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Single-phased β-Zn4Sb3 and β-Zn4Sb3/ Zn1-δAlδO composites with different amounts of Zn1-δAlδO (AZO) are prepared by the combination of vacuum melting and spark plasma sintering (SPS). Thermoelectric properties of the materials are investigated in a temperature range from 300 K to 673 K. As a result, the electrical conductivity of each sample increases while the Seebeck coefficient and the thermal conductivity decrease with the increase of AZO. The maximum ZT value of the composite reaches 1.16 at 673 K when the amount of AZO is 0.2 wt%, which is higher than that for the single-phased β-Zn4Sb3 (1.03).
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Keywords:
- β-Zn4Sb3 /
- Zn1-δAlδO /
- composite materials /
- thermoelectric properties
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[2] Disalvo F J 1999 Science 285 703
[3] Cao W Q, Yan Y G, Tang X F 2010 Acta Phys. Sin. 59 630 (in Chinese) [曹卫强、鄢永高、唐新峰 2010 59 630]
[4] Li K Z, Liang R S, Wei Z J 2008 Chin. Phys. B 17 1349
[5] Deng S K, Tang X F, Tang R S 2009 Chin. Phys. B 18 3084
[6] Xiong C, Deng S K, Tang X F, Qi Q, Zhang Q J 2008 Acta Phys. Sin. 57 1190 (in Chinese) [熊 聪、邓书康、唐新峰、祁 琼、张清杰 2008 57 1190]
[7] Chen X Y, Xu X F, Hu R X, Ren Z, Xu Z A, Cao G H 2007 Acta Phys. Sin. 56 1627 (in Chinese) [陈晓阳、徐象繁、胡荣星、任 之、许祝安、曹光旱 2007 56 1627]
[8] Zhang X, Li J, Lu Q M, Zhang J X, Liu Y Q 2008 Acta Phys. Sin. 57 4466 (in Chinese) [张 忻、李 佳、路清梅、张久兴、刘燕琴 2008 57 4466]
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[10] Snyder G J, Christensen M, Nishibori E, Caillat T, Iversen B B 2004 Nat. Mater. 3 458
[11] Caillat T, Borshchevsky A, Fleurial J P 2005 US Patent 6942728B2
[12] Mozharivskyj Y, Pecharsky A O, Bud’ko S 2004 Chem. Mater. 16 1580
[13] Caillat T, Fleurial J P, Borshchevsky A 1997 J. Phys. Chem. Solids 58 1119
[14] Chitroub M, Besse F, Scherrer H 2008 J. Alloys Compd. 460 90
[15] Pedersen B L, Birkedal H, Nygren M, Frederiksen P T, Iversen B B 2009 J. Appl. Phys. 105 013517
[16] Nylen J, Lidin S, Andersson M, Liu H X, Newman N, Hussermann U 2007 J. Solid State Chem. 180 2603
[17] Liu F, Qin X Y, Liu M 2009 Chin. Phys. B 18 4386
[18] Tsutsui M, Zhang L T, Ito K, Yamaguchi M 2004 Intermetallics 12 809
[19] Cui J L, Fu H, Chen D Y, Mao L D, Liu X L, Yang W 2009 Mater. Charact. 60 824
[20] Nakamoto G, Souma T, Yamaba M, Kurisu M 2004 J. Alloys Compd. 377 59
[21] Li W, Zhou L M, Li Y L, Jiang J, Xu G J 2009 J. Alloys Compd. 486 335
[22] Qi Q, Tang X F, Xiong C, Zhao W Y, Zhang Q J 2006 Acta Phys. Sin. 55 5539 (in Chinese) [祁 琼、唐新峰、熊 聪、赵文瑜、张清杰 2006 55 5539]
[23] Ueno K, Yamamoto A, Noguchi T, Li C H, Inoue T, Sodeoka S, Obara H 2006 J. Alloys Compd. 417 259
