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中国物理学会期刊

染料J聚集体Langmuir_Blodgett膜光致发光谱的温度影响与多声子跃迁

CSTR: 32037.14.aps.40.1095

MULTIPHONON TRANSITION AND TEMPERATURE DEPENDENCE OF PHOTOLUMINESCENCE SPECTRA OF DYE J一AGGREGATE LANGMIUR-BLODGETT FILMS

CSTR: 32037.14.aps.40.1095
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  • 在2 0 一3 0 0 K 的范围内测量了三种花青染料聚集体L a n g m i u r 一B lo d g e t t (L B ) 膜的光致发光谱. 随着温度下降零声子线J 峰强度的增大, 观察到声子伴带的异常加强. 分析表明生长不均匀的聚集体L B 膜具有低维晶体的特性, 声子祸合强, 且无辐射跃迁起着重要的作用.

     

    In temperature range of 20K to 300K, we measured photoluminescence spectra of heterogeneous J-aggregate Langmiur-Blodgett (LB) films made of three kinds of cyanine dye. With temperature reduced, while the intensity of J-peak, the zero phonon line increased, anomalous enhancement of the phonon sideband was observed. Analysis shows that J-aggregate LB films are of characteristics like that of low dimensional crystal, they have strong phonon coupling and nonradiative transition plays important role.

     

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