Synthesis and electrical property of oxide ionic conductor La1.9Y0.1Mo2O9 fine grain ceramic

Zhang De-Ming; Zhuang Zhong; Wang Xian-Ping; Fang Qian-Feng

doi:10.7498/aps.62.076601

Abstract

A series of La1.9Y0.1Mo2O9 bulk samples of different grain sizes were made by microwave sintering the nanocrystalline powders prepared by sol-gel methods. Phases, microstructure, grain size of the powders and bulk samples were examined by using X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM) and scanning electron microscope (SEM); and the electrical properties of the bulk samples were studied by AC impedance spectroscopy. Experimental results show that the substituent Y can stabilize the cubic β phase to room temperature; the bulk samples are dense and uniform with an average grain size from 60 nm to 4 μm; the highly dense bulk samples show enhanced ionic conduction, e.g. the conductivity of the sample with relative density 99% is 0.026 S/cm at 600 ℃, which is two times higher than that of bulk samples prepared by solid-state reaction. It can be concluded that the effect of sample density on the electrical conductivity is mainly due to the grain boundary conductivity; and the effect of sample grain size (from 60 nm to 4 μm) on the electrical properties is not so significant.

Keywords:

Authors and contacts

1.
The Key Lab of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China;
2.
The Key Lab of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China

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[43]	Luo J, Zhu H T, Liang J K 2009 Physics 38 267 (in Chinese) [骆军, 朱航天, 梁敬魁 2009 物理 38 267]
[44]	Xiang J, Li L P, Su W H 2003 Acta Phys. Sin. 52 1474 (in Chinese) [向军, 李莉萍, 苏文辉 2003 52 1474]
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Cited By

