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中国物理学会期刊

Tm3+掺杂锗铌酸盐玻璃及其红外光谱特性

CSTR: 32037.14.aps.59.5808

Germanium-niobate glasses doped with Tm3+ and their infrared spectral properties

CSTR: 32037.14.aps.59.5808
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  • 用高温熔融法制备了相同质量百分比浓度4%Tm2O3掺杂浓度下(90-x)GeO2-xNb2O5-10Na2O(其中数字为摩尔百分比x=1,2,4,6,8)以及Tm2O3掺杂浓度分别为质量百分比1%,2%,3%,4%下86GeO2-4Nb2O5-10Na2O(其中数字为摩尔分数)系列玻璃.研究了Nb2O5组分对玻璃热稳定性,荧光强度和J-O参数的影响.应用Judd-Ofelt理论,计算了Tm3+离子在Nb2O5浓度不同时的J-O强度参数(Ω2,Ω4,Ω6)及Tm3+离子各激发态能级的自发跃迁概率、荧光分支比以及辐射寿命等光谱参量.根据McCumber理论,计算了Tm3+离子能级3F4→3H6(1.8 μm)跃迁的吸收截面和受激发射截面.从获得的吸收截面、发射截面与离子掺杂浓度计算了1.8 μm荧光波段的增益截面曲线.在808 nm波长光的激发下,研究了Tm3+掺杂玻璃在1.47与1.8 μm附近的荧光特性.发现当Tm2O3掺杂浓度为质量百分比3%时,在1.8 μm处的荧光强度达最大,然后随着掺杂浓度的增大,其荧光强度反而降低;当Nb2O5摩尔分数含量大约在2%时,Tm3+在1.8 μm处的荧光强度最强.并讨论了Nb2O5组分变化对玻璃结构与光谱特性的影响情况.

     

    Glasses with the compositions of (90-x)GeO2-xNb2O5-10Na2O(x=1,2,4,6,8 molar ratio)doped with Tm2O3 at the same concentration (4wt%) and 86GeO2-4Nb2O5-10Na2O dore at different concentrations were fabricated respectively by conventional melting method.The effects of Nb2O5 content on glass stability,fluorescence strength and J-O strength parameters were studied.According to the Judd-Ofelt theory,the J-O strength parameters (Ω2, Ω4, Ω6) of Tm3+ in different Nb2O5 concentration were calculated,with which the radiative transition probabilities,branching ratios and radiative lifetime were obtained.Meanwhile,according to the McCumber theory,the absorption and emission cross-sections corresponding to the 3F4→3H6 transitions of Tm3+ at 1.8 μm were obtained.The gain cross section was calculated by using the emission cross-section,absorbtion cross section and Tm3+ concentration.The fluorescence features (under 808 nm LD excitation) at ~1.47 and ~1.8 μm of Tm3+-doped glasses of different concentrations were studied.The fluorescence intensity at ~1.8 μm reached to the maximum when the Tm2O3-doping concentration was about 3wt%,and then decreased as the doping concentration increased further.The fluorescence intensity at ~1.8 μm reached to the maximum when the Nb2O5 content in glass composition was about 2 mol%.The effects of Nb2O5 content on the glass structure and the spectra properties were also discussed.

     

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