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中国物理学会期刊

共轭聚合物中库仑作用对定域激发的影响

CSTR: 32037.14.aps.34.1075

THE EFFECT OF THE COULOMB INTERACTION ON LOCALISED STATES IN CONJUGATED POLYMERS

CSTR: 32037.14.aps.34.1075
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  • 利用紧束缚哈密顿量计算共轭聚合物(conjugated polymers)中库仑作用对于电中性的定域激发态的影响。对于反式(CH)x计算了激子谱,重新计算了光吸收系数,对边缘部分进行了修正,所得到的结果与实验符合。

     

    The effect of the coulomb interaction on electrically neutral, localised states of conjugated polymers is investigated using a tight binding Hamiltonian. For trans- (CH)x, we calculated the excitonic spectrum, recalculated the absorption coefficient, and corrected the edge of the absorption profile. The results are shown to be in good agreement with experiments.

     

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