非贵金属表面增强拉曼散射基底的研究进展

刘小红; 姜珊; 常林; 张炜

doi:10.7498/aps.69.20200788

摘要

表面增强拉曼散射(surface-enhanced Raman scattering, SERS)在分析检测领域中具有重要地位, 然而随着其不断发展, 贵金属SERS基底在实际应用中受到限制. 基于C, Ti, Zn, Cu, Mo, W等非贵金属纳米材料的SERS基底相比于贵金属基底具有更优异的经济性、稳定性、选择性以及生物相容性等, 逐渐被广泛研究和应用. 并且由于其化学增强占主导的特性, 非贵金属基底为SERS化学增强机理的研究提供了理想的平台. 因此, 本文对近年来非贵金属SERS基底的发展进行了综述, 讨论了不同材料的增强机理及SERS性能, 并探讨了其未来的研究与发展方向.

关键词:

Abstract

Surface-enhanced Raman scattering (SERS) is of great importance in analytical science, the noble-metal such as gold and silver are widely used in SERS research and applications. However, noble-metal based substrates are hampered in practical application. As for comparison, the Non-noble metal especially the semiconductor materials are the emerging SERS research frontier. Non-noble metal (such as C, Ti, Zn, Cu, Mo, W, etc.) nanomaterials based SERS substrate have been widely studied and applied due to their superior stability, selectivity, biocompatibility and low cost comparing to noble metal materials. As the chemical enhancement dominate its total SERS signals, it also provides an ideal platform for the investigation of chemical enhancement mechanism. In this review, we explored the development of non-noble metal SERS substrates, focusing on its enhancement mechanism and SERS performance of different materials as well as the future development direction.

Keywords:

non-noble metal materials /
surface-enhanced Raman scattering substrate /
semiconductor /
Raman spectroscopy

作者及机构信息

1.
重庆青年职业技术学院, 重庆　400712

2.
中国科学院重庆绿色智能技术研究院, 重庆　400714

通信作者: 张炜, andyzhangwei@163.com

基金项目: 国家自然科学基金(批准号: 61575196)、重庆市自然科学基金(批准号: cstc2019jcyj-msxmX0663)、重庆市教委科学技术研究项目(批准号: KJQN201904102)和北碚区基础研究与前沿探索项目(批准号: 2019-2)资助的课题

Authors and contacts

1.
Chongqing Youth Vocational & Technical College, Chongqing 400712, China

2.
Chongqing Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714, China

Corresponding author: Zhang Wei, andyzhangwei@163.com

Funds: Project supported by the National Natural Science Foundation of China (Grant No. 61575196), the Natural Science Foundation of Chongqing, China (Grant No. cstc2019jcyj-msxmX0663), the Science and Technology Research Program of Chongqing Municipal Education Commission, China (Grant No. KJQN201904102), and the Scientific and Technological Program Project of Beibei, China (Grant No. 2019-2)

文章全文

参考文献

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施引文献

图 1 (a) 不同pH下, 4-MBA分子在TiO₂基底上的SERS光谱^[21]; (b) 4-MBA分子在不同Zn掺杂程度TiO₂基底上的SERS光谱^[22]; (c) 4-MBA分子在不同体系中的能级图^[24]; (d) TiO₂球形谐振器(T-rex)的制备流程和T-rex 100样品的SEM图像^[26]

Fig. 1. (a) SERS spectra of 4-MBA adsorbed on TiO₂ nanoparticles under the different pH values^[21]; (b) SERS spectra of 4-MBA adsorbed on TiO₂ and Zn-doped TiO₂^[22]; (c) schematic diagram of the HOMO and LUMO of 4-MBA, 4-MBA@a-TiO₂, and 4-MBA@c-TiO₂^[24]; (d) scheme of preparation of TiO₂ spherical resonators (Trex). SEM image of T-rex100 sample^[26].

