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中国物理学会期刊

严格可解四参数双原子分子势函数

CSTR: 32037.14.aps.48.1992

EXACTLY SOLVABLE POTENTIAL WITH FOUR PARAMETERS FOR DIATOMIC MOLECULES

CSTR: 32037.14.aps.48.1992
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  • 提出一个四参数双原子分子势函数,对s波Schrdinger方程进行了严格求解,并采用一个简便的方法考虑了转动修正.该势函数对实验Rydberg-Klein-Rees曲线及振动-转动能级的计算精度远优于常用的Morse势,且将Morse势等势函数作为特例包括于其中.

     

    A four-parameter potential function is proposed.The corresponding s-wave Schrdinger equation is solved exactly,and the rotational energy is approximately considered by using a simple method.The evaluating accuracy of the potential for the experimental RKR curve and the rotational-vibrating level is far better than the usual Morse potential,and the latter is contained in this potential as a special case.

     

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