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中国物理学会期刊

B2+和B+离子的静态偶极极化率和超极化率的理论研究

Theoretical study of static dipole polarizabilities and hyperpolarizability of B2+ and B+ ions

CSTR: 32037.14.aps.72.20221990
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  • 利用相对论组态相互作用模型势方法计算了B2+和B+离子的波函数、能级和振子强度, 进一步得到B2+离子2s1/2, 2p1/2, 2p3/2, 3s1/2态的电偶极极化率和基态2s1/2的超极化率, 以及B+离子2s2 1S0与2s2p 3P0态的电偶极极化率. B2+离子2p1/2和2p3/2的偶极极化率为负值, 基态2s1/2的超极化率的贡献主要来自于与极化率相关的 \rm\alpha ^1\rm\beta _0 项. 对于B+离子, 钟跃迁2s2p 3P0 → 2s2 1S0在室温下的黑体辐射频移是0.01605 Hz, 该黑体辐射频移比碱土金属原子的钟跃迁黑体辐射频移小1—2个数量级.

     

    The wave functions, energy levels, and oscillator strengths of B2+ ions and B+ ions are calculated by using a relativistic potential model, which is named the relativistic configuration interaction plus core polarization (RCICP) method.The presently calculated energy levels are in very good agreement with experimental energy levels tabulated in NIST Atomic Spectra Database, with difference no more than 0.05%.The presently calculated oscillator strengths agree very well with NIST and some available theoretical results. The difference is no more than 0.6%. By using these energy levels and oscillator strengths, the electric-dipole static polarizability of the 2s1/2, 2p1/2, 2p3/2, and 3s1/2 state and static hyperpolarizability of the ground state 2s1/2 for B2+ ion, as well as electric-dipole static polarizability of the 2s2 1S0 state and 2s2p 3P0 state for B+ ion are determined, respectively. The polarizability of the 2p1/2 state and 2p3/2 state of B2+ ion are negative. The main reason is that the absorption energy of the 2p1/2,3/2 → 2s1/2 resonance transition is negative. The contribution to the polarizability of the 2p1/2 state and 2p3/2 state are both negative. For the tensor polarizability of the 2p3/2 state, the main contribution from the 2p3/2 → 2s1/2 transition and 2p3/2 → 3d5/2 transition are 2.4963 a.u. and –0.2537 a.u., respectively, and the present RCICP result is 2.1683 a.u. The largest contribution to the hyperpolarizability of the ground state 2s1/2 originates from the term of \alpha ^1\beta _0 . The electric-dipole static polarizability of the 2s2 1S0 state and 2s2p 3P0 state of B+ ion are 9.6220 a.u. and 7.7594 a.u., respectively. The presently calculated blackbody radiation (BBR) shift of the 2s2p 3P0 → 2s2 1S0 clock transition is 0.01605 Hz. This BBR shift is one or two orders of magnitude smaller than that for alkaline-earth-metal atom.

     

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