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中国物理学会期刊

杂质对K2ZnCl4晶体无公度结构相变的影响

CSTR: 32037.14.aps.41.1087

EFFECT OF IMPURITIES ON INCOMMENSURATE PHASE TRANSITION OF K2ZnCl4 CRYSTAL

CSTR: 32037.14.aps.41.1087
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  • 对K2ZnCl4铁电晶体在无公度-公度转变的相变点附近的孤子行为进行了研究。发现在相变点附近杂质使介电函数明显偏离居里-外斯定律,并导致介电峰值的明显下降;同时还发现杂质对升温相变点Tch较之对降温相变点Tcc有更大的影响,这与Rb2ZnCl4等晶体中的情况恰好相反。采用朗道自由能理论可较好地描述杂质在相变点附近对介电函数的影响。分

     

    The soliton behavior of K2ZnCl4 crystal near commensurate-incommensurate phase transition point is investigated by dielectric measurement. It is found that the dielectric curve deviate from Curie-Weiss law and the dielectric peak value decrease with the increasing of the impurities. The influence of impurities on phase transition point Tch in heating run is larger than phase transition point Tcc in cooling run. This phenomenon is contrary to the case of Rb2ZnCl4 crystal. The linear and nonlinear response of a multisoliton lattice is well described by a Landau-type theory. Analysis shows that the thermal hysteresis is mainly determined by the action of impurities, but this does not imply that the Peierls lattice pinning potential may not play any role in the thermal hysteresis.

     

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