下载: 全尺寸图片幻灯片

图 2 (a) a-ZnO NCs和c-ZnO NCs的制备过程; (b) a-和c-ZnO NCs的TEM图像和高分辨透射电镜(High-resolution TEM, HRTEM)显微照片; (c)—(e) 单个a-和c-ZnO NCs上的4-MBA, 4-MPY, 4-ATP分子(10^-4 M)的SERS光谱, 实测的(M)和模拟的(S)^[32]

Fig. 2. (a) A schematic of the fabrication of a- and c-ZnO NCs; (b) SEM and TEM images of a- and c-ZnO NCs.; (c)-(e) SERS spectra of 4-MBA, 4-MPY, and 4-ATP (10^-4 M) molecules adsorbed onto a single a- and c-ZnO NC, Measured (M) and simulated (S)^[32]

下载: 全尺寸图片幻灯片

图 3 (a) 4-NBT分子分别在{100}单立方、{110}十二面体和{111}八面体Cu₂O粒子上的SERS谱^[36]; (b) 分别为立方Cu₂O、八面体Cu₂O、十二面体Cu₂O结构的SEM图^[36]; (c) Cu₂O立方型超结构的自组装过程^[37]

Fig. 3. (a) SERS spectra of 4-NBT molecule obtained on single {100}-cubic, {110}-dodecahedral, and {111}-octahedral Cu₂O particle, respectively ^[36]; (b) the SEM images of the cubic Cu₂O, octahedral Cu₂O, and dodecahedral Cu₂O structures^[36]; (c) self-assembly process for the formation of Cu₂O cube-like superstructures^[37].

下载: 全尺寸图片幻灯片

图 4 (a) TIS方法制备Cu₂O CSs的流程; (b), (c) Cu₂O CSs的SEM图和TEM图^[40]

Fig. 4. (a) Scheme illustration of the TIS process for the formation of Cu₂O CSs; (b), (c) SEM and TEM images of Cu₂O CSs^[40].

下载: 全尺寸图片幻灯片

图 5 (a) 哑铃状MoO₂纳米晶的TEM图^[12]; (b) 2D MoS₂上4-MPy的范德华相互作用的模型示意图^[7]; (c) MoO₂, MoO_2-_x纳米粒子的XRD图谱和单斜MoO₂晶体结构示意图^[43]

Fig. 5. (a) TEM images of the MoO₂ powders^[12]; (b) schematic model of the van der Waals interaction of 4-MPy on top of the 2D MoS₂^[7]; (c) XRD patterns of MoO₂ and MoO_2-_x nanoparticles; Schematic illustrating the crystal structure of monoclinic MoO₂^[43].

下载: 全尺寸图片幻灯片

图 6 (a) WO₃和W₁₈O₄₉的结构示意图^[45]; (b) WO_3-x SERS基底3D结构示意图^[47]; (c) 4种不同增强模式实验设置示意图^[49]

Fig. 6. (a) Structure illustration for WO₃ and W₁₈O₄₉ ^[45]; (b) 3D schematic structure of the WO_3-x SERS substrate^[47]; (c) schematic illustration of the experiment settings for four different enhancement mode^[49].

下载: 全尺寸图片幻灯片

图 7 (a) ReS₂纳米片SERS效应示意图^[53]; (b)空心M(OH)x (M = Fe, Co, Ni)八面体的制备流程^[54]

Fig. 7. (a) Schematic illustration of the experimental setup for understanding the Raman enhancement mechanism on ReS₂ nanosheets ^[53]; (b) schematic illustration of preparation of hollow M(OH)x (M = Fe, Co, Ni) octahedra^[54].

