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By diagonalizing the complete energy matrix for d3 configuration ion in a trigonal ligand-field based on ligand-field theory，optical and EPR spectra of Cr3+：Be3Al2(SiO3)6 system are studied，the results of which are in good agreement with experimental facts. By analyzing optical and EPR spectra of (CrO6)9- cluster，the local polarization of oxygen ligands in (CrO6)9- cluster are studied. Results show that oxygen ligands in (CrO6)9- cluster exhibit remarkable polarization effect due to the effect of surrounding environment.
[1] ［1］ Quarles G J，Suchocki A，Powell RC，Lai S 1988 Phys. Rev. B 38 9996
[2] ［2］ Geusic J E，Peter M，Bois E O Schulz-Du 1959 Bell. System. Technical. Journal 38 291
[3] ［3］ Yang Z Y 1999 Chin. J. Quantum. Electron 16 243 (in Chinese) ［杨子元 1999 量子电子学报 16 243］
[4] ［4］ Burns G，Geiss E A，Jenkins BA，Nathan MI 1965 Phys. Rev. 139A 1687
[5] ［5］ Fonger W H，Struck C W 1975 Phys. Rev. B 11 3251
[6] ［6］ Parikh P，Saini N L，Dalela S，Bhardwaj D M，Fernandes S，Gupta R P，Garg K B 2003 Nucl. Instrum. Methods Phys. Res.，Sect. B 199 489
[7] ［7］ Fairbank，Jr. W M，Klauminzer G K，Schawlow A L 1975 Phys. Rev. B 11 60
[8] ［8］ García-Lastra J M，Aramburu J A，Barriuso M T，Moreno M 2006 Phys. Rev. B 74 115118
[9] ［9］ Wang H，Kuang X Y，Mao A J，Yang X 2007 Chem. Phys. Lett. 436 149
[10] ］ Wei Q 2009 Acta Phys. Sin. 58 3485 (in Chinese) ［魏群 2009 58 3485］
[11] ］ Wei Q，Yang Z Y，Wan C J，Xu Q M 2007 Acta Phys. Sin. 56 0507 (in Chinese) ［魏群、杨子元、王参军、许启明 2007 56 0507］
[12] ］ Abragam A，Bleany B 1970 Electron Paramagnetic Resonance of Transition Ions (London：Oxford University Press)
[13] ］ Newman D J，Urban W 1975 Adv. Phys. 24 793
[14] ］ Van Vleck J H 1932 Phys. Rev. 41 208
[15] ］ Zhao M G，Xu J A，Bai G R，Xie H S 1983 Phys. Rev. B 27 1516
[16] ］ McClure D S 1963 J. Chem. Phys. 38 2289
[17] ］J￠rgensen C K 1962 Absorption spectra and chemical bonding in complexes (Pergamon Press，Oxford. London. NewYork. Paris) p290
[18] ］ Bravo D，López F J 1992 J. Phys.：Condens. Matter 4 10335
[19] ］ Wang H Q，Kuang X Y，Li H F，Mao A J 2009 J. Alloys Compd 468 1
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[1] ［1］ Quarles G J，Suchocki A，Powell RC，Lai S 1988 Phys. Rev. B 38 9996
[2] ［2］ Geusic J E，Peter M，Bois E O Schulz-Du 1959 Bell. System. Technical. Journal 38 291
[3] ［3］ Yang Z Y 1999 Chin. J. Quantum. Electron 16 243 (in Chinese) ［杨子元 1999 量子电子学报 16 243］
[4] ［4］ Burns G，Geiss E A，Jenkins BA，Nathan MI 1965 Phys. Rev. 139A 1687
[5] ［5］ Fonger W H，Struck C W 1975 Phys. Rev. B 11 3251
[6] ［6］ Parikh P，Saini N L，Dalela S，Bhardwaj D M，Fernandes S，Gupta R P，Garg K B 2003 Nucl. Instrum. Methods Phys. Res.，Sect. B 199 489
[7] ［7］ Fairbank，Jr. W M，Klauminzer G K，Schawlow A L 1975 Phys. Rev. B 11 60
[8] ［8］ García-Lastra J M，Aramburu J A，Barriuso M T，Moreno M 2006 Phys. Rev. B 74 115118
[9] ［9］ Wang H，Kuang X Y，Mao A J，Yang X 2007 Chem. Phys. Lett. 436 149
[10] ］ Wei Q 2009 Acta Phys. Sin. 58 3485 (in Chinese) ［魏群 2009 58 3485］
[11] ］ Wei Q，Yang Z Y，Wan C J，Xu Q M 2007 Acta Phys. Sin. 56 0507 (in Chinese) ［魏群、杨子元、王参军、许启明 2007 56 0507］
[12] ］ Abragam A，Bleany B 1970 Electron Paramagnetic Resonance of Transition Ions (London：Oxford University Press)
[13] ］ Newman D J，Urban W 1975 Adv. Phys. 24 793
[14] ］ Van Vleck J H 1932 Phys. Rev. 41 208
[15] ］ Zhao M G，Xu J A，Bai G R，Xie H S 1983 Phys. Rev. B 27 1516
[16] ］ McClure D S 1963 J. Chem. Phys. 38 2289
[17] ］J￠rgensen C K 1962 Absorption spectra and chemical bonding in complexes (Pergamon Press，Oxford. London. NewYork. Paris) p290
[18] ］ Bravo D，López F J 1992 J. Phys.：Condens. Matter 4 10335
[19] ］ Wang H Q，Kuang X Y，Li H F，Mao A J 2009 J. Alloys Compd 468 1
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