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中国物理学会期刊

Dy3Al5O12磁热性质研究

CSTR: 32037.14.aps.64.177502

Study on the magnetic and magnetocaloric effects of Dy3Al5O12

CSTR: 32037.14.aps.64.177502
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  • 用量子理论计算了Dy3Al5O12的晶场能谱、Zeeman劈裂能级和波函数. 在外磁场He为0HeT, 温度为3T3Al5O12内磁性离子间的交换作用非常微弱, 可以忽略. 从理论上给出了绝热退磁过程中温度变化ΔT与T的关系, 并与Gd3Ga5O12晶体进行了比较, 发现不同外磁场下, Dy3Al5O12和Gd3Ga5O12的低温制冷性能在不同温区有差别. 在进行低温(T3Al5O12作为磁制冷材料较好; 若外磁场较高, 选择Gd3Ga5O12作为磁制冷材料较好.

     

    The crystal field (CF)- and external magnetic field- split ground state of Dy3+ in Dy3Al5O12 (DyAG) has been calculated based on the quantum theory in this paper. The eight CF-split levels are obtained, which are all twofold degenerates and are removed by the external magnetic field. On the basis of the results, the magnetic moments and the magnetic entropy changes of DyAG are calculated in the temperature range of 3THe3Ga5O12(GdGG) is stronger at low temperatures and dependent on the temperature and external magnetic field. Besides, the variation of the adiabatic temperature change ΔT with T is theoretically anticipated and the anticipated results are comparied with that of GdGG. It is found that the maximum adiabatic temperature change ΔT of DyAG is 1.27 times larger than that of GdGG when T=11 K and He=1 T. However, it changes to 1.15 times that of GdGG when T=16 K and He=2 T. There are differences between the refrigerative properties of DyAG and GdGG when they are in different external magnetic fields and different temperature regions. At low temperature s(THe is higher, GdGG is a good selection. This study is helpful to select suitable materials for the magnetic refrigeration technology.

     

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