[24] Cui J L, Mao L D, Chen D Y, Qian X, Liu X L, Yang W 2009 Curr. Appl. Phys. 9 713
[25] Guan Z D, Zhang Z T, Jiao J S 1992 Physical Properties of Inorganic Material (Beijing: Tsinghua University Press) p265 (in Chinese)[关振铎、张中太、焦金生 1992 无机材料物理性能(北京:清华大学出版社)第265页]
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[1] Tang X F, Chen L D, Goto T, Hirai T, Yuan R Z 2002 Acta Phys. Sin. 51 2823 (in Chinese) [唐新峰、陈立东、後藤孝、平井敏雄、袁润章 2002 51 2823]
[2] Disalvo F J 1999 Science 285 703
[3] Cao W Q, Yan Y G, Tang X F 2010 Acta Phys. Sin. 59 630 (in Chinese) [曹卫强、鄢永高、唐新峰 2010 59 630]
[4] Li K Z, Liang R S, Wei Z J 2008 Chin. Phys. B 17 1349
[5] Deng S K, Tang X F, Tang R S 2009 Chin. Phys. B 18 3084
[6] Xiong C, Deng S K, Tang X F, Qi Q, Zhang Q J 2008 Acta Phys. Sin. 57 1190 (in Chinese) [熊 聪、邓书康、唐新峰、祁 琼、张清杰 2008 57 1190]
[7] Chen X Y, Xu X F, Hu R X, Ren Z, Xu Z A, Cao G H 2007 Acta Phys. Sin. 56 1627 (in Chinese) [陈晓阳、徐象繁、胡荣星、任 之、许祝安、曹光旱 2007 56 1627]
[8] Zhang X, Li J, Lu Q M, Zhang J X, Liu Y Q 2008 Acta Phys. Sin. 57 4466 (in Chinese) [张 忻、李 佳、路清梅、张久兴、刘燕琴 2008 57 4466]
[9] Slack G A, Tsoukala V G 1994 J. Appl. Phys. 76 1665
[10] Snyder G J, Christensen M, Nishibori E, Caillat T, Iversen B B 2004 Nat. Mater. 3 458
[11] Caillat T, Borshchevsky A, Fleurial J P 2005 US Patent 6942728B2
[12] Mozharivskyj Y, Pecharsky A O, Bud’ko S 2004 Chem. Mater. 16 1580
[13] Caillat T, Fleurial J P, Borshchevsky A 1997 J. Phys. Chem. Solids 58 1119
[14] Chitroub M, Besse F, Scherrer H 2008 J. Alloys Compd. 460 90
[15] Pedersen B L, Birkedal H, Nygren M, Frederiksen P T, Iversen B B 2009 J. Appl. Phys. 105 013517
[16] Nylen J, Lidin S, Andersson M, Liu H X, Newman N, Hussermann U 2007 J. Solid State Chem. 180 2603
[17] Liu F, Qin X Y, Liu M 2009 Chin. Phys. B 18 4386
[18] Tsutsui M, Zhang L T, Ito K, Yamaguchi M 2004 Intermetallics 12 809
[19] Cui J L, Fu H, Chen D Y, Mao L D, Liu X L, Yang W 2009 Mater. Charact. 60 824
[20] Nakamoto G, Souma T, Yamaba M, Kurisu M 2004 J. Alloys Compd. 377 59
[21] Li W, Zhou L M, Li Y L, Jiang J, Xu G J 2009 J. Alloys Compd. 486 335
[22] Qi Q, Tang X F, Xiong C, Zhao W Y, Zhang Q J 2006 Acta Phys. Sin. 55 5539 (in Chinese) [祁 琼、唐新峰、熊 聪、赵文瑜、张清杰 2006 55 5539]
[23] Ueno K, Yamamoto A, Noguchi T, Li C H, Inoue T, Sodeoka S, Obara H 2006 J. Alloys Compd. 417 259
[24] Cui J L, Mao L D, Chen D Y, Qian X, Liu X L, Yang W 2009 Curr. Appl. Phys. 9 713
[25] Guan Z D, Zhang Z T, Jiao J S 1992 Physical Properties of Inorganic Material (Beijing: Tsinghua University Press) p265 (in Chinese)[关振铎、张中太、焦金生 1992 无机材料物理性能(北京:清华大学出版社)第265页]
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