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中国物理学会期刊

碳含量对Y-Ni-B-C超导相的形成与临界温度的影响

CSTR: 32037.14.aps.48.56

Effects of Carbon Content on the Formation and Critical Temperature of Y-Ni-B-C Superconductor

CSTR: 32037.14.aps.48.56
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  • 报道ThCr2Si2型结构的四元金属间化合物Y2Ni2B2Cx的形成与超导电性.当碳配比含量x=0.9—1.2时,电弧熔炼的合金结晶为较好的YNi2B2C单相.当x<0.8或x>1.2时,合金中虽仍以YNi2B2C为主相,但杂相明显增加.超导转变温度Tc随碳含量增加明显分为两个台阶.x≤0.8时,Tc约为12.5K;x≥0.9时,Tc约为15K.

     

    In this paper, we report the formation and superconductivity of quaternary intermetallic system Yni2B2Cx with ThCr2Si2-type structure. Samples prepared by arc-melting crystallize in single phase of the composition of YNi2B2Cx when x=0.9—1.2 while the secondary unknown phases increase obviously when x<0.8 or x>1.2. Superconducting-transition temperature Tc determined by the tem,perature dependence of magnetization displays two steps with increasing carbon concentration: Tc≈12.5K for x≤0.8, Tx≈15K for x≥0.9.

     

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