[1]	Lacorre P, Goutenoire F, Bohnke O, Retoux R, Laligant Y 2000 Nature 404 856
[2]	Goutenoire F, Isnard O, Retoux R, Lacorre P 2000 Chem. Mate. 12 2575
[3]	Fang Q F, Wang X P, Zhang G G, Yi Z G 2003 J. Alloys Compd 355 177
[4]	Wang X P, Cheng Z J, Fang Q F 2005 Solid State Ionics 176 761
[5]	Goutenoire F, Isnard O, Suard E, Bohnke O, Laligant Y, Retoux R, Lacorre P 2001 J. Mater. Chem. 11 119
[6]	Wang X P, Fang Q F 2002 Solid State Ionics 146 185
[7]	Subasri R, Matusch D, Nafe H, Aldinger F 2004 J. Eur. Ceram Soc. 24 129
[8]	Basu S, Devi P S, Maiti H S 2004 Appl. Phys. Lett. 85 3486
[9]	Zhang G G, Fang Q F, Wang X P, Yi Z G 2003 Phys. Stat. Sol. A 199 329
[10]	Georges S, Goutenoire F, Altorfer F, Sheptyakov D, Fauth F, Suard E, Lacorre P 2003 Solid State Ionics 161 231
[11]	Georges S, Goutenoire F, Laligant Y, Lacorre P 2003 J. Mater Chem. 13 2317
[12]	Georges S, Goutenoire F, Bohnke O, Steil M C, Skinner S J, Wiemhofer H D, Lacorre P 2004 J. New Mater Electrochem Syst 7 51
[13]	Marozau I P, Marrero-Lopez D, Shaula A L, Kharton V V, Tsipis E V, Nunez P, Frade J R 2004 Electrochim Acta 49 3517
[14]	Yang J H, Gu Z H, Wen Z Y Yan D S 2005 Solid State Ionics 176 523
[15]	Wang X P, Fang Q F, Li Z S, Zhang G G. Yi Z G 2002 Appl. Phys. Lett. 81 3434
[16]	Fang Q F, Wang X P, Li Z S, Zhang G G, Yi Z G 2004 Mater Sci. Eng. A 370 365
[17]	Khadasheva Z S, Venskovskii N U, Safronenko M G, Mosunov A V, Politova E D, Stefanovich S Y 2002 Inorg Mater 38 1168
[18]	Chen Y Y, Hou C J, Kong X S, Liu C S, Wang X P, Fang Q F 2011 Acta Phys. Sin. 60 046603 (in Chinese) [陈跃云, 侯春菊, 孔祥山, 刘长松, 王先平, 方前锋 2011 60 046603]
[19]	Wang J X, Wang X P, Liang F J, Cheng Z J, Fang Q F 2006 Solid State Ionics 177 1437
[20]	Subramania A, Saradha T, Muzhunathi S 2008 J. Alloys Comp. 456 234
[21]	Subramania A, Saradha T, Muzhunathi S 2008 Mater. Res. Bull. 43 1153
[22]	Basu S Maiti H S 2010 Ionics 16 111
[23]	Tealdi C, Malavasi L, Ritter C, Flor G, Costa G 2008 J. Solid State Chem. 181 603
[24]	Marrero-Lopez D, Canales-Vazquez J, Ruiz-Morales J C, Rodriguez A, Irvine J T S, Nunez P 2005 Solid State Ionics 176 1807
[25]	Marrero-Lopez D, Ruiz-Morales J C, Nunez P, Abrantes J C C, Frade J R 2004 J. Solid State Chem. 177 2378
[26]	Saradha T, Muzhumathi S, Subramania A 2008 J. Solid State Electrochem 12 143
[27]	Yi Z G, Fang Q F, Wang X P, Zhang G G 2003 Solid State Ionics 160 117
[28]	Yang J H, Wen Z Y, Gu Z H, Yan D S 2005 J. Eur. Ceram Soc. 25 3315
[29]	Li Q, Xia T, Li J Y, Liu X D, Ma X F, Meng J, Cao X Q 2004 J. Rare Earth 22 102
[30]	Subramania A, Saradha T, Muzhumathi S 2007 J. Power Sources 167 319
[31]	Georges S, Skinner S J, Lacorre P, Steil M C 2004 Dalton T. 19 3101
[32]	Goutenoire F, Retoux R, Suard E, Lacorre P 1999 J Solid State Chem. 142 228
[33]	Zhang Y W, Yang Y, Jin S, Tian S T, Li G B, Jia J T, Liao C S, Yan C H 2001 Chem. Mater. 13 372
[34]	Zhang Y W, Jin S, Yang Y, Li G B, Tian S J, Liao C S, Yan C H 2000 Appl. Phys. Lett. 77 3409
[35]	Garcia-Barriocanal J, Rivera-Calzada A, Varela M, Sefrioui Z, Iborra E, Leon C, Pennycook S J, Santamaria J, 2008 Science 321 676
[36]	Jiang X N, Wang H, Ma X Y, Meng X Q, Zhang Q Y 2008 Acta Phys. Sin. 57 1851 (in Chinese) [姜雪宁, 王昊, 马小叶, 孟宪芹, 张庆瑜 2008 57 1851]
[37]	Laffez P, Chen X Y, Banerjee G, Pezeril T, Rossell M D, Van Tendeloo G, Lacorre P, Liu J M, Liu Z G 2006 Thin Solid Films 500 27
[38]	Zhuang Z, Wang X P, Sun A H, Li Y, Fang Q F 2008 J. Sol-Gel Sci. Technol. 48 315
[39]	Zhuang Z, Wang X P, Li D, Zhang T, Fang Q F 2009 J. Am. Ceram. Soc. 92 839
[40]	Zhang D M. Zhuang Z, Gao Y X, Wang X P, Fang Q F 2010 Solid State Ionics 181 1510
[41]	Zhang D M, Zhuang Z, Wang X P, Gao Y X, Fang Q F 2012 J. Eu.r Ceram Soc. 32 3239
[42]	Das S, Mukhopadhyay A K, Datta S, Basu D 2009 Bull Mater Sci. 32 1
[43]	Luo J, Zhu H T, Liang J K 2009 Physics 38 267 (in Chinese) [骆军, 朱航天, 梁敬魁 2009 物理 38 267]
[44]	Xiang J, Li L P, Su W H 2003 Acta Phys. Sin. 52 1474 (in Chinese) [向军, 李莉萍, 苏文辉 2003 52 1474]
[45]	Hu Y G, Xiao J Z, Xia F, Wu X W, Yan S Z 2010 Acta Phys. Sin. 59 7447 (in Chinese) [胡永刚, 肖建中, 夏风, 武玺旺, 闫双志 2010 59 7447]

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Vol. 62, Issue 7 - 2013-04-05

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