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为提升钇钡铜氧(YBCO)高温超导带材的临界载流能力,本研究创新性地采用质子辐照技术对工程实用化YBCO带材进行缺陷调控。基于4.5MV静电加速器材料辐照终端,系统开展了3MeV质子束流在不同注量下的辐照实验,成功在超导体中构建高密度、低维度的可控人工钉扎中心。这种缺陷工程通过为磁通线创造低能量钉扎位点,显著抑制了磁通蠕动现象并增强钉扎作用,从而显著削弱外磁场对临界电流(Ic)的抑制作用。实验数据显示,在注量率为8×1016 p/cm2的辐照条件下,样品在4.2K@6.5T极端工况下的临界电流实现了8倍的突破性提升,同时在20K@5T、30K@4T下临界电流密度最大提升因子分别也达到5.5倍、4.8倍。这一性能突破显著增强了超导带材在低温高场环境中的应用潜力,尤其适用于离子加速器、聚变反应堆等对高性能超导磁体有迫切需求的前沿领域。研究证实,离子辐照技术无需改变YBCO带材的现有制备工艺,即可通过缺陷工程实现临界性能的高效优化,为超导材料的实用化性能调控提供了一条工艺兼容性强、可行性高的技术路径。This research proposes an innovative method that proton irradiation technology for defect control in practical engineering YBCO tapes,to improve the critical current density of YBCO high-temperature superconducting tapes in high magnetic fields.Based on the material irradiation terminal of a 4.5 MV electrostatic accelerator at Peking University, systematic irradiation experiments were conducted using 3 MeV proton beams on YBCO superconducting tapes at different fluence rates, successfully constructing high-density, low-dimensional controllable artificial pinning centers in the high superconducting tapes. This defect engineering significantly suppresses the flux creep phenomenon and enhances the pinning effect by creating low-energy pinning sites for flux lines, thereby significantly weakening the inhibitory effect of external magnetic fields on critical current (Ic). Comparative analysis of superconducting tapes before and after irradiation, including superconducting transition temperature, superconducting critical performance, and critical current density on magnetic field dependence.As the irradiation dose increases, high-density point defects (vacancies, interstitial atoms, etc.) and a small number of vacancy clusters are implanted inside the superconducting tape, resulting in a corresponding decrease in the superconducting phase. Therefore, as the dose increases, the orderliness of the superconducting phase in the superconducting tape decreases sharply, leading to a gradual widening of the superconducting transition temperature zone. By measuring the hysteresis loops of samples irradiated with different doses of protons and calculating the critical current density Jc based on the Bean model, the experimental data show that under irradiation conditions with a fluence rate of 8×1016 P/cm2, the critical current of the sample under extreme operating conditions of 4.2K@6.5T achieved an 8-fold breakthrough improvement. Meanwhile, the maximum improvement factors in critical current density at 20K@5T and 30K@4T were also 5.5 times and 4.8 times, respectively. The logarithmic curve was fitted using the Jc ∝ B– α power exponent model to obtain the power parameterα values of 0.276, 0.361, and 0.397 for the variation of critical current density with magnetic field at three temperature ranges of 4.2K, 20K, and 30K, respectively. This indicates that the superconducting tape irradiated with protons will form more effective strong pinning centers at lower temperatures, reducing the dependence of the critical current density of the superconducting tape on the magnetic field.This performance breakthrough significantly enhances the application potential of high superconducting tapes in low-temperature and high magnetic fields environments, especially in frontier fields such as particle accelerators and fusion reactors, where there is an urgent demand for high-performance superconducting magnets. The study confirms that proton irradiation technology can achieve efficient optimization of critical performance through defect engineering without altering the existing preparation process of YBCO tapes, providing a highly feasible and process-compatible technical path for practical performance control of superconducting materials.
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Keywords:
- YBCO /
- Proton irradiation /
- Pinning centers /
- Critical current density
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