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中国物理学会期刊

近三相点温度低温固体氘的红外吸收谱

CSTR: 32037.14.aps.62.163301

Infrared absorption spectrum of solid deuterium at near-triple point temperature

CSTR: 32037.14.aps.62.163301
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  • 基于量子力学理论和D2的零点振动能, 计算出了D2的低模式能量, 分析判断出了发生振转能量跃迁概率最大模式. 利用自主研制的低温平面冷冻靶系统和低温红外测量系统, 制备出了光滑、均匀、透光性好的平面固体氘膜, 测得了其红外吸收谱. 其中吸收明显的峰位主要由于Q1(0)+S0(0), Q1(0)+S0(1), Q1(0)+S0(0)+S0(1) 振动、转动模式构成.实验结果与理论计算结果一致.

     

    The low mode energy of deuterium is calculated by quantum mechanics theory and deuterium zero-point vibration energy. The smooth, uniformity, euphotic solid deuterium film is obtained by home-made planar cryotarget system. The infrared absorption spectrum of solid deuterium film is studied by infrared spectroscopy system. The strong absorption peaks mostly result from the Q1(0)+S0(0), Q1(0)+S0(1), Q1(0)+S0(0)+S0(1) vibration, rotation modes. The experimental data are in good agreement with the analysis results.

     

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