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Cobalt-doped ferroferriborate ((Fe1-xCox)3BO5) nanorods (NRs) have been synthesized by using a high-temperature organic-solution-phase method, and characterized by high resolution transmission electron microscope (HRTEM) and SQUID. The aspect ratios of the NRs are tuned by reductive decomposition of Fe(acac)3 and Co(acac)2 with a predetermined ratio. HRTEM showS that the sample is polycrystalline NRs and the top view of a NR tip reveals a multiply-twined structure. Magnetization curves indicate that (Fe1-xCox)3BO5 NRs are ferromagnetic above room temperature and the antiferromagnetic component is included, the magnetic properties are dramatically modified by Co substitutional doping. The NRs are expected to be used to study the mechanical properties of biological macromolecules.
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Keywords:
- nanorods /
- chemical doping /
- ferromagnetic /
- antiferromagnetic
[1] Douvalis A P, Moukarika A, Bakas T, Kallias G, Papaefthymiou V 2002 J. Phys.: Condens. Matter 14 3303
[2] Mir M, Guimaraes R B, Fernandes J C, Continentino M A, Doriguetto A C, Mascarenhas Y P, Ellena J, Castellano E E, Freitas R S, Ghivelder L 2001 Phys. Rev. Lett. 87 147201
[3] Fernandes J C, Guimaraes R B, Continentino M A, Ghivelder L, Freitas R S 2000 Phys. Rev. B 61 850
[4] Guimaraes R B, Mir M, Fernandes J C, Continentino M A 1999 Phys. Rev. B 60 6617
[5] Freitas D C, Continentino M A, Guimaraes R B, Fernandes J C, Ellena J, Ghivelder L 2008 Phys. Rev. B 77 184422
[6] Bartolome J, Arauzo A, Kazak N, Ivanova N, Ovchinnikov S, Knyazev Y V, Lyubutin I 2011 Phys. Rev. B 83 144426
[7] Cherkezova-Zheleva Z, Tsoncheva T, Tyuliev G, Mitov I 2006 Appl. Catal. A: General 298 24
[8] Ruvalds J 1996 Supercond. Sci. Technol. 9 905
[9] Douvalis A, Moukarika A, Bakas T, Kallias G, Papaefthymiou V J 2002 Phys.:Condens. Matter 14 3303
[10] Bordet P, Suard E 2009 Phys. Rev. B 79 144408
[11] Larrea J, Sanchez D, Baggio-Saitovitch E, Fernandes J, Guimaraes R, Continentino M, Litterst F J 2001 Magn. Magn. Mater 226 1079
[12] Sanchez D, Litterst F, Baggio-Saitovitch E, Fernandes J, Guimaraes R, Continentino M 2004 Phys. Rev. B 70 174452
[13] Rao G N, Yao Y, Chen J 2005 IEEE Trans. Magn 41 3409
[14] Zhu H, Luo J, Liang J, Rao G, Li J, Zhang J, Du z 2008 Phys. B: Condens. Matter 403 3141
[15] Zysler R D, Winkler E, Vasquez Mansilla M, Fiorani D 2006 Phys. B: Condens. Matter 384 277
[16] Liu Y, Peng S, Ding Y, Rong C B, Kim J, Liu J P, Wang Z L, Sun S H 2009 Adv. Funct. Mater. 19 3146
[17] Liu X C, Shi E W, Song L X, Zhang H W, Chen Z Z 2006 Acta Phys. Sin. 55 2557 (in Chinese) [刘学超, 施尔畏, 宋力昕, 张华伟, 陈之战 2006 55 2557]
[18] Wang J Z, Fang Q Q 2004 Acta Phys. Sin. 53 3186 (in Chinese) [汪金枝, 方庆清 2004 53 3186]
