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中国物理学会期刊

有序金纳米颗粒阵列的制备及光吸收特性研究

CSTR: 32037.14.aps.62.198101

Fabrication of ordered Au nanoparticles array and its optical absorption properties

CSTR: 32037.14.aps.62.198101
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  • 采用纳米球刻蚀技术中漂移法在玻璃基片上制备较大 面积不同直径的聚苯乙烯小球掩模板, 采用磁控溅射技术在掩模板上沉积不同厚度的金薄膜, 去除聚苯乙烯小球后, 通过扫描电子显微镜观察到周期排列的三角状金纳米颗粒点阵. 通过紫外-可见分光光度计测试所制备样品的光吸收特性, 发现表面等离子体共振峰随粒径增大发生红移, 随金纳米颗粒高度增加发生蓝移. 基于Mie理论, 利用Matlab软件编程对不同粒径的金阵列光吸收特性进行理论模拟, 并与实验结果进行对比.

     

    Three kinds of polystyrene spheres with different sizes were fabricated on glasses by drifting method of nanosphere lithography. Au thin films with various thicknesses were prepared by magnetron sputtering under controlled deposition time. Triangle-shaped Au nanoparticles array in three different heights after removing the PS template were observed using scanning electron microscopy. The absorption characteristics of all samples were measured by ultraviolet-visible spectrophotometer. Surface plasmon resonance peak was seen to shift to the longer wavelength with increasing diameter of Au nanoparticles. And the surface plasmon resonance peak was shifted to the shorter wavelength with increasing height of Au nanoparticles. Based on Mie theory, we simulated the extinction properties, which vary with the diameter of Au nanoparticles, using Matlab software. The conclusion is in accordance with our experimental results.

     

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