: 10.7498/aps.73.20231578
[2]	李哲夫, 贾彦彦, 刘仁多, 徐玉海, 王光宏, 夏晓彬, 沈卫祖. 质子辐照对永磁合金微观结构演化的研究. , 2018, 67(1): 016104. doi: 10.7498/aps.67.20172025
[3]	李哲夫, 贾彦彦, 刘仁多, 徐玉海, 王光宏, 夏晓彬. Sm2Co17型永磁合金的辐照效应研究. , 2017, 66(22): 226101. doi: 10.7498/aps.66.226101
[4]	管鹏飞, 王兵, 吴义成, 张珊, 尚宝双, 胡远超, 苏锐, 刘琪. 不均匀性：非晶合金的灵魂. , 2017, 66(17): 176112. doi: 10.7498/aps.66.176112
[5]	卞西磊, 王刚. 非晶合金的离子辐照效应. , 2017, 66(17): 178101. doi: 10.7498/aps.66.178101
[6]	段芳莉, 王明, 刘静. 摩擦导致的聚合物表层微观结构改变. , 2015, 64(6): 066801. doi: 10.7498/aps.64.066801
[7]	唐杰, 杨梨容, 王晓军, 张林, 魏成富, 陈擘威, 梅杨. 高压对大块(PrNd)xAl0.6Nb0.5Cu0.15B1.05Fe97.7-x合金微观结构和性能的影响. , 2012, 61(24): 240701. doi: 10.7498/aps.61.240701
[8]	于松楠, 吴汉华, 陈根余, 袁鑫, 李乐. Al(OH)3溶胶浓度对TC4钛合金微弧氧化膜特性的影响. , 2011, 60(2): 028104. doi: 10.7498/aps.60.028104
[9]	孙光爱, 陈波, 吴二冬, 李武会, 张功, 汪小琳, V. Ji, T. Pirling, D. Hughes. 中子衍射分析时效处理对镍基单晶高温合金相结构的影响. , 2011, 60(8): 086102. doi: 10.7498/aps.60.086102
[10]	孙光爱, Darren Hughes, Thilo Pirling, Vincent Ji, 陈波, 陈华, 吴二冬, 张俊. 中子衍射法研究单晶镍基高温合金热机械疲劳引起的应力和晶格错配. , 2009, 58(4): 2549-2555. doi: 10.7498/aps.58.2549
[11]	侯兆阳, 刘丽霞, 刘让苏, 田泽安. Al-Mg合金熔体快速凝固过程中微观结构演化机理的模拟研究. , 2009, 58(7): 4817-4825. doi: 10.7498/aps.58.4817
[12]	李怀林, 杨文, 杨启法. JLF-1钢高温循环变形后硬度与微观结构的数值关系. , 2009, 58(13): 338-S342. doi: 10.7498/aps.58.338
[13]	范鲜红, 陈波, 关庆丰. 质子辐照对纯铝薄膜微观结构的影响. , 2008, 57(3): 1829-1833. doi: 10.7498/aps.57.1829
[14]	李岫梅, 刘涛, 郭朝晖, 朱明刚, 李卫. 稀土含量对速凝工艺制备(Nd,Dy)-(Fe,Al)-B合金结构和磁性能的影响. , 2008, 57(6): 3823-3827. doi: 10.7498/aps.57.3823
[15]	陈中军, 王维, 蔡泉, 陈兴, 吴忠华, 李蓉萍, 车传强, 潘伟. 用SAXS和XRD方法研究TiO2纳米颗粒微观结构. , 2008, 57(9): 5793-5799. doi: 10.7498/aps.57.5793
[16]	徐锦锋, 代富平, 魏炳波. 急冷条件下Cu-Pb偏晶合金的相分离研究. , 2007, 56(7): 3996-4003. doi: 10.7498/aps.56.3996
[17]	冯文然, 阎殿然, 何继宁, 陈光良, 顾伟超, 张谷令, 刘赤子, 杨思泽. 反应等离子喷涂纳米TiN涂层的显微硬度及微观结构研究. , 2005, 54(5): 2399-2402. doi: 10.7498/aps.54.2399
[18]	关庆丰, 安春香, 秦颖, 邹建新, 郝胜志, 张庆瑜, 董闯, 邹广田. 强流脉冲电子束应力诱发的微观结构. , 2005, 54(8): 3927-3934. doi: 10.7498/aps.54.3927
[19]	周炳卿, 刘丰珍, 朱美芳, 谷锦华, 周玉琴, 刘金龙, 董宝中, 李国华, 丁琨. 利用x射线小角散射技术研究微晶硅薄膜的微结构. , 2005, 54(5): 2172-2175. doi: 10.7498/aps.54.2172
[20]	潘梦霄, 曹兴忠, 李养贤, 王宝义, 薛德胜, 马创新, 周春兰, 魏龙. 氧化钒薄膜微观结构的研究. , 2004, 53(6): 1956-1960. doi: 10.7498/aps.53.1956

计量

文章访问数: 9064
PDF下载量: 829
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板