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中国物理学会期刊

新型苯乙烯衍生物掺杂的蓝色及白色有机电致发光器件

CSTR: 32037.14.aps.55.2008

Blue and white organic light emitting diodes based on a new stilbene derivative dopant

CSTR: 32037.14.aps.55.2008
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  • 研究了新型高效蓝色掺杂剂EBDP的电致发光性能. 分别以EBDP为掺杂剂制备了结构为氧化铟 锡(ITO)/酞菁铜(CuPc)/N,N′-二(1-萘基)-N,N′-二苯基-1,1′-联苯-4-4′-二胺(NPB)/2- 叔丁基-9,10-二-(2-萘基)蒽(TBADN):EBDP/8-羟基喹啉铝(Alq3)/LiF/Al 与ITO /CuPc/NPB/TBADN:EBDP: 4-二氰亚甲基-2-叔丁基-6-(1,1,7,7-四甲基久咯呢定基-9-烯基)- 4H-吡喃/Alq3

     

    In this paper the electroluminescene of highly efficient blue dopant EBDP was in vestigated. The blue and white organic light emitting diodes with the structure: indium-tin oxide(ITO)/ copper phthalocyanine(CuPc)/N,N′-bis-(1-naphenyl)-N,N′ -biphenyl -1,1′-bipheny1-4-4′-diamine (NPB)/2-t-butyl-9,10-di-(2-naphthyl)anth racene(TBADN):EBDP/tris(8-hydroxyquinoline) aluminum(Alq3)/LiF/Al and ITO/CuPc/NPB/TBADN:EBDP: 4-(dicyanomethylene)-2-t-butyl-6-(1,1,7,7-tetramethylj ulolidyl-9-enyl)-4H-pyran/Alq3/LiF/Al were studied by using EBDP as b lue dopant. For the blue device, the maximum luminance was 26961cd/m2 , and its maximum efficiency was 8.29cd/A. The luminance at a current density 20 mA/cm2 was 1597cd/m2. For the white device, the maximum lu minance 32291cd/m2 and maximum efficiency 8.31cd/A,the luminance of 1 413cd/m2 at a current density 20mA/cm2 were obtained. The slow decrease of efficiency with the increase of current density indicates weak exciton-exciton annihilation, which results from the large steric hindrance due to a non-planar structure of the fluorescence dye EBDP.

     

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