[19] Yan J, Sun Y, Wang C, Shi Z X, Deng S H, Shi K W, Lu H Q 2014 Acta Phys. Sin. 63 167502 (in Chinese) [闫军, 孙莹, 王聪, 史再兴, 邓司浩, 史可文, 卢会清 2014 63 167502]
[20] Shang Z F, Qi W H, Ji D H, Xu J, Tang G D, Zhang X Y, Li Z Z, Lang L L 2014 Chin. Phys. B 23 107503
[21] Tang Y M, Chen L Y, Wei J, Tang S L, Du Y W 2014 Chin. Phys. B 23 077503
[22] He S L, Zhang H, Xing H, Li K., Cui H F, Yang C G, Sun S H, Zeng H 2014 Nano Lett. 14 3914
[23] Chen J Y, Wiley B J, Xia Y 2007 Langmuir. 23 4120
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[1] Douvalis A P, Moukarika A, Bakas T, Kallias G, Papaefthymiou V 2002 J. Phys.: Condens. Matter 14 3303
[2] Mir M, Guimaraes R B, Fernandes J C, Continentino M A, Doriguetto A C, Mascarenhas Y P, Ellena J, Castellano E E, Freitas R S, Ghivelder L 2001 Phys. Rev. Lett. 87 147201
[3] Fernandes J C, Guimaraes R B, Continentino M A, Ghivelder L, Freitas R S 2000 Phys. Rev. B 61 850
[4] Guimaraes R B, Mir M, Fernandes J C, Continentino M A 1999 Phys. Rev. B 60 6617
[5] Freitas D C, Continentino M A, Guimaraes R B, Fernandes J C, Ellena J, Ghivelder L 2008 Phys. Rev. B 77 184422
[6] Bartolome J, Arauzo A, Kazak N, Ivanova N, Ovchinnikov S, Knyazev Y V, Lyubutin I 2011 Phys. Rev. B 83 144426
[7] Cherkezova-Zheleva Z, Tsoncheva T, Tyuliev G, Mitov I 2006 Appl. Catal. A: General 298 24
[8] Ruvalds J 1996 Supercond. Sci. Technol. 9 905
[9] Douvalis A, Moukarika A, Bakas T, Kallias G, Papaefthymiou V J 2002 Phys.:Condens. Matter 14 3303
[10] Bordet P, Suard E 2009 Phys. Rev. B 79 144408
[11] Larrea J, Sanchez D, Baggio-Saitovitch E, Fernandes J, Guimaraes R, Continentino M, Litterst F J 2001 Magn. Magn. Mater 226 1079
[12] Sanchez D, Litterst F, Baggio-Saitovitch E, Fernandes J, Guimaraes R, Continentino M 2004 Phys. Rev. B 70 174452
[13] Rao G N, Yao Y, Chen J 2005 IEEE Trans. Magn 41 3409
[14] Zhu H, Luo J, Liang J, Rao G, Li J, Zhang J, Du z 2008 Phys. B: Condens. Matter 403 3141
[15] Zysler R D, Winkler E, Vasquez Mansilla M, Fiorani D 2006 Phys. B: Condens. Matter 384 277
[16] Liu Y, Peng S, Ding Y, Rong C B, Kim J, Liu J P, Wang Z L, Sun S H 2009 Adv. Funct. Mater. 19 3146
[17] Liu X C, Shi E W, Song L X, Zhang H W, Chen Z Z 2006 Acta Phys. Sin. 55 2557 (in Chinese) [刘学超, 施尔畏, 宋力昕, 张华伟, 陈之战 2006 55 2557]
[18] Wang J Z, Fang Q Q 2004 Acta Phys. Sin. 53 3186 (in Chinese) [汪金枝, 方庆清 2004 53 3186]
[19] Yan J, Sun Y, Wang C, Shi Z X, Deng S H, Shi K W, Lu H Q 2014 Acta Phys. Sin. 63 167502 (in Chinese) [闫军, 孙莹, 王聪, 史再兴, 邓司浩, 史可文, 卢会清 2014 63 167502]
[20] Shang Z F, Qi W H, Ji D H, Xu J, Tang G D, Zhang X Y, Li Z Z, Lang L L 2014 Chin. Phys. B 23 107503
[21] Tang Y M, Chen L Y, Wei J, Tang S L, Du Y W 2014 Chin. Phys. B 23 077503
[22] He S L, Zhang H, Xing H, Li K., Cui H F, Yang C G, Sun S H, Zeng H 2014 Nano Lett. 14 3914
[23] Chen J Y, Wiley B J, Xia Y 2007 Langmuir. 23 4120
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