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中国物理学会期刊

基于局部纳米点调控的类突触非晶态MoS2/TiO2忆阻器

CSTR: 32037.14.aps.75.20251224

High-stability amorphous-MoS2/amorphous-TiO2 heterojunction structure analog memristor for bio-synaptic emulation and neuromorphic computing

CSTR: 32037.14.aps.75.20251224
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  • 忆阻器作为新一代非易失性存储器, 可应用于神经形态计算等新型计算范式. TiO2材料因其高介电常数与热稳定性被广泛应用于忆阻器的功能层, 然而TiO2基忆阻器仍存在稳定性较差及模拟性能欠优等瓶颈. 本文引入非晶态的二维材料MoS2 (a-MoS2)与非晶态TiO2 (a-TiO2)构建了异质结结构, 获得了超200次循环、高数据保持时间(>104 s)的模拟忆阻器. 此外, W/a-MoS2/a-TiO2/Pt器件可通过控制扫描电压实现多级电导调制功能, 通过导电机制拟合分析构建了一种基于局部纳米点诱导的导电细丝形成及断裂的物理开关模型, 分析了器件实现多级电导调制的物理机制. 最后, 在W/a-MoS2/a-TiO2/Pt器件上实现了长时程增强与抑制功能. 本文设计构建了W/a-MoS2/a-TiO2/Pt异质结结构, 为过渡金属氧化物基忆阻器性能改进与应用提供了有效方案.

     

    Memristors, as a new generation of non-volatile memory, can simulate biological synapses. Current research on memristor dielectric materials primarily focuses on transition of metal oxides, perovskites, and organic polymers. Among these, the transition metal oxide TiO2 is widely used for the switching layer due to its high dielectric constant and excellent thermal stability. However, TiO2-based memristors face challenges including poor stability and inadequate analog performance, which fundamentally limit their applicability in neuromorphic computing. In this study, a high-performance analog memristor is developed using an a-MoS2/a-TiO2 (amorphous MoS2/amorphous TiO2) heterostructure, achieving over 200 stable cycles and a long data retention time exceeding 104 s. This device exhibits a lower threshold voltage, higher endurance, and excellent data retention compared with previously reported TiO2-based heterostructure memristors. Furthermore, various voltage sweep schemes are designed to successfully modulate multi-level conductance in the W/a-MoS2/a-TiO2/Pt device. The resistive switching mechanism of the W/a-MoS2/a-TiO2/Pt device is elucidated by combining conductive mechanism fitting with a physical model that attributes the switching to the localized formation and rupture of conductive filaments. Finally, synaptic functions such as LTP and LTD are achieved in the device by using square-wave pulses. In this study, a W/a-MoS2/a-TiO2/Pt heterostructure is developed, which significantly enhances analog memristive performance and provides an effective strategy for improving transition metal oxide-based memristors.

     

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