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中国物理学会期刊

面心立方(001)方向AB合金薄膜表面层的有序无序相变

CSTR: 32037.14.aps.55.413

Order-disorder phase transitions in the surface layers of fcc (001) AB alloy thin films

CSTR: 32037.14.aps.55.413
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  • 采用平均场近似方法对两组元面心立方合金薄膜的有序无序相转变过程进行模拟计算,结果表明,合金薄膜的有序无序相变受薄膜层数奇偶性的影响.薄膜层数奇偶性不同,会导致薄膜具有不同的相结构和热力学性质.在弱表面偏析作用下,对于偶数层薄膜,由于薄膜边界对称性破缺,对应体组分x=0.5的化学势区间,偶数层薄膜有序无序相变过程中出现了中间温度相和浸润现象.而奇数层薄膜的有序无序相变类似体材料的相变.在强表面偏析作用下,由于受表面偏析作用和有限尺寸效应影响,对应体组分x=0.5的化学势区间,奇数层薄膜中出现AB(AB) 

    The order-disorder phase transitions of the fcc AB alloy thin films in (001) direction are studied numerically by the cluster variation method. The computation results show that the order-disorder phase transitions of thin films are determined by the parity of the layer number of films. The thin films with different parity will show different phase structures and thermodynamic properties. When the surface field is weak, for films with even number of layers, in the chemical potential region corresponding to the bulk concentration x=0.5, there appears the middle-temperature phase as well as the wetting phenomenon due to the missing of symmetry of the films. While for films with odd number of layers, the order-disorder phase transitions are similar with that of the bulk materials. When the surface field is strong, for films with odd number of layers, in the chemical potential region corresponding to the bulk concentration x=0.5, there is an AB(AB)nA phase which does not show order-disorder phase transtion with the increase of temperature due to the combined effect of the surface field and finite size.

     

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