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将晶格振动的平面波线性组合得到一组充分反映杂质格位对称性的正则模(对称“驻波”)。任一对称类型的驻波的频谱分布只与整个格波的频谱分布差一个常数因子。使用对称分析得出电声子耦合导致杂质中心吸收或荧光带变宽的位差效应中的对称驻波选择定则,指出参与电声子耦合的声子的频率基本上遍布于全部格波的频谱,并且定性地估计了纵波声子的耦合强度对波长的函数关系的轮廓;从而对Williams位形坐标理论的本质作出了批判性的阐述。其次,讨论了在掺有铁族元素的刚玉晶体的宽带上出现先行线(或称系列线)的问题,指出了一般文献在这一问题上存在着的某些错误概念和格波频谱上临界点(k=0的除外)与先行线之间可能有的联系。文中也给出了有关对称驻波的数学分析,并以具体图象表明了对称驻波与孤立集团模型中的振动模之间的联系。For considering the electron-phonon coupling in the problem of impurity absorption band, a set of normal modes of lattice vibration were formed by the linear combination of plane (running) waves in order to present fully the site symmetry of the impurity. The symmetric (standing) waves of a definite type are characterized by an irreducible representation of the site group. The frequency distribution function of the phonons of a certain symmetry type is that of the lattice vibration divided by a constant. The phonons involved in the transition of an absorption band are restricted to certain symmetry types but no selection on the frequency may be found. The configuration coordinate approximation of Williams et al. was critically examined at this stage. The dependence of the coupling strength on the frequency of phonons was qualitatively discussed and the possible importance of the critical points of the frequency distribution was remarked. The mathematical analysis of symmetric standing waves was given in details. The relation between this set of normal modes of lattice vibration and those of an isolated cluster containing a central ion and the ligands was demonstrated.
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