下载: 全尺寸图片幻灯片

map

[1]	Fleischmann M, Hendra P J, McQuillan A J 1974 Chem. Phys. Lett. 26 163 Google Scholar
[2]	Moskovits M 1978 J. Chem. Phys. 69 4159 Google Scholar
[3]	Kneipp K, Wang Y, Kneipp H, Perelman L T, Itzkan I, Dasari R R, Feld M S 1997 Phys. Rev. Lett. 78 1667 Google Scholar
[4]	Ji W, Zhao B, Ozaki Y 2016 J. Raman Spectrosc. 47 51 Google Scholar
[5]	Ling X, Xie L, Fang Y, Xu H, Zhang H, Kong J, Dresselhaus M S, Zhang J, Liu Z 2010 Nano Lett. 10 553 Google Scholar
[6]	Xue X, Ji W, Mao Z, Mao H, Wang Y, Wang X, Ruan W, Zhao B, Lombardi J R 2012 J. Phys. Chem. C 116 8792 Google Scholar
[7]	Muehlethaler C, Considine C R, Menon V, Lin W C, Lee Y H, Lombardi J R 2016 ACS Photonics 3 1164 Google Scholar
[8]	Tan Y, Gu J, Xu W, Chen Z, Liu D, Liu Q, Zhang D 2013 ACS Appl. Mater. Interfaces 5 9878 Google Scholar
[9]	Daglar B, Khudiyev T, Demirel G B, Buyukserin F, Bayindir M 2013 J. Mater. Chem. C 1 7842 Google Scholar
[10]	赵冰, 徐蔚青, 阮伟东, 韩晓霞 2008 高等学校化学学报 29 2591 Google Scholar Zhao B, Xu W Q, Ruan W D, Han X X 2008 Chem. J. Chin. Univ. 29 2591 Google Scholar
[11]	Wang X, Guo L 2020 Angew. Chem. Int. Ed. 59 4231 Google Scholar
[12]	Zhang Q, Li X, Ma Q, Zhang Q, Bai H, Yi W, Liu J, Han J, Xi G 2017 Nat. Commun. 8 14903 Google Scholar
[13]	Shi L, Tuzer T U, Fenollosa R, Meseguer F 2012 Adv. Mater. 24 5934 Google Scholar
[14]	Ji W, Li L, Song W, Wang X, Zhao B, Ozaki Y 2019 Angew. Chem. Int. Ed. 58 14452 Google Scholar
[15]	Yang L, Jiang X, Ruan W, Zhao B, Xu W, Lombardi J R 2008 J. Phys. Chem. C 112 20095 Google Scholar
[16]	Jung N, Crowthe A C, Kim N, Kim P, Brus L 2010 ACS Nano 4 7005 Google Scholar
[17]	Feng S, Santos M C D, Carvalho B R, et al. 2016 Sci. Adv. 2 1600322 Google Scholar
[18]	Huang S, Ling X, Liang L, Song Y, Fang W, Zhang J, Kong J, Meunier V, Dresselhaus M S 2015 Nano Lett. 15 2892 Google Scholar
[19]	Begliarbekov M, Sul O, Santanello J, Ai N, Zhang X, Yang E H, Strauf S 2011 Nano Lett. 11 1254 Google Scholar
[20]	Papadakis D, Diamantopoulou A, Pantazopoulos P A, et al. 2019 Nanoscale 11 21542 Google Scholar
[21]	Yang L, Jiang X, Ruan W, Zhao B, Xu W, Lombardi J R 2009 J. Raman Spectrosc. 40 2004 Google Scholar
[22]	Yang L, Zhang Y, Ruan W, Zhao B, Xu W, Lombardi J R 2010 J. Raman Spectrosc. 41 721 Google Scholar
[23]	Keshavarz M, Kassanos P, Tan B, Venkatakrishnan K 2020 Nanoscale Horiz. 5 294 Google Scholar
[24]	Wang X, Shi W, Wang S, Zhao H, Lin J, Yang Z, Chen M, Guo L 2019 J. Am. Chem. Soc. 141 5856 Google Scholar
[25]	Lin J, Ren W, Li A, Yao C, Chen T, Ma X, Wang X, Wu A 2020 ACS Appl. Mater. Interfaces 12 4204 Google Scholar
[26]	Alessandri I 2013 J. Am. Chem. Soc. 135 5541 Google Scholar
[27]	Qi D, Lu L, Wang L, Zhang J 2014 J. Am. Chem. Soc. 136 9886 Google Scholar
[28]	Sarycheva A, Makaryan T, Maleski K, et al. 2017 J. Phys. Chem. C 121 19983 Google Scholar
[29]	Ye Y T, Yi W C, Liu W, Zhou Y, Bai H, Li J F, Xi G C 2020 Sci. China Mater. 63 794 Google Scholar
