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中国物理学会期刊

固体电解质与电极之间界面的分数维模型及其频率响应

CSTR: 32037.14.aps.38.1621

FRACTAL MODEL OF THE INTERFACE BETWEEN ELECTROLYTE AND ELECTRODE AND ITS FREQUENCY RESPONSE

CSTR: 32037.14.aps.38.1621
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  • 本文提出了固体电解质与电极之间界面的分数维模型,讨论了分数维界面的频率响应,解释了测量系统中出现的表达式为Zp=A(iω)-p的恒相角(CPA)阻抗现象,得出指数p与分数维维数D的关系为p=(4-D)/2,并与前人提出的分数维模型进行了比较。

     

    A fractal model of the interface between electrolyte and electrode has been proposed. The ac frequency response of the interface is discussed. The phenomenon of the constant phase angle (CPA) impedance expressed by Zp= A(iω)-p discovered in the measurements is explained. A relation between the exponent p and the dimension D of the fractal interface p=(4-D)/2 is obtained and compared with those suggested by others previously.

     

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