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中国物理学会期刊

链间耦合对聚合物中双激子态反向极化的影响

CSTR: 32037.14.aps.54.665

Effect of interchain coupling on the inversed polarization of a biexciton in conjugated polymers

CSTR: 32037.14.aps.54.665
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  • 从紧束缚模型出发,研究了链间相互作用对双激子态反向极化的影响.结果发现:加链间耦合后,双激子态仍主要局域在一条链中.当简并破缺较小时,反向极化程度随耦合强度的增加大幅提高;当简并破缺较大时,反向极化程度随耦合强度的增加基本不变.

     

    Effect of interchain coupling on the inversed polarization of a biexciton has been studied in the framework of a tightbinding approximation. It was found that a biexciton state is mainly confined in one chain even the interchain coupling is included. The inversed polarization will be enhanced remarkably with the interchain coupling in the case of a weak nondegenerate confinement. However, the inversed polarization will keep nearly unchanged for a strong nondegenerate confinement.

     

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