[30]	Wen H, He T J, Xu C Y, Zuo J, Liu F C 1996 Mol. Phys. 88 281 Google Scholar
[31]	Sun Z, Zhao B, Lombardi J R 2007 Appl. Phys. Lett. 91 221106 Google Scholar
[32]	Wang X, Shi W, Jin Z, Huang W, Lin J, Ma G, Li S, Guo L 2017 Angew. Chem. Int. Ed. 56 9851 Google Scholar
[33]	Zhao X, Deng M, Rao G, et al. 2018 Small 14 1802477 Google Scholar
[34]	Li X, Shang Y, Lin J, Li A, Wang X, Li B, Guo L 2018 Adv. Funct. Mater. 28 1801868 Google Scholar
[35]	Li X, Ren X, Zhang Y, Choy W C, Wei B 2015 Nanoscale 7 11291 Google Scholar
[36]	Wang R C, Li C H 2011 Acta Mater. 59 822 Google Scholar
[37]	Lin J, Hao W, Shang Y, Wang X, Qiu D, Ma G, Chen C, Li S, Guo L 2018 Small 14 1703274 Google Scholar
[38]	Lin J, Shang Y, Li X, Yu J, Wang X, Guo L 2017 Adv. Mater. 29 10 Google Scholar
[39]	Qiu C, Zhang L, Wang H, Jiang C 2012 J. Phys. Chem. Lett. 3 651 Google Scholar
[40]	Jiang L, You T, Yin P, Shang Y, Zhang D, Guo L, Yang S 2013 Nanoscale 5 2784 Google Scholar
[41]	Zhang Q, Li X, Yi W, Li W, Bai H, Liu J, Xi G 2017 Anal. Chem. 89 11765 Google Scholar
[42]	Wu H, Zhou X, Li J, Li X, Li B, Fei W, Zhou J, Yin J, Guo W 2018 Small 14 1802276 Google Scholar
[43]	Cao Y, Liang P, Dong Q, Wang D, Zhang, Tang L, Wang L, Jin S, Ni D, Yu Z 2019 Anal. Chem. 91 8683 Google Scholar
[44]	Zheng Z, Cong S, Gong W, Xuan J, Li G, Lu W, Geng F, Zhao Z 2017 Nat. Commun. 8 1993 Google Scholar
[45]	Cong S, Yuan Y, Chen Z, Hou J, Yang M, Su Y, Zhang Y, Li L, Li Q, Geng F, Zhao Z 2015 Nat. Commun. 6 7800 Google Scholar
[46]	Fan X, Li M, Hao Q, Zhu M, Hou X, Huang H, Ma L, Schmidt O G, Qiu T 2019 Adv. Mater. Interfaces 6 1901133 Google Scholar
[47]	Zhou C L, Sun L F, Zhang F Q, Gu C J, Zeng S W, Jiang T, Shen X, Ang D S, Zhou J 2019 ACS Appl. Mater. Interfaces 11 34091 Google Scholar
[48]	Ye Y T, Bai H, Li M C, Tian Z, Du R F, Fan W H, Xi G C 2019 Adv. Mater. Technol. 4 1900282 Google Scholar
[49]	Hou X Y, Luo X G, Fan X C, Peng Z H, Qiu T 2019 Phys. Chem. Chem. Phys. 21 2611 Google Scholar
[50]	Wang X, Shi W, She G, Mu L 2011 J. Am. Chem. Soc. 133 16518 Google Scholar
[51]	侯近龙, 贾祥非, 薛向欣, 陈雷, 宋微, 徐蔚青, 赵冰 2012 高等学校化学学报 33 139 Google Scholar Hou J L, Jia X F, Xue X X, Chen L, Song W, Xu W Q, Zhao B 2012 Chem. J. Chin. Univ. 33 139 Google Scholar
[52]	Miao P, Wu J, Du Y, Sun Y, Xu P 2018 J. Mater. Chem. C 6 10855 Google Scholar
[53]	Miao P, Qin J K, Shen Y, Su H, Dai J, Song B, Du Y, Sun M, Zhang W, Wang H L, Xu C Y, Xu P 2018 Small 14 1704079 Google Scholar
[54]	Gao M, Miao P, Han X, Sun C, Ma Y, Gao Y, Xu P 2019 Inorg. Chem. Front. 6 2318 Google Scholar
[55]	Lee N, Schuck P J, Nico P S, Gilbert B 2015 J. Phys. Chem. Lett. 6 970 Google Scholar
[56]	Fu X, Pan Y, Wang X, Lombardi J R 2011 J. Chem. Phys. 134 024707 Google Scholar
[57]	Quagliano L G 2004 J. Am. Chem. Soc. 126 7393 Google Scholar
[58]	Livingstone R, Zhou X, Tamargo M C, Lombardi J R, Quagliano L C, Jean M F 2010 J. Phys. Chem. C 114 17460 Google Scholar

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非贵金属表面增强拉曼散射基底的研究进展